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Hordenine

Product Name
Hordenine
CAS No.
539-15-1
Chemical Name
Hordenine
Synonyms
Hordenin;Hordeine;Anhalin;Cactine;Anhaline;Hordetin;Ordenina;Ordenine;Eremursin;Hordenine
CBNumber
CB4747471
Molecular Formula
C10H15NO
Formula Weight
165.23
MOL File
539-15-1.mol
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Hordenine Property

Melting point:
117-118°
Boiling point:
bp11 173°
Density 
1.0203 (rough estimate)
refractive index 
1.4820 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
pka
10.05±0.26(Predicted)
form 
Solid
color 
Pale Yellow to Dark Beige
Merck 
14,4746
BRN 
2207615
LogP
1.400 (est)
CAS DataBase Reference
539-15-1(CAS DataBase Reference)
NIST Chemistry Reference
Phenol, 4-[2-(dimethylamino)ethyl]-(539-15-1)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36-43
Safety Statements 
26-36/37
WGK Germany 
3
HS Code 
29222990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
04476
Product name
Hordenine
Purity
≥97.0% (HPLC)
Packaging
100mg
Price
$96.2
Updated
2024/03/01
Sigma-Aldrich
Product number
PHL80469
Product name
Hordenine
Purity
phyproof? Reference Substance
Packaging
50mg
Price
$382
Updated
2024/03/01
Sigma-Aldrich
Product number
04476
Product name
Hordenine
Purity
≥97.0% (HPLC)
Packaging
1g
Price
$713
Updated
2024/03/01
TCI Chemical
Product number
H1351
Product name
Hordenine
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$38
Updated
2024/03/01
TCI Chemical
Product number
H1351
Product name
Hordenine
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$115
Updated
2024/03/01
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Hordenine Chemical Properties,Usage,Production

Description

Hordenine (Item No. 21626) is a naturally occurring alkaloid found in a variety of plants, most commonly germinated barley (Hordeum species) from which the name is derived, and is structurally classified as a phenethylamine. It is biosynthesized by the step-wise double methylation of tyramine . Hordenine binds to and activates the dopamine D2 receptor (Ki = 13 μM) but antagonizes D2 receptor β-arrestin recruitment. It inhibits tyrosinase activity and expression at concentrations ≥ 50 μM resulting in reduced melanin accumulation in human melanocytes. Hordenine is present in significant amounts in beer and can be measured in serum in the free form, for up to 2 hours, and the glucuronidated form, for up to 6 hours, after beer consumption. This product is intended for research and forensic applications.

Chemical Properties

Light yellow solid

Uses

Hordenine is suitable to study the effect of reed canary grass alkoloids on in vito digestibility. It is also suitable for use as a standard to identify endogenous hordenine in ungerminated and germinated barley by HPLC/diode array detection analysis. Hordenine may be used as an analytical reference material and in research on the activities of phenethylamine type alkaloids.

Uses

A phenethylamine alkaloid with antibacterial and antibiotic properties found mainly in plants from the cactaceae family. It showed effects similar to Cytosine (C998950) and acted as a depressant on the central nervous system (CNS) during animal testing.

Definition

ChEBI: Hordenine is a phenethylamine alkaloid. It has a role as a human metabolite and a mouse metabolite.

Biochem/physiol Actions

Hordenine is an alkaloid found in plants, e.g. the roots of germinating barley and marine algae. It is a metabolite in tyrosine metabolism, biosynthesized from tyramine by two subsequent N-methylations, it is metabolized by monoamine oxidase. Hordenine is a sympathomimetic and its pharmacological actions are of interest, as it is occasionally found in post race urine samples. Hordenine inhibits melanogenesis by suppression of cyclic adenosine monophosphate (cAMP) production. cAMP is involved in the expression of melanogenesis-related proteins. Hordenine may be used in the inhibition of hyperpigmentation. It is present in barley roots from the first day of seed germination, but is not present in seeds.

Purification Methods

Crystallise Hordenine from EtOH or H2O and sublime it at 105o/5mm. The 4,4’-dichlorodiphenyl disulfimide salt has m 145-146o (from Me2CO/H2O) [Runge et al. Chem Ber 88 50 1955]. [Beilstein 13 H 626, 13 I 236, 13 II 356, 13 III 1640, 13 IV 1790.]

Hordenine Preparation Products And Raw materials

Raw materials

Preparation Products

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Hordenine Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8415
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
jiliang chemicals
Tel
21-62165282 15801962796;
Fax
021 61153784
Email
bidingchem@163.com
Country
China
ProdList
1183
Advantage
60
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
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View Lastest Price from Hordenine manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Hordenine 539-15-1
Price
US $200.00-85.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-23
Hebei Yanxi Chemical Co., Ltd.
Product
4-(2-dimethylaminoethyl)phenol 539-15-1
Price
US $1.00/kg
Min. Order
1kg
Purity
99.0%
Supply Ability
20tons
Release date
2023-09-06
Hebei Weibang Biotechnology Co., Ltd
Product
Hordenine 539-15-1
Price
US $10.00/pc
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-03-30

539-15-1, HordenineRelated Search:


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