TERT-BUTYLPEROXY ISOPROPYL CARBONATE Property

Melting point:

-20 °C

Boiling point:

170.8±23.0 °C(Predicted)

Density 

0.905

vapor pressure 

60Pa at 22℃

refractive index 

n20/D 1.448

Flash point:

47 °C

storage temp. 

Refrigerator (+4°C) + Flammables area

Water Solubility 

2.2g/L at 20℃

LogP

2.5 at 30℃

EPA Substance Registry System

Carbonoperoxoic acid, OO-(1,1-dimethylethyl) O-(1-methylethyl) ester (2372-21-6)

Safety

Hazard Codes 

Xi-E,Xi,O,T

Risk Statements 

7-36-2-10-41-65-45

Safety Statements 

36/37/39-35-3/7-26-14A-14-62-45-53

RIDADR 

3103

HazardClass 

5.2

PackingGroup 

II

HS Code 

29159000

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H242Heating may cause a fire

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H317May cause an allergic skin reaction

H400Very toxic to aquatic life

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P234Keep only in original container.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P391Collect spillage. Hazardous to the aquatic environment

P403+P235Store in a well-ventilated place. Keep cool.

P411Store at temperatures not exceeding … oC/…oF.

P420Store away from other materials.

P501Dispose of contents/container to..…

TERT-BUTYLPEROXY ISOPROPYL CARBONATE Chemical Properties,Usage,Production

Chemical Properties

clear solution

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 1254, 1950 DOI: 10.1021/ja01159a052

General Description

Sensitive to heat. Must be stored with stringent maintenance of low temperature.

Reactivity Profile

TERT-BUTYLPEROXY ISOPROPYL CARBONATE is a oxidizing agent. Decomposes violently or explosively at temperatures 0-10°C owing to self- accelerating exothermic decomposition; Several explosions were due to shock, heat or friction. Amines and certain metals can accelerate decomposition [Bretherick 1979 p. 151].

Flammability and Explosibility

Not classified