3-CHLORO-2,4-PENTANEDIONE
- Product Name
- 3-CHLORO-2,4-PENTANEDIONE
- CAS No.
- 1694-29-7
- Chemical Name
- 3-CHLORO-2,4-PENTANEDIONE
- Synonyms
- 3-chloropentane-2,4-dione;3-Chloro-2,4-pentadione;3-Chloro-2,4-pentanedione,98%;3-Cl-ACAC;3-CHLOROACETYLACETONE;3-chloro-4-pentanedione;3-Chloropentandione-2,4;-chloropentane-2,4-dione;3-CHLORO-2,4-PENTANEDIONE;3-Chloroacetylacetone >
- CBNumber
- CB4774318
- Molecular Formula
- C5H7ClO2
- Formula Weight
- 134.56
- MOL File
- 1694-29-7.mol
3-CHLORO-2,4-PENTANEDIONE Property
- Melting point:
- -15 °C
- Boiling point:
- 49-52 °C/18 mmHg (lit.)
- Density
- 1.1921 g/mL at 20 °C (lit.)
- vapor pressure
- 15 hPa (20 °C)
- refractive index
- n20/D 1.483(lit.)
- Flash point:
- 54 °F
- storage temp.
- 2-8°C
- solubility
- 7.65g/l
- form
- Liquid
- pka
- 6.77±0.46(Predicted)
- Specific Gravity
- 1.129
- color
- Clear yellow to very deep brown
- PH
- 3.9 (7.65g/l, H2O, 20℃)
- explosive limit
- 2.1%(V)
- BRN
- 605870
- CAS DataBase Reference
- 1694-29-7(CAS DataBase Reference)
- EPA Substance Registry System
- 2,4-Pentanedione, 3-chloro- (1694-29-7)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 227153
- Product name
- 3-Chloro-2,4-pentanedione
- Purity
- 97%
- Packaging
- 100g
- Price
- $176
- Updated
- 2025/07/31
- Product number
- C1277
- Product name
- 3-Chloroacetylacetone
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $40
- Updated
- 2025/07/31
- Product number
- FC35362
- Product name
- 3-Chloro-2,4-pentanedione
- Packaging
- 25g
- Price
- $80
- Updated
- 2021/12/16
- Product number
- FC35362
- Product name
- 3-Chloro-2,4-pentanedione
- Packaging
- 50g
- Price
- $125
- Updated
- 2021/12/16
- Product number
- FC35362
- Product name
- 3-Chloro-2,4-pentanedione
- Packaging
- 10g
- Price
- $40
- Updated
- 2021/12/16
3-CHLORO-2,4-PENTANEDIONE Chemical Properties,Usage,Production
Chemical Properties
clear yellow to very deep brown liquid
Uses
3-Chloro-2,4-pentanedione was used in the synthesis of tetrathiafulvenyl-acetylacetonate (TTFSacacH), precursor of novel redox-active ligands.
General Description
The tautomeric properties of 3-chloro-2,4-pentanedione were studied using gas electron diffraction (GED) and quantum chemical calculations.
Synthesis
123-54-6
1694-29-7
The general procedure for the synthesis of 3-chloro-2,4-pentanedione from acetylacetone under solvent-free conditions was as follows: first, a temperature control device was installed to maintain the reaction temperature at 15°C and the system pressure was adjusted to 1-2 atm. Acetylacetone was introduced continuously into the reaction system via a metering pump at a flow rate of 1 mol/h and chlorine at a flow rate of 1.0 mol/h. The reaction time was strictly controlled to 20 seconds. During the reaction, the temperature at the reactor outlet was gradually increased to 35 °C and the temperature at the outlet of Pipeline 2 was increased to 25 °C. The reaction lasted for 1 h and was terminated and sampled for gas phase analysis. The results showed that the reaction selectivity was 83.1% and the quantitative yield was 79.2%.
References
[1] Patent: CN105418548, 2016, A. Location in patent: Paragraph 0017
[2] Journal of the Chinese Chemical Society (Taipei, Taiwan), 1997, vol. 44, # 3, p. 309 - 312
[3] Journal of Organic Chemistry, 1995, vol. 60, # 10, p. 3074 - 3083
[4] Advanced Synthesis and Catalysis, 2015, vol. 357, # 1, p. 148 - 158
[5] Journal of the American Chemical Society, 1945, vol. 67, p. 395,399
3-CHLORO-2,4-PENTANEDIONE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-CHLORO-2,4-PENTANEDIONE manufacturers
- Product
- 3-CHLORO-2,4-PENTANEDIONE 1694-29-7
- Price
- US $8.80/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 100kg
- Release date
- 2019-07-04