1-METHYL-1,3-DIHYDRO-INDOLE-2-THIONE

1-METHYL-1,3-DIHYDRO-INDOLE-2-THIONE Property

form 

powder or crystals

color 

white to yellow

InChI

InChI=1S/C9H9NS/c1-10-8-5-3-2-4-7(8)6-9(10)11/h2-5H,6H2,1H3

InChIKey

GBSPZRWQIJCQQB-UHFFFAOYSA-N

SMILES

S=C1N(C)C2=CC=CC=C2C1

Safety

WGK Germany 

WGK 3

Storage Class

11 - Combustible Solids

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

1-METHYL-1,3-DIHYDRO-INDOLE-2-THIONE Chemical Properties,Usage,Production

Uses

1-Methylindoline-2-thione is a indole thiolate has been used in the synthesis of:

• Brassilexin, Sinalexin and Wasalexins
• Functionilized thiopyrano-indole annulated heterocycles
• N-Alkylated Analogues of Indolylthio Glycosides

• The activation of C-F. C-Cl and C-O bonds
• The synthesis of thioethers from aryl chlorides & alcohols

reaction suitability

reaction type: Photocatalysis