Thiocyanic acid Property

Melting point:

-110 °C

Boiling point:

-87.78°C (estimate)

Density 

1.228 (estimate)

refractive index 

1.4640 (estimate)

pka

0.93±0.10(Predicted)

PH

pKa1= –0.87(25℃)

LogP

0.429 (est)

EPA Substance Registry System

Thiocyanic acid (463-56-9)

Safety

Hazard Codes 

Xn

Risk Statements 

20/21/22-32-52/53

Safety Statements 

13-61

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H332Harmful if inhaled

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P322Specific measures (see …on this label).

P330Rinse mouth.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

Thiocyanic acid Chemical Properties,Usage,Production

Chemical Properties

White substance with an enamel luster. M.p. —110°C. Polymerizes between —90 and —85°C to a white crystalline mass. Converts with careful heating in vacuum to bright-yellow, ether-soluble thiocyanuric acid [(HNCS)3?], which readily dissocates into HNCS. If either HNCS or the yellow form is heated at room temperature without evacuation, the material slowly turns dark red, both in the presence and in the absence of air. At about +3°C, a rapid exothermic reaction occurs. The entire mass foams and coalesces into a slurry. Miscible with water in all proportions. Dilute solutions (<5%) are stable. Very strong acid.

Definition

ChEBI: A hydracid that is cyanic acid in which the oxygen is replaced by a sulfur atom.

Definition

thiocyanic acid: An unstable gas, HSCN.

Synthesis

A mixture of KNCS and KHSO4 is ground together as finely as possible and allowed to stand for 3-4 weeks over P3OS. Then flask a of an apparatus is successively charged (the order of addition should be maintained) with 250 g. of glass beads (6-7 mm. in diameter), 100 g. of KNCS alternated with beads, then a covering layer of glass beads, then the required amount of KHSO4 mixed with glass beads. Without disturbing these layers, the glass flask is mounted in a rigid support and joined on one side of the horizontal tube p via a ground glass spray trap / . The other ground glass joint of a is closed off with a cap.
KNCS + KHSO4 = K2SO4 + HNCS