ChemicalBook > CAS DataBase List > 3-Aminophenylacetic acid, N-BOC protected

3-Aminophenylacetic acid, N-BOC protected

Product Name: 3-Aminophenylacetic acid, N-BOC protected
CAS No.: 123036-51-1
Chemical Name: 3-Aminophenylacetic acid, N-BOC protected
Synonyms: Boc-3-APAC-OH;3-(Boc-aMino)phenylacetic acid;N-BOC-3-AMINOPHENYLACETIC ACID;3-[N-BOC-Amino]benzeneacetic acid;3-Aminophenylacetic acid, N-BOC protected;2-(3-((tert-Butoxycarbonyl)aMino)phenyl)acetic acid;3-[(tert-Butoxycarbonyl)amino]phenylacetic acid 95+%;3-[[(1,1-dimethylethoxy)carbonyl]amino]Benzeneacetic acid;Benzeneacetic acid,3-[[(1,1-diMethylethoxy)carbonyl]aMino]-;2-[3-[(2-methylpropan-2-yl)oxycarbonylamino]phenyl]acetic acid
CBNumber: CB4956879
Molecular Formula: C13H17NO4
Formula Weight: 251.28
MOL File: 123036-51-1.mol

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3-Aminophenylacetic acid, N-BOC protected Property

Melting point:: 100-102
storage temp.: 2-8°C
form: solid
color: Off-white

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Safety

Hazard Codes: Xi
HazardClass: IRRITANT
HS Code: 29225090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: B630013
Product name: N-Boc-3-AminophenylaceticAcid
Packaging: 500mg
Price: $155
Updated: 2021/12/16

AK Scientific

Product number: 4429AA
Product name: N-Boc-3-Aminophenylaceticacid
Packaging: 1g
Price: $157
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4656-1-X7
Product name: 3-[(tert-Butoxycarbonyl)amino]phenylacetic acid
Packaging: 1g
Price: $125
Updated: 2021/12/16

Matrix Scientific

Product number: 012558
Product name: 3-tert-Butoxy carbonylaminophenyl acetic acid
Purity: 98%
Packaging: 500mg
Price: $63
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB49897
Product name: Boc-3-aminophenylacetic acid
Packaging: 500mg
Price: $95
Updated: 2021/12/16

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3-Aminophenylacetic acid, N-BOC protected Chemical Properties,Usage,Production

Synthesis

24424-99-5

14338-36-4

123036-51-1

GENERAL STEPS: 3-Aminophenylacetic acid (12.4 g, 26.46 mmol, 1 equiv) was dissolved in a solvent mixture of dioxane (52 mL) and water (52 mL). An aqueous solution of sodium carbonate (2.8 g, 26.42 mmol, 1 equiv) was added to this solution (26 mL) under cooling in an ice bath. Subsequently, di-tert-butyl dicarbonate (Boc2O, 6.24 g, 28.59 mmol, 1.1 eq.) was added all at once and stirred continuously for 4 hours at room temperature. Upon completion of the reaction, the dioxane was removed by distillation under reduced pressure. The aqueous layer was cooled, covered with ethyl acetate and acidified with dilute KHSO4 solution to pH 4. The organic layer was extracted with ethyl acetate and purified by silica gel column chromatography (ethyl acetate was used as the eluent) to afford the target compound, N-Boc-3-aminophenylacetic acid (6.65 g, 85% yield), as a white solid.1H-NMR (300 MHz, CDCl3) data were as follows: δ 7.31 (d, 2H, J = 8.4 Hz), 7.20 (d, 2H, J = 8.4 Hz), 6.56 (br s, 1H), 3.59 (s, 2H), 1.50 (s, 9H).

References

[1] Tetrahedron, 2002, vol. 58, # 43, p. 8695 - 8702
[2] Molecules, 2017, vol. 22, # 1,
[3] Organic and Biomolecular Chemistry, 2018, vol. 16, # 22, p. 4127 - 4140

3-Aminophenylacetic acid, N-BOC protected Preparation Products And Raw materials

Raw materials

Preparation Products

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