5-(Hydroxymethyl)-1-methyl-1H-pyrazole
- Product Name
- 5-(Hydroxymethyl)-1-methyl-1H-pyrazole
- CAS No.
- 84547-61-5
- Chemical Name
- 5-(Hydroxymethyl)-1-methyl-1H-pyrazole
- Synonyms
- 1-Methylpyrazole-5-methanol;(2-methylpyrazol-3-yl)methanol;(2-methyl-3-pyrazolyl)methanol;1H-pyrazole-5-methanol, 1-methyl-;(1-Methyl-1H-pyrazol-5-yl)methanol;(2-Methyl-2H-pyrazol-3-yl)-methanol;5-(Hydroxymethyl)-1-methyl-1H-pyrazole;(1-methyl-1H-pyrazol-5-yl)methanol - [M87519]
- CBNumber
- CB4957487
- Molecular Formula
- C5H8N2O
- Formula Weight
- 112.13
- MOL File
- 84547-61-5.mol
5-(Hydroxymethyl)-1-methyl-1H-pyrazole Property
- Melting point:
- 55-59.5
- Boiling point:
- 243.6±15.0 °C(Predicted)
- Density
- 1.16±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- form
- powder to crystal
- pka
- 14.35±0.10(Predicted)
- color
- White to Almost white
Safety
- Hazard Note
- Harmful
- HS Code
- 2933199090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- M2831
- Product name
- 1-Methylpyrazole-5-methanol
- Purity
- >98.0%(GC)(T)
- Packaging
- 1g
- Price
- $159
- Updated
- 2025/07/31
- Product number
- M2831
- Product name
- 1-Methylpyrazole-5-methanol
- Purity
- >98.0%(GC)(T)
- Packaging
- 200mg
- Price
- $40
- Updated
- 2025/07/31
- Product number
- M321443
- Product name
- (1-Methyl-1H-pyrazol-5-yl)methanol
- Packaging
- 500mg
- Price
- $130
- Updated
- 2021/12/16
- Product number
- OR12407
- Product name
- 5-(Hydroxymethyl)-1-methyl-1H-pyrazole
- Packaging
- 250mg
- Price
- $27
- Updated
- 2021/12/16
- Product number
- 4H01-1-U0
- Product name
- 5-(Hydroxymethyl)-1-methyl-1H-pyrazole
- Packaging
- 250mg
- Price
- $29
- Updated
- 2021/12/16
5-(Hydroxymethyl)-1-methyl-1H-pyrazole Chemical Properties,Usage,Production
Synthesis
16034-46-1
84547-61-5
1-Methyl-1H-pyrazole-5-carboxylic acid (2 g, 15.86 mmol) was dissolved in tetrahydrofuran (50 mL) at 0 °C and in an inert atmosphere, followed by batchwise addition of lithium aluminum hydride (LiAlH4, 720 mg, 18.97 mmol). The reaction system was stirred under nitrogen protection at room temperature for 2 hours. Upon completion of the reaction, water (2 mL) was slowly added to quench the reaction. The mixture was dried over anhydrous sodium sulfate and filtered to remove the solid. The filtrate was concentrated under reduced pressure to afford the target product (1-methyl-1H-pyrazol-5-yl)methanol as a colorless oil (1.2 g, 67% yield). Mass spectrum (ESI, m/z): [M + H]+ 113.0. 1H NMR (300 MHz, CDCl3) δ 7.36 (d, J = 1.8 Hz, 1H), 6.18 (d, J = 1.8 Hz, 1H), 4.66 (s, 2H), 3.88 (s, 3H).
References
[1] Patent: WO2014/66795, 2014, A1. Location in patent: Paragraph 0175
[2] J. Gen. Chem. USSR (Engl. Transl.), 1982, vol. 52, # 11, p. 2297 - 2303
[3] Zhurnal Obshchei Khimii, 1982, vol. 52, # 11, p. 2598 - 2605
[4] Patent: WO2014/151142, 2014, A1
[5] Patent: WO2016/29454, 2016, A1. Location in patent: Page/Page column 64
5-(Hydroxymethyl)-1-methyl-1H-pyrazole Preparation Products And Raw materials
Raw materials
Preparation Products
5-(Hydroxymethyl)-1-methyl-1H-pyrazole Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
View Lastest Price from 5-(Hydroxymethyl)-1-methyl-1H-pyrazole manufacturers
- Product
- 5-(Hydroxymethyl)-1-methyl-1H-pyrazole 84547-61-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 10g
- Purity
- 98%
- Supply Ability
- >10kg
- Release date
- 2021-07-09
- Product
- 5-(Hydroxymethyl)-1-methyl-1H-pyrazole 84547-61-5
- Price
- US $500.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2018-08-04