ChemicalBook > CAS DataBase List > 1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO&

1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO&

Product Name
1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO&
CAS No.
638132-66-8
Chemical Name
1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO&
Synonyms
R,R-Me-BozPhos;1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide;1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide kanata purity;(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethyl-1;[1-(2R,5R)-2,5-dimethylphospholanyl]-[2-(2R,5R)-2,5-dimethylphospholanyl-1-oxide]benzene;(2R,5R)-1-(2-[(2R,5R)-2,5-Dimethylphospholan-1-yl]phenyl)-2,5-dimethylphospholane 1-oxide;Phospholane, 1-[2-[(2R,5R)-2,5-dimethyl-1-oxido-1-phospholanyl]phenyl]-2,5-dimethyl-, (2R,5R)-;(2R,5R)-1-(2-[(2R,5R)-2,5-DiMethylphospholan-1-yl]phenyl)-2,5-diMethylphospholane 1-oxide, 97+%;[1-(2R,5R)-2,5-DIMETHYLPHOSPHOLANYL]-[2-(2R,5R)-2,5-DIMETHYLPHOSPHOLANYL-1-OXIDE]BENZENE,MIN.97%;[1-(2R,5R)-2,5-dimethylphospholanyl]-[2-(2R,5R)-2,5-dimethylphospholanyl-1-oxide]benzene, min. 97%
CBNumber
CB4972938
Molecular Formula
C18H28OP2
Formula Weight
322.36
MOL File
638132-66-8.mol
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1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO& Property

Melting point:
116-122 °C
Boiling point:
484.0±28.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
color 
white
optical activity
[α]22/D -171°, c = 1 in chloroform
Sensitive 
Air Sensitive
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
678635
Product name
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide
Purity
kanata purity
Packaging
100mg
Price
$115
Updated
2023/06/20
Sigma-Aldrich
Product number
678635
Product name
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide
Purity
kanata purity
Packaging
500mg
Price
$384
Updated
2023/06/20
Alfa Aesar
Product number
H60834
Product name
(2R,5R)-1-(2-[(2R,5R)-2,5-Dimethylphospholan-1-yl]phenyl)-2,5-dimethylphospholane 1-oxide, 97+%
Packaging
250mg
Price
$171
Updated
2024/03/01
Alfa Aesar
Product number
H60834
Product name
(2R,5R)-1-(2-[(2R,5R)-2,5-Dimethylphospholan-1-yl]phenyl)-2,5-dimethylphospholane 1-oxide, 97+%
Packaging
1g
Price
$568
Updated
2024/03/01
Strem Chemicals
Product number
15-7360
Product name
[1-(2R,5R)-2,5-Dimethylphospholanyl]-[2-(2R,5R)-2,5-dimethylphospholanyl-1-oxide]benzene, min. 97%
Packaging
100mg
Price
$100
Updated
2024/03/01
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1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO& Chemical Properties,Usage,Production

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

General Description

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide is a chiral ligand whose copper complexes are used extensively in many organic reactions such as addition to imines, nitroalkenes, and reduction of β,β-disubstituted vinyl sulfones.

1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO& Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO& Suppliers

638132-66-8, 1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO&Related Search:


  • 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide
  • R,R-Me-BozPhos, (2R,5R)-1-{2-[(2R,5R)-2,5-Dimethylphospholan-1-yl]phenyl}-2,5-dimethylphospholane 1-oxide
  • [1-(2R,5R)-2,5-dimethylphospholanyl]-[2-(2R,5R)-2,5-dimethylphospholanyl-1-oxide]benzene, min. 97%
  • (2R,5R)-1-(2-[(2R,5R)-2,5-DiMethylphospholan-1-yl]phenyl)-2,5-diMethylphospholane 1-oxide, 97+%
  • R,R-Me-BozPhos
  • 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide kanata purity
  • [1-(2R,5R)-2,5-DIMETHYLPHOSPHOLANYL]-[2-(2R,5R)-2,5-DIMETHYLPHOSPHOLANYL-1-OXIDE]BENZENE,MIN.97%
  • [1-(2R,5R)-2,5-dimethylphospholanyl]-[2-(2R,5R)-2,5-dimethylphospholanyl-1-oxide]benzene
  • Phospholane, 1-[2-[(2R,5R)-2,5-dimethyl-1-oxido-1-phospholanyl]phenyl]-2,5-dimethyl-, (2R,5R)-
  • (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethyl-1
  • (2R,5R)-1-(2-[(2R,5R)-2,5-Dimethylphospholan-1-yl]phenyl)-2,5-dimethylphospholane 1-oxide
  • 638132-66-8