Methyl 4-hydroxy-3-methylbenzoate

Product Name: Methyl 4-hydroxy-3-methylbenzoate
CAS No.: 42113-13-3
Chemical Name: Methyl 4-hydroxy-3-methylbenzoate
Synonyms: methyl 4-hydoxy-3-methylbenzoate;METHYL 4-HYDROXY-3-METHYLBENZOATE;Methyl 3-methyl-4-hydroxybenzoate;Methyl 4-hydroxy-3-Methylbenzoic acid;3-methyl-4-hydroxybenzoic acid methyl ester
CBNumber: CB51010654
Molecular Formula: C9H10O3
Formula Weight: 166.17
MOL File: 42113-13-3.mol

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Methyl 4-hydroxy-3-methylbenzoate Property

Melting point:: 124-125℃
Boiling point:: 282.9±20.0 °C(Predicted)
Density: 1.169±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
pka: 8.70±0.18(Predicted)
Appearance: Light brown to off-white Solid

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Safety

HS Code: 2918290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M323510
Product name: Methyl4-hydroxy-3-methylbenzoate
Packaging: 500mg
Price: $65
Updated: 2021/12/16

Matrix Scientific

Product number: 063755
Product name: Methyl 4-hydroxy-3-methylbenzoate
Packaging: 500mg
Price: $16
Updated: 2021/12/16

Apolloscientific

Product number: OR911863
Product name: Methyl4-hydroxy-3-methylbenzoate
Purity: 98%
Packaging: 1g
Price: $124
Updated: 2021/12/16

AK Scientific

Product number: J92403
Product name: Methyl4-hydroxy-3-methylbenzoate
Packaging: 25g
Price: $225
Updated: 2021/12/16

Apolloscientific

Product number: OR911863
Product name: Methyl4-hydroxy-3-methylbenzoate
Purity: 98%
Packaging: 10g
Price: $363
Updated: 2021/12/16

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Methyl 4-hydroxy-3-methylbenzoate Chemical Properties,Usage,Production

Synthesis

67-56-1

499-76-3

42113-13-3

General procedure for the synthesis of methyl 3-methyl-4-hydroxybenzoate from methanol and 4-hydroxy-3-methylbenzoic acid: 4-hydroxy-3-methylbenzoic acid (342 g, 2.24 mol) was dissolved in methanol (3.5 L), and the solution was bubbled with hydrogen chloride gas (HCl) for 5 min. Subsequently, the reaction mixture was stirred at room temperature for 12 hours. Upon completion of the reaction, the reaction mixture was concentrated to afford methyl 3-methyl-4-hydroxybenzoate (372 g, quantitative yield). NMR hydrogen spectrum of the product (1H-NMR, CDCl3, δ ppm): 7.82 (1H, single peak), 7.78 (1H, double peak), 6.80 (1H, double peak), 3.86 (3H, single peak), 2.22 (3H, single peak).

References

[1] Patent: WO2003/101978, 2003, A1. Location in patent: Page 170-171
[2] European Journal of Medicinal Chemistry, 2009, vol. 44, # 7, p. 2994 - 3008
[3] Patent: US2006/135484, 2006, A1. Location in patent: Page/Page column 59
[4] Journal of Medicinal Chemistry, 2018, vol. 61, # 7, p. 3059 - 3075
[5] Patent: WO2012/125613, 2012, A1. Location in patent: Page/Page column 146

Methyl 4-hydroxy-3-methylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 4-hydroxy-3-methylbenzoate Suppliers

China 80 India 1 United Kingdom 1 United States 6 Global 88

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View Lastest Price from Methyl 4-hydroxy-3-methylbenzoate manufacturers

Career Henan Chemical Co

Product: 4-HYDROXY-3-METHYL-BENZOIC ACID METHYL ESTER 42113-13-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-03

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Methyl 4-hydroxy-3-Methylbenzoic acid

Methyl 3-methyl-4-hydroxybenzoate

methyl 4-hydoxy-3-methylbenzoate

METHYL 4-HYDROXY-3-METHYLBENZOATE

3-methyl-4-hydroxybenzoic acid methyl ester

42113-13-3