ChemicalBook > CAS DataBase List > Phenylsulfenylchloride

Phenylsulfenylchloride

Product Name
Phenylsulfenylchloride
CAS No.
931-59-9
Chemical Name
Phenylsulfenylchloride
Synonyms
phenyl hypochlorothioite;fenyL;BENZENESULFENYL CHLORIDE;(Chlorothio)benzene;Phenylthio chloride;Phenylchloro sulfide;Phenylsulfenylchloride;Benzene, (chlorothio)-;Phenyl Thiohypochlorite;(Chlorosulfanyl)benzene
CBNumber
CB51075374
Molecular Formula
C6H5ClS
Formula Weight
144.62
MOL File
931-59-9.mol
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Phenylsulfenylchloride Property

Boiling point:
262℃
Density 
1.25
Flash point:
110℃
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC
Product number
P296045
Product name
PhenylsulfenylChloride
Packaging
25mg
Price
$90
Updated
2021/12/16
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Phenylsulfenylchloride Chemical Properties,Usage,Production

Uses

Phenylsulfenyl Chloride is an intermediate used in the synthesis of Tabanone (T003450), which is found in oils of Trifolium pratense L. and is a potential natural anti-oxidant.

Preparation

To a flask containing 32.7 gm (0.15 mole) of diphenyl disulfide dissolved in 100 ml of dichloromethane containing 3 ml of pyridine is slowly dropwise added at room temperature 20.3 gm (0.15 mole) of freshly distilled sulfuryl chloride. After completion of the addition, the solution is stirred for an additional hour, concentrated under reduced pressure (12 mm Hg) at 25°C, and the residue distilled to afford 33 gm (76%), b.p. 49°C (4 mm Hg), of a dark red liquid.

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 1208, 1978 DOI: 10.1021/jo00400a041
Chemical and Pharmaceutical Bulletin, 28, p. 126, 1980 DOI: 10.1248/cpb.28.126

Phenylsulfenylchloride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Phenylsulfenylchloride manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Benzenesulfenyl chloride 931-59-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
Benzenesulfenyl chloride 931-59-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08
Shaanxi Dideu Medichem Co. Ltd
Product
Phenylsulfenylchloride 931-59-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%+
Supply Ability
100 tons
Release date
2020-01-07

931-59-9, PhenylsulfenylchlorideRelated Search:


  • Phenylsulfenylchloride
  • BENZENESULFENYL CHLORIDE
  • BenzeneSulfenic acid chloride
  • Phenylchloro sulfide
  • Phenylthio chloride
  • Phenylsulphenyl chloride
  • phenyl hypochlorothioite
  • (Chlorosulfanyl)benzene
  • Phenyl Thiohypochlorite
  • fenyL
  • (Chlorothio)benzene
  • Benzene, (chlorothio)-
  • Phenylsulfenylchloride ISO 9001:2015 REACH
  • Benzenesulfenyl chloride (6CI, 7CI, 8CI, 9CI, ACI)
  • 931-59-9