ChemicalBook > CAS DataBase List > 4-CYANO-3,5-DIFLUORO BENZALDEHYDE

4-CYANO-3,5-DIFLUORO BENZALDEHYDE

Product Name
4-CYANO-3,5-DIFLUORO BENZALDEHYDE
CAS No.
433939-88-9
Chemical Name
4-CYANO-3,5-DIFLUORO BENZALDEHYDE
Synonyms
2,6-DIFLUORO-4-FORMYLBENZONITRILE;Benzonitrile,2,6-difluoro-4-formyl-;4'-Chloro-2,2,3-trifluoroacetophenone
CBNumber
CB51119287
Molecular Formula
C8H3F2NO
Formula Weight
167.11
MOL File
433939-88-9.mol
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4-CYANO-3,5-DIFLUORO BENZALDEHYDE Property

Melting point:
48-50℃
Boiling point:
263℃
Density 
1.35
Flash point:
113℃
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Appearance
White to yellow Solid
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Safety

HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
D456598
Product name
2,6-difluoro-4-formylbenzonitrile
Packaging
100mg
Price
$60
Updated
2021/12/16
Apolloscientific
Product number
PC201253
Product name
2,6-Difluoro-4-formylbenzonitrile
Purity
98%
Packaging
1g
Price
$83
Updated
2021/12/16
AK Scientific
Product number
W6274
Product name
2,6-Difluoro-4-formylbenzonitrile
Packaging
1g
Price
$131
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD16001
Product name
2,6-Difluoro-4-formylbenzonitrile
Packaging
50mg
Price
$40
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0049733
Product name
2,6-DIFLUORO-4-FORMYLBENZONITRILE
Purity
95.00%
Packaging
1G
Price
$195.41
Updated
2021/12/16
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4-CYANO-3,5-DIFLUORO BENZALDEHYDE Chemical Properties,Usage,Production

Chemical Properties

Light yellow Cryst

Synthesis

479621-01-7

433939-88-9

2,6-Difluoro-4-[(methylsulfinyl)(methylthio)methyl]benzonitrile (2.17 g, 8.32 mmol) was used as a raw material, which was dissolved in 90 mL of tetrahydrofuran (THF), followed by the addition of 3.5 mL of concentrated sulfuric acid. The reaction mixture was stirred at room temperature for 3 days. After completion of the reaction, the mixture was slowly poured into 450 mL of water and extracted three times with ethyl acetate (EtOAc). The organic phases were combined, washed twice sequentially with aqueous sodium bicarbonate and saturated saline, dried over anhydrous sodium sulfate and concentrated under reduced pressure to give the target product 2,6-difluoro-4-formylphenyl cyanide. Yield: 1.36 g (98%). The structure of the product was confirmed by 13C NMR, where the carbon signal at 140.7 ppm showed the expected coupling pattern with two coupling constants of 260 Hz and 6.3 Hz, corresponding to ipso and meso coupling to the fluorine atom.1H NMR (400 MHz, CDCl3) δ 10.35 (s, 1H), 7.33 (m, 2H).

References

[1] Patent: US2004/19033, 2004, A1. Location in patent: Page/Page column 47

4-CYANO-3,5-DIFLUORO BENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-CYANO-3,5-DIFLUORO BENZALDEHYDE Suppliers

ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
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57
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
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64
Beijing Eternalchem Co,. Ltd.
Tel
010-59484199 18611897322
Email
sales@eternalchem.com
Country
China
ProdList
4383
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60
Wuhan Arike Technology Co., Ltd.
Tel
027- 51832457 94518350
Fax
E-Mail Inquiry
Country
China
ProdList
746
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Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
6387
Advantage
52
Wuhan ariel chemical Co., LTD.
Tel
18986259541
Fax
027-87840182
Email
sales@3stc.com
Country
China
ProdList
3764
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58
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12335
Advantage
58
Shanghai Topbiochem Technology Co., Ltd
Tel
+86-21-60341587
Fax
+86-21-61294319
Email
sales@topbiochem.com
Country
China
ProdList
6175
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View Lastest Price from 4-CYANO-3,5-DIFLUORO BENZALDEHYDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
2,6-difluoro-4-formylbenzonitrile 433939-88-9
Price
US $0.00-0.00/KG
Min. Order
10mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-13
Career Henan Chemical Co
Product
4-CYANO-3,5-DIFLUORO BENZALDEHYDE 433939-88-9
Price
US $1.00/g
Min. Order
1g
Purity
98%
Supply Ability
100KG
Release date
2020-01-12

433939-88-9, 4-CYANO-3,5-DIFLUORO BENZALDEHYDE Related Search:


  • 2,6-DIFLUORO-4-FORMYLBENZONITRILE
  • Benzonitrile,2,6-difluoro-4-formyl-
  • 4'-Chloro-2,2,3-trifluoroacetophenone
  • 433939-88-9
  • Nitrile
  • Liquid Crystal intermediates