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2-METHYLPROPYLZINC BROMIDE

Product Name
2-METHYLPROPYLZINC BROMIDE
CAS No.
126403-67-6
Chemical Name
2-METHYLPROPYLZINC BROMIDE
Synonyms
ISOBUTYLZINC BROMIDE;Isobutylzinc(II) bromide;2-METHYLPROPYLZINC BROMIDE;Zinc, bromo(2-methylpropyl)-;isobutylzinc bromide solution;bromozinc(1+),2-methanidylpropane;Isobutylzinc bromide solution 0.5 in THF;2-Methylpropylzinc bromide, 0.5 M in THF;Isobutylzinc broMide solution 0.5 M in THF;Isobutylzinc bromide 0.5 M in THF Cap: 100 ml
CBNumber
CB5112102
Molecular Formula
C4H9BrZn
Formula Weight
202.4
MOL File
126403-67-6.mol
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2-METHYLPROPYLZINC BROMIDE Property

Density 
0.943 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
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Safety

Hazard Codes 
F,Xn
Risk Statements 
14-19-22-36/37/38-40-36/37-14/15-11
Safety Statements 
16-23-26-36-43-36/37
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
HazardClass 
4.3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H318Causes serious eye damage

H319Causes serious eye irritation

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
498963
Product name
Isobutylzinc bromide solution
Purity
0.5 M in THF
Packaging
50ml
Price
$328
Updated
2024/03/01
Rieke Metals
Product number
2038
Product name
2-Methylpropylzincbromide
Packaging
100mL
Price
$394
Updated
2021/12/16
Rieke Metals
Product number
2422
Product name
2-Methylpropylzincbromide
Packaging
100mL
Price
$426
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005695
Product name
2-METHYLPROPYLZINC BROMIDE
Purity
95.00%
Packaging
100ML
Price
$2725.8
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005695
Product name
2-METHYLPROPYLZINC BROMIDE
Purity
95.00%
Packaging
500ML
Price
$5185.95
Updated
2021/12/16
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2-METHYLPROPYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

Isobutylzinc bromide is an organozinc compound, which can be used as a reagent in the palladium-catalyzed Negishi cross-coupling reaction to construct a carbon-carbon bond by reacting with aryl or heteroaryl halides . It is also used to prepare regioselective unsaturated ketones by reacting with tert-butyl isocyanide via an allylic carbonylative coupling reaction in the presence of a nickel catalyst.

2-METHYLPROPYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-METHYLPROPYLZINC BROMIDE Suppliers

SIGMA-RBI
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Country
Switzerland
ProdList
6896
Advantage
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Achemica
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Email
contact@achemica.com
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Switzerland
ProdList
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126403-67-6, 2-METHYLPROPYLZINC BROMIDERelated Search:


  • ISOBUTYLZINC BROMIDE
  • 2-METHYLPROPYLZINC BROMIDE
  • ISOBUTYLZINC BROMIDE, 0.5M SOLUTION IN T ETRAHYDROFURAN
  • isobutylzinc bromide solution
  • Isobutylzinc bromide solution 0.5 in THF
  • Isobutylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
  • Isobutylzinc broMide solution 0.5 M in THF
  • Isobutylzinc broMide, 0.5 M solution in THF, SpcSeal
  • Isobutylzinc(II) bromide
  • Zinc, bromo(2-methylpropyl)-
  • Isobutylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
  • 2-Methylpropylzinc bromide, 0.5 M in THF
  • bromozinc(1+),2-methanidylpropane
  • Isobutylzinc bromide 0.5 M in THF Cap: 100 ml
  • 126403-67-6
  • CH32CHCH2ZnBr
  • Alkyl
  • Organozinc Halides
  • Organometallic Reagents
  • Reike and Organozinc Reagents
  • Chemical Synthesis
  • Organometallic Reagents
  • Organozinc Halides
  • Rieke and Organozinc Reagents
  • Alkyl
  • Organozinc Halides
  • Reike and Organozinc Reagents