ALLYL ANTHRANILATE Property

Melting point:

224-228 °C(lit.)

Boiling point:

105 °C2 mm Hg(lit.)

Density 

1.118 g/mL at 25 °C(lit.)

FEMA 

2020 | ALLYL ANTHRANILATE

refractive index 

n20/D 1.574(lit.)

Flash point:

110 °C

solubility 

Almost insoluble in water. Miscible with alcohol and oils, poorly soluble in Propylene glycol.

pka

2.18±0.10(Predicted)

color 

Colorless or pale yellowish liquid.

Odor

at 100.00 %. green leaf floral grape

Odor Type

floral

JECFA Number

20

LogP

2.87

EPA Substance Registry System

Allyl anthranilate (7493-63-2)

Safety

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

HS Code 

2922498050

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

ALLYL ANTHRANILATE Chemical Properties,Usage,Production

As a flavor ingredient

Identification

  Description: Allyl anthranilate is used as a flavor enhancer and flavoring agent.
  Regulatory Status:
CoE: n/a
FDA: 21 CFR 172.515
FDA (other): n/a
JECFA: ADI: Acceptable. No safety concern at current levels of intake when used as a flavoring agent. (1996).


Reported uses (ppm): (FEMA, 1994)   Natural occurrence: Not reported found in nature.

Chemical Properties

Allyl anthranilate is used as a flavor enhancer and flavoring agent.

Uses

Allyl Anthraniliate is used in the synthesis of diazabicyclo-heptanone compounds mimicking β-lactam antibiotics.

Uses

Allyl Anthranilate is a synthetic flavoring agent that is a light yel- low colored liquid of green leaf-wine odor. it is stable but may cause discoloration. it should be stored in glass or tin containers. it is used as flavoring for its wine note and has application in beverages and candy at 1–2 ppm.

Definition

ChEBI: 2-Propenyl 2-aminobenzoate is a benzoate ester.

General Description

Clear golden liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

The unsaturated aliphatic hydrocarbons are generally much more reactive than the alkanes, which are saturated aliphatic hydrocarbons. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: Toxic; fire hazard.

Fire Hazard

ALLYL ANTHRANILATE is probably combustible.

Synthesis

Allyl Anthraniliate is produced by alcoholysis on lsatoic anhydride and Allyl alcohol, using Sodium methylate catalyst. The cross-esterification method yields a very impure material.