Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4
- Product Name
- Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4
- CAS No.
- 909393-65-3
- Chemical Name
- Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4
- Synonyms
- Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II);Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4;Tetrakis[mu-[(alphaR)-1,3-dihydro-1,3-dioxo-alpha-tricyclo[3.3.1.1(3,7)]dec-1-yl-2H-isoindole-2-acetato]]dirhodium;Rhodium, tetrakis[μ-[(αR)-1,3-dihydro-1,3-dioxo-α-tricyclo[3.3.1.13,7]dec-1-yl-2H-isoindole-2-acetato-κO2:κO2']]di-, (Rh-Rh)
- CBNumber
- CB51181141
- Molecular Formula
- C80H80N4O16Rh2
- Formula Weight
- 1559.34
- MOL File
- 909393-65-3.mol
Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4 Property
- Melting point:
- >300°C
- alpha
- -40.6 (c 0.067, CHCl3)
- form
- Powder
- color
- green
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- 45-2070
- Product name
- Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II) Rh2(R-PTAD)4
- Packaging
- 50mg
- Price
- $95
- Updated
- 2022/04/27
- Product number
- 45-2070
- Product name
- Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II) Rh2(R-PTAD)4
- Packaging
- 250mg
- Price
- $383
- Updated
- 2022/04/27
- Product number
- CM102879
- Product name
- Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
- Purity
- 95%
- Packaging
- 250mg
- Price
- $845
- Updated
- 2021/12/16
- Product number
- A259464
- Product name
- Tetrakis[(R)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
- Purity
- 98%
- Packaging
- 50mg
- Price
- $195
- Updated
- 2021/12/16
- Product number
- CM102879
- Product name
- Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
- Purity
- 95%
- Packaging
- 50mg
- Price
- $212
- Updated
- 2021/12/16
Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4 Chemical Properties,Usage,Production
Uses
This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereo-control.
Reactions
- Enantioselective reactions of carbenoids and olefins.
- Enantioselective C–H insertion reactions of carbenoids.
- Enantioselective oxygen transfer from diazosulfonylamidines.
Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4 Preparation Products And Raw materials
Raw materials
Preparation Products
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