ChemicalBook > CAS DataBase List > Silver carbonate

Silver carbonate

Product Name
Silver carbonate
CAS No.
534-16-7
Chemical Name
Silver carbonate
Synonyms
SILVER(I) CARBONATE;Silver carbonate on celite;Silver(II) carbonate;Silver Carbonate on Celite (~40 wt. % loading);99.50%;ver carbonate;Silvecarbonate;SILVER CARBONATE;Silvcr Carbonate;disilvercarbonate
CBNumber
CB5118836
Molecular Formula
CAg2O3
Formula Weight
275.75
MOL File
534-16-7.mol
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Silver carbonate Property

Melting point:
210 °C (dec.) (lit.)
Density 
6.08 g/mL at 25 °C (lit.)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Aqueous Acid (Slightly), Aqueous Base (Slightly)
form 
Granular Powder
color 
Green-yellow to greenish
Specific Gravity
6.08
Water Solubility 
insoluble(3.489×10-3/100ml/20℃)
Sensitive 
Light Sensitive
Merck 
14,8507
BRN 
6936654
Solubility Product Constant (Ksp)
pKsp: 11.07
Stability:
Stability Stable, but light sensitive. Incompatible with reducing agents, acids.
InChIKey
KQTXIZHBFFWWFW-UHFFFAOYSA-L
CAS DataBase Reference
534-16-7(CAS DataBase Reference)
NIST Chemistry Reference
silver carbonate(534-16-7)
EPA Substance Registry System
Silver(I) carbonate (534-16-7)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38-20
Safety Statements 
26-37/39-36
WGK Germany 
3
RTECS 
FG0700000
F 
8
TSCA 
Yes
HazardClass 
9
HS Code 
28432900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
179647
Product name
Silver carbonate
Purity
99%
Packaging
5g
Price
$43.4
Updated
2024/03/01
Sigma-Aldrich
Product number
179647
Product name
Silver carbonate
Purity
99%
Packaging
25g
Price
$138
Updated
2024/03/01
Alfa Aesar
Product number
011420
Product name
Silver carbonate, 99.5% (metals basis)
Packaging
25g
Price
$127
Updated
2024/03/01
Alfa Aesar
Product number
011420
Product name
Silver carbonate, 99.5% (metals basis)
Packaging
100g
Price
$342
Updated
2023/06/20
Strem Chemicals
Product number
93-4706
Product name
Silver carbonate (99+%-Ag)
Packaging
10g
Price
$78
Updated
2024/03/01
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Silver carbonate Chemical Properties,Usage,Production

Chemical Properties

Silver carbonate (chemical formula: Ag2CO3) is a light yellow or yellow-green powder, slightly soluble in water, and easily turns dark purple or dark gray under long-term light. After heating, it will decompose to produce silver oxide, which is used to prepare other silver compounds.

Uses

Silver carbonate is a mild oxidizing agent for conversion of alcohols to aldehydes and ketones. It is also used as Biological stain and Koenigs-Knorr glycosylation.

Application

Silver Carbonate on Celite is a reagent used in the synthesis of 3-Oxo-12a-hydroxy-5β-cholanoic Acid which is a keto bile acid derivative.

Preparation

Silver carbonate is prepared by the reaction of sodium carbonate and silver nitrate.
Reaction: Dissolve 53g of sodium carbonate in 600ml of water and slowly add it to a solution of 172g of silver nitrate dissolved in 2L of water (10min). Silver nitrate is in a slight excess. The reaction mixture was vigorously stirred with a mechanical stirrer, and the silver carbonate was filtered off, washed with a small amount of acetone to facilitate drying, and then air-dried. All operations must be carried out in a dark room.

Reactions

Silver carbonate is not a powerful oxidizing agent but it is useful in Organic chemistry. Rapoport et al. were probably the first to use silver carbonate for the oxidation of alcohols to carbonyl derivatives. Rapoport refluxed codeine with silver carbonate in benzene and obtained a 75% yield of codeinone. In later work King et al. oxidized codeine with silver carbonate in refluxing toluene or xylene and obtained an 85% yield of codeinone with a much shorter reaction time.

General Description

Odorless yellow to brown solid. Sinks in water.

Reactivity Profile

Silver carbonate is a carbonates salt that has weak oxidizing or reducing powers. It is decomposed by acids with the evolution of carbon dioxide.

Health Hazard

Contact with eyes causes irritation. If continued for a long period, ingestion or inhalation of silver compounds can cause permanent discoloration of the skin (argyria).

Fire Hazard

Behavior in Fire: Decomposes to silver oxide, silver, and carbon dioxide; the reaction is not hazardous.

Silver carbonate Preparation Products And Raw materials

Raw materials

Silver Sodium carbonate

Preparation Products

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Silver carbonate Suppliers

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View Lastest Price from Silver carbonate manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
Silver carbonate 534-16-7
Price
US $10.00/PCS
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2021-03-30
Hebei Longbang Technology Co., Ltd
Product
Silver carbonate 534-16-7
Price
US $5.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-05-11
Hebei Saisier Technology Co., LTD
Product
Silver carbonate 534-16-7
Price
US $6.00/KG
Min. Order
1KG
Purity
More than 99%
Supply Ability
2000KG/Month
Release date
2024-04-02

534-16-7, Silver carbonateRelated Search:

Dimethyl carbonate Sodium carbonate Sodium bicarbonate Polycarbonate Ethylene carbonate Silver Calcium carbonate Lithium carbonate Ammonium bicarbonate Silver chloride potassium ferricyanide Lead tetraacetate SILVER NITRITE Silver sulfate Rubidium carbonate Cesium carbonate Cerium(III) carbonate hydrate Zinc carbonate

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