6-Methyl-2-mercaptobenzothiazole
- Product Name
- 6-Methyl-2-mercaptobenzothiazole
- CAS No.
- 2268-79-3
- Chemical Name
- 6-Methyl-2-mercaptobenzothiazole
- Synonyms
- 6-Methyl-2-benzothiazolethiol;2-Mercapto-6-methylbenzothiazole;6-Methylbenzo[d]thiazole-2-thiol;6-Methyl-2-mercaptobenzothiazole;6-Methyl-2(3H)-benzothiazolethione;2(3H)-Benzothiazolethione, 6-methyl-;6-methyl-3H-1,3-benzothiazole-2-thione;2(3H)-Benzothiazolethione,6-methyl-(9CI)
- CBNumber
- CB51272528
- Molecular Formula
- C8H7NS2
- Formula Weight
- 181.28
- MOL File
- 2268-79-3.mol
6-Methyl-2-mercaptobenzothiazole Property
- Melting point:
- 183 °C
- Boiling point:
- 323 °C
- Density
- 1.39
- Flash point:
- 149 °C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 9.92±0.20(Predicted)
- Appearance
- White to off-white Solid
Safety
- HS Code
- 2934208090
N-Bromosuccinimide Price
- Product number
- CS-0061342
- Product name
- 6-Methylbenzo[d]thiazole-2-thiol
- Purity
- 97.93%
- Packaging
- 1g
- Price
- $122
- Updated
- 2021/12/16
- Product number
- OR958424
- Product name
- 6-Methyl-2-mercaptobenzothiazole
- Purity
- 95%
- Packaging
- 250mg
- Price
- $140
- Updated
- 2021/12/16
- Product number
- 7H70-1-13
- Product name
- 6-Methyl-2,3-dihydro-1,3-benzothiazole-2-thione
- Packaging
- 250mg
- Price
- $224
- Updated
- 2021/12/16
- Product number
- OR958424
- Product name
- 6-Methyl-2-mercaptobenzothiazole
- Purity
- 95%
- Packaging
- 1g
- Price
- $335
- Updated
- 2021/12/16
- Product number
- CS-0061342
- Product name
- 6-Methylbenzo[d]thiazole-2-thiol
- Purity
- 97.93%
- Packaging
- 5g
- Price
- $370
- Updated
- 2021/12/16
6-Methyl-2-mercaptobenzothiazole Chemical Properties,Usage,Production
Synthesis
75-15-0
29289-13-2
2268-79-3
2-Iodo-4-methylaniline (2 mmol), carbon disulfide (10 mmol), sodium sulfide (4 mmol), and N,N-dimethylformamide (2 mL) were added to a 50 mL sealed tube at room temperature and protected by argon and sealed by three times of argon displacement. The reaction mixture was stirred electromagnetically at 110 °C for 12 h. The reaction progress was monitored by thin layer chromatography (TLC) on silica gel plates. After completion of the reaction, the mixture was cooled to room temperature, 3 mol/L hydrochloric acid (2 mL) was added and stirred for 30 min. Subsequently, the reaction mixture was extracted with dichloromethane (3 x 20 mL). The organic phases were combined, dried with anhydrous magnesium sulfate and concentrated. The residue was purified by silica gel column chromatography with the eluent being a mixed petroleum ether/ethyl acetate solvent to afford the target product 6-methylbenzo[d]thiazole-2-thiol.
References
[1] Synthetic Communications, 2017, vol. 47, # 20, p. 1916 - 1925
[2] Organic Letters, 2011, vol. 13, # 12, p. 3202 - 3205
[3] Patent: CN104098529, 2016, B. Location in patent: Paragraph 0047-0048
6-Methyl-2-mercaptobenzothiazole Preparation Products And Raw materials
Raw materials
Preparation Products
6-Methyl-2-mercaptobenzothiazole Suppliers
- Tel
- --
- Fax
- --
- Marketing@canchemia.com
- Country
- Canada
- ProdList
- 171
- Advantage
- 42
View Lastest Price from 6-Methyl-2-mercaptobenzothiazole manufacturers
- Product
- 6-methyl-3H-1,3-benzothiazole-2-thione 2268-79-3
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.7%
- Supply Ability
- 100 tons
- Release date
- 2022-01-14