9-(bromomethyl)anthracene
- Product Name
- 9-(bromomethyl)anthracene
- CAS No.
- 2417-77-8
- Chemical Name
- 9-(bromomethyl)anthracene
- Synonyms
- ICR-506;9-Anthrylmethyl bromide;9-(bromomethyl)anthracene;Anthracene, 9-(broMoMethyl)-
- CBNumber
- CB51458850
- Molecular Formula
- C15H11Br
- Formula Weight
- 271.15
- MOL File
- 2417-77-8.mol
9-(bromomethyl)anthracene Property
- Melting point:
- 143-146℃
- Boiling point:
- 320.83°C (rough estimate)
- Density
- 1.448
- refractive index
- 1.6822 (estimate)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- powder
- color
- Yellow
- InChI
- InChI=1S/C15H11Br/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9H,10H2
- InChIKey
- KOWKPLCVFRHICH-UHFFFAOYSA-N
- SMILES
- C1=C2C(C=C3C(=C2CBr)C=CC=C3)=CC=C1
Safety
- RIDADR
- UN3261
- HazardClass
- 8
- HS Code
- 2903998090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H318Causes serious eye damage
H400Very toxic to aquatic life
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P310Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- B6565
- Product name
- 9-(Bromomethyl)anthracene
- Packaging
- 1G
- Price
- $66
- Updated
- 2025/07/31
- Product number
- B6565
- Product name
- 9-(Bromomethyl)anthracene
- Packaging
- 5G
- Price
- $198
- Updated
- 2025/07/31
- Product number
- 1700-9-39
- Product name
- 9-(Bromomethyl)anthracene
- Packaging
- 1g
- Price
- $240
- Updated
- 2021/12/16
- Product number
- 094817
- Product name
- 9-(Bromomethyl)anthracene
- Purity
- 95+%
- Packaging
- 1g
- Price
- $260
- Updated
- 2021/12/16
- Product number
- 1755AB
- Product name
- 9-(Bromomethyl)anthracene
- Packaging
- 25mg
- Price
- $20
- Updated
- 2021/12/16
9-(bromomethyl)anthracene Chemical Properties,Usage,Production
Synthesis
1468-95-7
2417-77-8
General procedure for the synthesis of 9-(bromomethyl)anthracene from 9-anthracenemethanol: To a stirred suspension of 9-anthracenemethanol (2.0 g, 9.6 mmol) in toluene (100 ml) at 0 °C was added dropwise phosphorus tribromide (PBr3, 1.2 mL, 12.51 mmol), and the reaction system was kept stirred at 0 °C for 1 hour. Subsequently, the reaction mixture was slowly warmed up to room temperature and stirring was continued for 1 h. It was observed that the mixture transformed into a yellow solution. Upon completion of the reaction, the reaction was quenched by the addition of aqueous potassium carbonate solution (10 mL). The toluene solvent was removed by rotary evaporator under reduced pressure. The residue was dissolved in ethyl acetate (EtOAc), and the organic phase was washed sequentially with saturated aqueous potassium carbonate solution, deionized water and saturated saline, and dried over anhydrous magnesium sulfate. After filtration, the organic phase was concentrated under reduced pressure, and the resulting crude product was purified by fast column chromatography with the eluent of petroleum ether: ethyl acetate (2:1, v/v), which finally afforded the target compound 9-(bromomethyl)anthracene (47, 1.4 g, 54% yield) as a yellow solid. The product was characterized by 1H NMR (500 MHz, CDCl3): δ= 8.45 (1H, s, Ar-10H), 8.27 (2H, d, J=8.0 Hz, Ar-1,8H), 8.00 (2H, d, J=8.0 Hz, Ar-4,5H), 7.62 (2H, t, J=7.5 Hz, Ar-2,7H), 7.48 (2H, t, J=7.5Hz, Ar-3,6H), 5.50 (2H, s, CH2Br).
References
[1] Tetrahedron, 2005, vol. 61, # 23, p. 5699 - 5704
[2] RSC Advances, 2016, vol. 6, # 5, p. 3783 - 3791
[3] Journal of Organic Chemistry, 2003, vol. 68, # 25, p. 9678 - 9686
[4] Bioorganic and Medicinal Chemistry, 2009, vol. 17, # 18, p. 6496 - 6504
[5] Angewandte Chemie - International Edition, 2016, vol. 55, # 8, p. 2719 - 2723
9-(bromomethyl)anthracene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 9-(bromomethyl)anthracene manufacturers
- Product
- 9-(bromomethyl)anthracene 2417-77-8
- Price
- US $3.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-16
- Product
- 9-(bromomethyl)anthracene 2417-77-8
- Price
- US $0.01/KG
- Min. Order
- 1KG
- Purity
- 98%; 99%
- Supply Ability
- 1kg；10kg; 25kg
- Release date
- 2020-01-07