ChemicalBook > CAS DataBase List > 3-BROMO-4-HYDROXYPHENYLACETIC ACID

3-BROMO-4-HYDROXYPHENYLACETIC ACID

Product Name
3-BROMO-4-HYDROXYPHENYLACETIC ACID
CAS No.
38692-80-7
Chemical Name
3-BROMO-4-HYDROXYPHENYLACETIC ACID
Synonyms
3-Bromo-4-hydroxyphenyl;3-BROMO-4-HYDROXYPHENYLACETIC ACID;3-BROMO-4-HYDROXYBENZENEACETIC ACID;Benzeneacetic acid, 3-bromo-4-hydroxy-;2-(3-bromo-4-hydroxyphenyl)acetic acid
CBNumber
CB5147520
Molecular Formula
C8H7BrO3
Formula Weight
231.04
MOL File
38692-80-7.mol
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3-BROMO-4-HYDROXYPHENYLACETIC ACID Property

Melting point:
105-107℃
Boiling point:
364℃
Density 
1.757
Flash point:
174℃
storage temp. 
Sealed in dry,Room Temperature
pka
4.33±0.10(Predicted)
CAS DataBase Reference
38692-80-7(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
22
HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B677920
Product name
3-Bromo-4-HydroxyphenylaceticAcid
Packaging
100mg
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
024747
Product name
3-Bromo-4-hydroxyphenylacetic acid
Purity
98%
Packaging
5g
Price
$15
Updated
2021/12/16
Oakwood
Product number
024228
Product name
3-Bromo-4-hydroxyphenylaceticacid
Purity
97%
Packaging
5g
Price
$40
Updated
2021/12/16
Matrix Scientific
Product number
024747
Product name
3-Bromo-4-hydroxyphenylacetic acid
Purity
98%
Packaging
25g
Price
$54
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB52439
Product name
3-Bromo-4-hydroxyphenylacetic acid
Packaging
25g
Price
$79
Updated
2021/12/16
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3-BROMO-4-HYDROXYPHENYLACETIC ACID Chemical Properties,Usage,Production

Synthesis

774-81-2

38692-80-7

Step (b) 3-bromo-4-methoxyphenylacetic acid (14.0 g, 0.057 mol) and anhydrous dichloromethane (100 mL) were added to a 250 mL round bottom flask. The reaction mixture was degassed by nitrogen bubbling for 5 min. Subsequently, a dichloromethane solution of 1 M boron tribromide (63 mL, 0.063 mol) was added slowly and dropwise through the addition funnel. The reaction mixture was stirred at room temperature and a white solid was observed to precipitate gradually. After the reaction was carried out for 2 h, the product was separated by filtration and the collected white crystals were washed several times with dichloromethane to finally obtain 3-bromo-4-hydroxyphenylacetic acid (12 g, 92% yield).

References

[1] Patent: US2003/114457, 2003, A1
[2] Patent: WO2004/62661, 2004, A1. Location in patent: Page/Page column 28
[3] Patent: US2009/197959, 2009, A1. Location in patent: Page/Page column 14; 15

3-BROMO-4-HYDROXYPHENYLACETIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-4-HYDROXYPHENYLACETIC ACID Suppliers

Carbosynth
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View Lastest Price from 3-BROMO-4-HYDROXYPHENYLACETIC ACID manufacturers

Career Henan Chemical Co
Product
3-BROMO-4-HYDROXYPHENYLACETIC ACID 38692-80-7
Price
US $6.60/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-02