ChemicalBook > CAS DataBase List > 4-TETRAZOL-1-YL-PHENOL

4-TETRAZOL-1-YL-PHENOL

Product Name
4-TETRAZOL-1-YL-PHENOL
CAS No.
64001-11-2
Chemical Name
4-TETRAZOL-1-YL-PHENOL
Synonyms
4-(1H-Tetrazol-1-yl);Phenol, 4-(1-tetrazolyl)-;Phenol, 4-(1H-tetrazol-1-yl)-;4-Tetrazol-1-yl-phenol, 97%min;4-(1H-1,2,3,4-tetrazol-1-yl)phenol;4-(1H-tetrazol-1-yl)phenol(SALTDATA: FREE)
CBNumber
CB51491787
Molecular Formula
C7H6N4O
Formula Weight
162.15
MOL File
64001-11-2.mol
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4-TETRAZOL-1-YL-PHENOL Property

Boiling point:
370.2±44.0 °C(Predicted)
Density 
1.46±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
8.68±0.13(Predicted)
Appearance
white solid
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Safety

HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H341Suspected of causing genetic defects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P281Use personal protective equipment as required.

P308+P313IF exposed or concerned: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

AK Scientific
Product number
X7159
Product name
4-Tetrazol-1-yl-phenol
Packaging
1g
Price
$151
Updated
2021/12/16
Matrix Scientific
Product number
057718
Product name
4-Tetrazol-1-yl-phenol
Purity
95%
Packaging
1g
Price
$174
Updated
2021/12/16
Matrix Scientific
Product number
057718
Product name
4-Tetrazol-1-yl-phenol
Purity
95%
Packaging
5g
Price
$478
Updated
2021/12/16
Ambeed
Product number
A237175
Product name
4-(1H-Tetrazol-1-yl)phenol
Purity
95+%
Packaging
100mg
Price
$7
Updated
2021/12/16
Ambeed
Product number
A237175
Product name
4-(1H-Tetrazol-1-yl)phenol
Purity
95+%
Packaging
250mg
Price
$9
Updated
2021/12/16
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4-TETRAZOL-1-YL-PHENOL Chemical Properties,Usage,Production

Synthesis

123-30-8

122-51-0

64001-11-2

GENERAL METHODS: Fe3O4WO3-EAE-SO3H(III) (0.01 g) was added to a solution in water (5 mL) containing 4-aminophenol (0.093 g, 1.0 mmol), triethyl orthoformate (0.177 g, 1.2 mmol) and 1-butyl-3-methylimidazolium azide (0.216 g, 1.2 mmol). The reaction mixture was magnetically stirred at 60 °C for 30 min. Upon completion of the reaction (monitored by TLC), the mixture was cooled to room temperature and the catalyst was separated with an external magnet. The resulting solution was extracted with EtOAc (3 x 15 mL). The organic layers were combined, washed with brine, dried over anhydrous Na2SO4 and concentrated under reduced pressure. The crude product was recrystallized with ethyl acetate/hexane (1/9 v/v) to give pure 4-tetrazol-1-ylphenol (1.48 g, 95% yield). The recovered catalyst was washed with hot ethyl acetate and dried at 60 °C for 2 h for subsequent recycling.

References

[1] Journal of the Iranian Chemical Society, 2014, vol. 11, # 1, p. 91 - 99
[2] Bulletin of the Chemical Society of Japan, 2017, vol. 90, # 10, p. 1119 - 1128
[3] Patent: US2012/53180, 2012, A1. Location in patent: Page/Page column 13

4-TETRAZOL-1-YL-PHENOL Preparation Products And Raw materials

Raw materials

Preparation Products

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4-TETRAZOL-1-YL-PHENOL Suppliers

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