ChemicalBook > CAS DataBase List > Tris(1,3-dichloro-2-propyl)phosphate

Tris(1,3-dichloro-2-propyl)phosphate

Product Name
Tris(1,3-dichloro-2-propyl)phosphate
CAS No.
13674-87-8
Chemical Name
Tris(1,3-dichloro-2-propyl)phosphate
Synonyms
TDCPP;tdcp;TRIS(1,3-DICHLORO-2-PROPYL) PHOSPHATE;TRIS(1,3-DICHLOROISOPROPYL)PHOSPHATE;tris(1,3-dichloropropan-2-yl) phosphate;pf 38;pf38/3;Fyrol FR 2;Fyrol FR-2R;emulsion212
CBNumber
CB5194948
Molecular Formula
C9H15Cl6O4P
Formula Weight
430.9
MOL File
13674-87-8.mol
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Tris(1,3-dichloro-2-propyl)phosphate Property

Melting point:
-64°C
Boiling point:
315°C
Density 
1.512
vapor pressure 
0Pa at 25℃
refractive index 
n20/D 1.503
Flash point:
249°C
storage temp. 
Store at -20°C
solubility 
Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form 
solid
Specific Gravity
1.518 (20/4℃)
color 
Colorless to Almost colorless
Water Solubility 
<0.1 g/100 mL at 24 ºC
Decomposition 
240-280 ºC
Merck 
14,9087
Stability:
Stable. Reacts slowly with aqueous acids and alkalies. May soften plastics.
InChIKey
ASLWPAWFJZFCKF-UHFFFAOYSA-N
LogP
3.69 at 20℃
CAS DataBase Reference
13674-87-8(CAS DataBase Reference)
NIST Chemistry Reference
Tris(1,3-dichloroisopropyl)phosphate(13674-87-8)
EPA Substance Registry System
Tris(1,3-dichloro-2-propyl)phosphate (13674-87-8)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
20/21/22-36/37/38-51/53-38-20-40
Safety Statements 
26-36/37/39-61-36/37
RIDADR 
UN 3082 9/PG 3
WGK Germany 
2
RTECS 
UB1473000
HazardClass 
9
PackingGroup 
III
HS Code 
29199000
Hazardous Substances Data
13674-87-8(Hazardous Substances Data)
Toxicity
LD50 orally in rats: 1.85 g/kg (Piotrowski)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H351Suspected of causing cancer

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

P391Collect spillage. Hazardous to the aquatic environment

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
32951
Product name
TDCPP
Purity
analytical standard
Packaging
100mg
Price
$229
Updated
2024/03/01
TCI Chemical
Product number
P0269
Product name
Tris(1,3-dichloro-2-propyl) Phosphate
Purity
>95.0%(GC)
Packaging
25g
Price
$43
Updated
2024/03/01
TCI Chemical
Product number
P0269
Product name
Tris(1,3-dichloro-2-propyl) Phosphate
Purity
>95.0%(GC)
Packaging
500g
Price
$152
Updated
2024/03/01
TRC
Product number
T876305
Product name
Tris(1,3-dichloro-2-propyl) Phosphate
Packaging
50g
Price
$230
Updated
2021/12/16
AK Scientific
Product number
I991
Product name
Tris(1,3-dichloro-2-propyl) Phosphate
Packaging
5g
Price
$18
Updated
2021/12/16
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Tris(1,3-dichloro-2-propyl)phosphate Chemical Properties,Usage,Production

Chemical Properties

Tris(1,3-dichloro-2-propyl)phosphate is a clear colorless viscous liquid with a relatively low molecular weight, low water solubility, and low lipophilicity (as indicated by log Kow).

Uses

Tris(1,3-dichloro-2-propyl) Phosphate is a flame retardant present in polyurethane foams.

Uses

Tris(1,3-dichloro-2-propyl)phosphate [TDCPP] is a halogenated phosphorus flame retardant used in a variety of sectors, including manufacturing of paints/coatings, furniture and related products, building/construction materials, fabrics/textiles/leather products, and foam seating and bedding products (EPA, 2012).
It is used extensively as an additive to flexible polyurethane foams (PUFs). Its end uses include molded automotive seating foam (e.g., seat cushions and headrests), slabstock foam in furniture, automotive fabric lining, and car roofing (ECHA, 2013). It is a high production volume chemical.

Definition

ChEBI: Tris(1,3-dichloropropan-2-yl) phosphate is a trialkyl phosphate.

General Description

Clear colorless viscous liquid. Generally a super-cooled liquid at room temperature but may occasionally solidify when held at low temperatures for prolonged periods.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Fyrol FR 2 hydrolyzes slowly when refluxed with an aqueous acid. Under alkaline conditions, Fyrol FR 2 exhibits a slow cleavage. Fyrol FR 2 has plasticizing properties and, as such, may soften or deteriorate certain plastics and elastomers (particularly vinyl-based resin, neoprene and natural rubbers).

Fire Hazard

Fyrol FR 2 is combustible.

Safety Profile

Moderately toxic by ingestion. An experimental teratogen. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of Cland POx.

Environmental Fate

A series of studies have been performed to evaluate the environmental fate and bioaccumulation potential of Tris(1,3-dichloro-2-propyl)phosphate (TDCPP).EU concluded that TDCPP is expected to be persistent in water, sediment, sewage sludge, and soil. When emitted to the environment, the EU concluded that TDCPP will likely adsorb to particulate matter, based on its low volatility and relatively high adsorption coefficient. The Henry’s law constant suggests that TDCPP will preferentially partition to water, rather than air. When assessing TDCPP's potential for persistence or bioaccumulation, the EU determined that TDCPP can potentially be persistent or very persistent and that it does not meet the criteria for bioaccumulative or very bioaccumulative compounds.

Tris(1,3-dichloro-2-propyl)phosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(1,3-dichloro-2-propyl)phosphate Suppliers

Americas 1 Canada 2 China 218 Europe 4 France 1 Germany 4 India 3 Italy 1 Japan 5 Slovakia 1 South Korea 2 Switzerland 1 The Netherlands 1 United Kingdom 8 United States 22 Global 274
HPC Standards GmbH
Tel
--
Fax
--
Email
chulze@hpc-standards.com
Country
Germany
ProdList
2139
Advantage
58
Dr. Ehrenstorfer GmbH
Tel
--
Fax
--
Email
info@analytical-standards.com
Country
Germany
ProdList
5545
Advantage
66
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
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View Lastest Price from Tris(1,3-dichloro-2-propyl)phosphate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Tdpp Tris (1, 3-Dichloro-2-Propyl) Phosphate 13674-87-8
Price
US $65.00-20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-31
Hebei Weibang Biotechnology Co., Ltd
Product
TCPP 13674-87-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-06-10
Henan Fengda Chemical Co., Ltd
Product
Tris(1,3-dichloro-2-propyl)phosphate 13674-87-8
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-23

13674-87-8, Tris(1,3-dichloro-2-propyl)phosphateRelated Search:

Tris(1-Chloro-2-Propyl) Phosphate Tris(2-chloroethyl) phosphate Tris(1,3-dichloropropyl) phosphate Ethyl thiooxamate Triethyl phosphate Trisodium phosphate Diphenyl isopropylphenyl phosphate Trimethyl phosphonoacetate TRI-(P-TERT-BUTYLPHENYL) PHOSPHATE Tris(2-butoxyethyl) phosphate Trixylyl phosphate Tris(1,3-dichloro-2-propyl)phosphate Diisopropyl phosphite 1,3-DICHLORO-2-PROPANOL TDCPP fire retardant 1,3-Dichloro-2-propanol 1,3-Dichloropropane ETHYL PHOSPHATE

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