(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS

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Product Name: (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
CAS No.: 850444-36-9
Chemical Name: (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
Synonyms: 97% TANIAPHOS;(SP)-1-[(S)-aL;(S,Sp)-Taniaphos;(2R)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(2Sp)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(SP)-1-[(S)-alpha-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane;(S)-1-Diphenylphosphino-2-[(S)-(N,N-dimethylamino) [2-(diphenylphosphino)phenyl]methyl]ferrocene;(S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene
CBNumber: CB52129553
Molecular Formula: C38H34NP2.C5H5.Fe
Formula Weight: 687.581
MOL File: 850444-36-9.mol

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(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Property

alpha: -312° ±15° (c 0.5, CHCl3)
storage temp.: 2-8°C
form: Powder
color: orange
Stability:: store cold

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Safety

WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 73476
Product name: (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
Purity: ≥97%, optical purity ee: ≥99%
Packaging: 1g
Price: $730
Updated: 2024/03/01

Sigma-Aldrich

Product number: 73476
Product name: (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
Purity: ≥97%, optical purity ee: ≥99%
Packaging: 5g
Price: $3370
Updated: 2024/03/01

Strem Chemicals

Product number: 26-1155
Product name: (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
Packaging: 100mg
Price: $96
Updated: 2024/03/01

Strem Chemicals

Product number: 26-1155
Product name: (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
Packaging: 500mg
Price: $355
Updated: 2024/03/01

Sigma-Aldrich

Product number: 73476
Product name: (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
Purity: ≥97%, optical purity ee: ≥99%
Packaging: 100mg
Price: $92.8
Updated: 2024/03/01

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(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Chemical Properties,Usage,Production

Reactions

Ligand for the Ru-catalyzed hydrogenation of $-ketoesters, enamides and itaconates.
Ligand for Cu-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones.
AgOAc-catalyzed asymmetric amination of glycine Schiff bases with azodicarboxylates.

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Suppliers

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850444-36-9, (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOSRelated Search:

(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-<br />diphenylphosphinophenyl)methane, min. 97% TANIAPHOS

(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane

97% TANIAPHOS

(S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene

(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-diMethylaMino) (2-diphenylphosphinophenyl)Methane TANIAPHOS

(SP)-1-[(S)-alpha-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene >=97%, optical purity ee: >=99%

Taniaphos SL-T001-2, (2R)-1-[(S)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS)

(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS

(SP)-1-[(S)-alpha-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene

(SP)-1-[(S)-aL

(2R)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene

(SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene

(S)-1-Diphenylphosphino-2-[(S)-(N,N-dimethylamino) [2-(diphenylphosphino)phenyl]methyl]ferrocene

(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS ISO 9001：2015 REACH

(S,Sp)-Taniaphos

(2Sp)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene

850444-36-9

Chiral Phosphine

Ferrocene Series

Taniaphos Series

metallocene