2,4,6-TRI-TERT-BUTYLANILINE
- Product Name
- 2,4,6-TRI-TERT-BUTYLANILINE
- CAS No.
- 961-38-6
- Chemical Name
- 2,4,6-TRI-TERT-BUTYLANILINE
- Synonyms
- AKOS BC-0696;TIMTEC-BB SBB000998;2,4,6-Tri-tert-butyL;2,4,6-tri-t-Butylaniline;Aniline, tri-tert-butyl-;2,4,6-T-tert-butylaniline;2,4,6-TRI-TERT-BUTYLANILINE;2,4,6-Tris(tert-butyl)aniline;Aniline, 2,4,6-tri-tert-butyl-;2,4,6-Tri-tert-butylaniline,95%
- CBNumber
- CB5228207
- Molecular Formula
- C18H31N
- Formula Weight
- 261.45
- MOL File
- 961-38-6.mol
2,4,6-TRI-TERT-BUTYLANILINE Property
- Melting point:
- 145-147 °C(lit.)
- Boiling point:
- 302.0±21.0 °C(Predicted)
- Density
- 0.896±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- powder to crystal
- pka
- 3.30±0.10(Predicted)
- color
- White to Light yellow
- Water Solubility
- Insoluble in water.
- Sensitive
- Light Sensitive
- BRN
- 2272612
- InChI
- InChI=1S/C18H31N/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11H,19H2,1-9H3
- InChIKey
- REJGDSCBQPJPQT-UHFFFAOYSA-N
- SMILES
- C1(N)=C(C(C)(C)C)C=C(C(C)(C)C)C=C1C(C)(C)C
- CAS DataBase Reference
- 961-38-6(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 223050
- Product name
- 2,4,6-Tri-tert-butylaniline
- Purity
- 99%
- Packaging
- 1g
- Price
- $31.5
- Updated
- 2025/07/31
- Product number
- 223050
- Product name
- 2,4,6-Tri-tert-butylaniline
- Purity
- 99%
- Packaging
- 5g
- Price
- $214
- Updated
- 2025/07/31
- Product number
- T1694
- Product name
- 2,4,6-Tri-tert-butylaniline
- Purity
- >98.0%(GC)(T)
- Packaging
- 1g
- Price
- $43
- Updated
- 2025/07/31
- Product number
- T1694
- Product name
- 2,4,6-Tri-tert-butylaniline
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $121
- Updated
- 2025/07/31
- Product number
- CHM0019492
- Product name
- 2,4,6-TRI(TERT-BUTYL)ANILINE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $970.2
- Updated
- 2021/12/16
2,4,6-TRI-TERT-BUTYLANILINE Chemical Properties,Usage,Production
Chemical Properties
White to off-white powder
Uses
2,4,6-Tri-tert-butylnitrobenzene (bulky amine) is used in the synthesis of monomeric iminophosphorane
Uses
2,4,6-Tri-tert-butylnitrobenzene (bulky amine) was used in the synthesis of monomeric iminophosphorane.
Definition
ChEBI: 2,4,6-tri-tert-butylaniline is an alkylbenzene.
Synthesis
4074-25-3
961-38-6
The general procedure for the synthesis of 2,4,6-tri-tert-butylaniline from 2,4,6-tri-tert-butylnitrobenzene was as follows: in a 4 mL glass reaction flask equipped with a septum cap and a magnetic stirring bar, Co-Co3O4Chit-700 catalyst (10 mg, 3.4 mol/kg Co), nitroaromatic hydrocarbons (0.5 mmol, 1.0 equiv), triethylamine ( 35 μL, 0.25 mmol, 0.5 equiv), and EtOH/H2O (3:1, 2 mL) mixed solvent. The reaction vial was placed in a 300 mL autoclave and pressurized to 40 bar after five displacements with hydrogen. The reaction mixture was stirred at 110 °C until the reaction was complete. At the end of the reaction, it was cooled to room temperature and the pressure in the autoclave was slowly released. The crude reaction mixture was filtered through a cotton fitted pipette and the filtrate was concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: ethyl acetate), and pure 2,4,6-tri-tert-butylaniline derivatives were obtained after removing the solvent under reduced pressure. Using the catalyst of the present invention, efficient preparation of the target aniline derivatives from the corresponding nitroaromatics can be realized.
References
[1] ChemSusChem, 2017, vol. 10, # 15, p. 3035 - 3039
[2] Patent: WO2018/114777, 2018, A1. Location in patent: Page/Page column 31-32
[3] Journal of the American Chemical Society, 1991, vol. 113, # 22, p. 8437 - 8443
[4] Journal of the American Chemical Society, 1982, vol. 104, # 25, p. 7191 - 7195
[5] Chemistry - A European Journal, 2017, vol. 23, # 59, p. 14738 - 14742
2,4,6-TRI-TERT-BUTYLANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,4,6-TRI-TERT-BUTYLANILINE manufacturers
- Product
- 2,4,6-TRI-TERT-BUTYLANILINE 961-38-6
- Price
- US $8.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10MT
- Release date
- 2018-12-17