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Samarium trifluoride

Uses
Product Name
Samarium trifluoride
CAS No.
13765-24-7
Chemical Name
Samarium trifluoride
Synonyms
SAMARIUM FLUORIDE;samarium trifluoride;Samarium(ll)Fluoride;Samarium(Ⅲ) Fluoride;samariumfluoride(smf3);SAMARIUM(III) FLUORIDE;SAMARIUM FLUORIDE 99+%;SAMARIUM FLUORIDE, 99.9%;Samarium fluoride, 99.90%;Samarium(III) trifluoride
CBNumber
CB5236448
Molecular Formula
F3Sm
Formula Weight
207.36
MOL File
13765-24-7.mol
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Samarium trifluoride Property

Melting point:
1306 °C
Boiling point:
2323 °C
Density 
6,928 g/cm3
solubility 
reacts with H2O
form 
Fine Crystalline Powder
Specific Gravity
6.928
color 
Slightly yellow
Water Solubility 
Soluble moderately in strong mineral acids. Insoluble in water.
Sensitive 
Hygroscopic
Crystal Structure
YF3 type
crystal system
Nogata
Space group
Pnma
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.6680.7060.4419090900.208
Exposure limits
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
Stability:
hygroscopic
CAS DataBase Reference
13765-24-7(CAS DataBase Reference)
EPA Substance Registry System
Samarium fluoride (SmF3) (13765-24-7)
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Safety

Hazard Codes 
Xi,T
Risk Statements 
36/37/38-32-23/24/25
Safety Statements 
37/39-26-45-36/37/39
RIDADR 
UN 3288
Hazard Note 
Irritant
TSCA 
TSCA listed
HazardClass 
6.1
PackingGroup 
III
HS Code 
28469000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
93-6205
Product name
Samarium(III) fluoride (99.9%-Sm) (REO)
Packaging
5g
Price
$48
Updated
2024/03/01
Strem Chemicals
Product number
93-6205
Product name
Samarium(III) fluoride (99.9%-Sm) (REO)
Packaging
25g
Price
$185
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0004846
Product name
SAMARIUM FLUORIDE
Purity
95.00%
Packaging
25G
Price
$1164.66
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0004846
Product name
SAMARIUM FLUORIDE
Purity
95.00%
Packaging
100G
Price
$2743.68
Updated
2021/12/16
Apolloscientific
Product number
PC6343
Product name
Samarium(III)fluoride
Purity
99.9%
Packaging
100g
Price
$433
Updated
2021/12/16
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Samarium trifluoride Chemical Properties,Usage,Production

Uses

Samarium Fluoride has specialized uses in glass, phosphors, lasers, and thermoelectric devices. Samarium-doped Calcium Fluoride crystals were used as an active medium in one of the first solid-state lasers designed and constructed. These magnets are found in small motors, headphones, and high-end magnetic pickups for guitars and related musical instruments.

Chemical Properties

Samarium (III) fluoride is a yellow solid or odourless powder and slightly hygroscopic. It is insoluble in water. Workers should avoid open flame, moisture, and strong acids.

Uses

Samarium(III) fluoride is used as laboratory reagent, in optical glasses, structural ceramics, catalysts, electrical components and photo-optical material. It has specialized uses in phosphors, lasers, and thermoelectric devices.

Synthesis

In FK3000 enamel reaction tank, add 1000L of samarium chloride solution with the concentration of 0.23mol/L, the samarium chloride solution is heated to 93??, add 300L of ammonium bicarbonate solution with the concentration of 2.5mol/L, the precipitation reaction is completed in 3 hours, the heat preservation aging is completed in 1 hour, washing, filtration, and then get the samarium carbonate and samarium carbonate alkaline precipitate, in which the weight ratio of samarium carbonate to samarium carbonate alkaline is 4:1; in 1000L fluoride transformation tank, add 130L of water, and then make the precipitation into slurry with paddle under stirring condition. Add 130L water in 1000L fluoride transformation tank, modulate samarium carbonate and samarium carbonate precipitate into slurry, add 40% hydrofluoric acid 40kg fluoride into the slurry under stirring, fluoride temperature at 20??, control the endpoint acidity pH value of 1.5~2.0, and then continue to stir for 1 hour, then wash, filter, and centrifugal drying of samarium fluoride precipitate, and then dry in drying kiln at 200??. The samarium fluoride precipitation was washed, filtered, centrifuged and dried in the drying kiln at 200?? for 12 hours, and the center particle size of samarium fluoride product was 30.06μm.

Samarium trifluoride Preparation Products And Raw materials

Raw materials

Preparation Products

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Samarium trifluoride Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9401
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
Shandong Xiya Chemical Co., Ltd
Tel
13355009207 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Beijing innoChem Science & Technology Co.,Ltd.
Tel
400-810-7969 010-59572699
Fax
010-59572688
Email
ningzi.li@inno-chem.com.cn
Country
China
ProdList
6134
Advantage
55
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View Lastest Price from Samarium trifluoride manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Samarium trifluoride 13765-24-7
Price
US $0.00/kg
Min. Order
1kg
Purity
99.90%
Supply Ability
20tons
Release date
2023-09-11
Hebei Yanxi Chemical Co., Ltd.
Product
Samarium trifluoride 13765-24-7
Price
US $0.00/kg
Min. Order
1kg
Purity
99.90%
Supply Ability
20tons
Release date
2023-09-11
Career Henan Chemical Co
Product
Samarium trifluoride 13765-24-7
Price
US $2.00/KG
Min. Order
1g
Purity
98%MIN
Supply Ability
ASK
Release date
2020-01-14

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