METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATE

Product Name: METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATE
CAS No.: 82788-37-2
Chemical Name: METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATE
Synonyms: METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATE;methyl 6-methyl-1-benzofuran-2-carboxylate;6-Methyl-2-benzofurancarboxylic acid methyl ester;2-Benzofurancarboxylic acid, 6-methyl-, methyl ester
CBNumber: CB52466809
Molecular Formula: C11H10O3
Formula Weight: 190.2
MOL File: 82788-37-2.mol

More

Less

METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATE Property

Boiling point:: 277.2±20.0 °C(Predicted)
Density: 1.184±0.06 g/cm3(Predicted)
storage temp.: 2-8°C

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

TRC

Product number: M779650
Product name: Methyl6-methylbenzofuran-2-carboxylate
Packaging: 1mg
Price: $45
Updated: 2021/12/16

AK Scientific

Product number: 2795AC
Product name: Methyl6-methylbenzofuran-2-carboxylate
Packaging: 250mg
Price: $161
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0393349
Product name: METHYL-6-METHYLBENZOFURAN-2-CARBOXYLATE
Purity: 95.00%
Packaging: 5MG
Price: $503.91
Updated: 2021/12/16

Chemenu

Product number: CM153763
Product name: methyl6-methylbenzofuran-2-carboxylate
Purity: 96%
Packaging: 5g
Price: $552
Updated: 2021/12/16

Crysdot

Product number: CD11050554
Product name: Methyl6-methylbenzofuran-2-carboxylate
Purity: 96%
Packaging: 5g
Price: $584
Updated: 2021/12/16

More

Less

METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATE Chemical Properties,Usage,Production

Synthesis

67-56-1

50779-65-2

82788-37-2

At room temperature, 6-methylbenzofuran-2-carboxylic acid (11 g, 62.4 mmol) was dissolved in a solvent mixture of toluene (468 mL) and methanol (156 mL). 2N trimethylsilyl diazomethane (TMS-CHN2, 46.8 mL, 94 mmol) was slowly added dropwise to the above solution. The reaction mixture was stirred continuously for 6 hours at room temperature. Upon completion of the reaction, the reaction was quenched by dropwise addition of acetic acid at 0 °C until the yellow color of the solution disappeared and no gas escaped. Subsequently, the reaction mixture was concentrated under reduced pressure to remove the solvent and the residue was purified by rapid chromatography on silica gel with a gradient of 100% heptane to 10% ethyl acetate/90% heptane as eluent to yield methyl 6-methylbenzofuran-2-carboxylate (7.96 g). The structure of the product was confirmed by 1H NMR (400 MHz, DMSO-d6): δ 2.46 (s, 3H), 3.88 (s, 3H), 7.20 (dd, J=8.3,1.0 Hz, 1H), 7.53 (s, 1H), 7.67 (d, J=8.1 Hz, 1H), 7.71 (d, J=1.0 Hz, 1H).

References

[1] Bollettino Scientifico della Facolta di Chimica Industriale di Bologna, 1952, vol. 10, p. 168
[2] Patent: WO2015/161052, 2015, A1. Location in patent: Page/Page column 48

METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATE Suppliers

China 23 India 1 United States 3 Global 27

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Amatek Scientific Co. Ltd.

Tel: 0512-56316828
Fax: 0512-56316826
Email: info@amateksci.com
Country: China
ProdList: 28772
Advantage: 58

Biokitchen

Tel: 021-021-021-31663258 13795219287
Fax: 021-31663258
Email: donghuanwen@126.com
Country: China
ProdList: 8816
Advantage: 58

Aikon International Limited

Tel: 025-66061636 19370895928
Fax: (3)02557626880
Email: qqyang@aikonchem.com
Country: China
ProdList: 15813
Advantage: 58

SHANGHAI FDC-CHEMICAL CO.,LTD

Tel: 021-61469567 13482353728
Fax: 021-61161605
Email: sales@fdc-chemical.com
Country: China
ProdList: 9964
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 021-4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52678
Advantage: 58

Shanghai Gugang New Materials Technology Co. Ltd.

Tel: 021-51317962
Fax: 021-51317962
Email: 296935822@qq.com
Country: China
ProdList: 999
Advantage: 58

Zhuhai Aobokai Biomedical Technology Co., Ltd.

Tel: 400-0628126
Email: sales-team@aobchem.com.cn
Country: China
ProdList: 19955
Advantage: 58

Labnetwork lnc.

Tel: +86-27-50766799 +8618062016861
Email: contact@labnetwork.com
Country: China
ProdList: 19987
Advantage: 58

Shanghai jingkang bioengineering co., ltd.

Tel: 021-54721350 13524668266
Fax: 021-5
Email: 2881505714@qq.com
Country: China
ProdList: 7872
Advantage: 58

82788-37-2, METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATERelated Search:

METHYL 6-METHYLBENZOFURAN-2-CARBOXYLATE

methyl 6-methyl-1-benzofuran-2-carboxylate

6-Methyl-2-benzofurancarboxylic acid methyl ester

2-Benzofurancarboxylic acid, 6-methyl-, methyl ester

82788-37-2