methyl 3-bromo-4-methyl-5-nitropicolinate

Product Name: methyl 3-bromo-4-methyl-5-nitropicolinate
CAS No.: 1150618-07-7
Chemical Name: methyl 3-bromo-4-methyl-5-nitropicolinate
Synonyms: methyl 3-bromo-4-methyl-5-nitropicolinate;methyl3-bromo-4-methyl-5-nitropyridine-2-carboxylate;methyl 3-bromo-4-methyl-5-nitropicolinate ISO 9001：2015 REACH;3-Bromo-4-methyl-5-nitro-2-pyridinecarboxylic acid methyl ester;2-Pyridinecarboxylic acid, 3-bromo-4-methyl-5-nitro-, methyl ester
CBNumber: CB52474727
Molecular Formula: C8H7BrN2O4
Formula Weight: 275.06
MOL File: 1150618-07-7.mol

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methyl 3-bromo-4-methyl-5-nitropicolinate Property

Boiling point:: 377.2±42.0 °C(Predicted)
Density: 1.668
storage temp.: 2-8°C
pka: -4.11±0.10(Predicted)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation

Product number: HCH0036420
Product name: METHYL 3-BROMO-4-METHYL-5-NITROPICOLINATE
Purity: 95.00%
Packaging: 5G
Price: $909.56
Updated: 2021/12/16

Chemenu

Product number: CM178410
Product name: Methyl3-bromo-4-methyl-5-nitropicolinate
Purity: 95%
Packaging: 1g
Price: $485
Updated: 2021/12/16

Alichem

Product number: 1150618077
Product name: Methyl3-bromo-4-methyl-5-nitropicolinate
Packaging: 5g
Price: $998
Updated: 2021/12/16

Chemenu

Product number: CM178410
Product name: Methyl3-bromo-4-methyl-5-nitropicolinate
Purity: 95%
Packaging: 5g
Price: $1457
Updated: 2021/12/16

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methyl 3-bromo-4-methyl-5-nitropicolinate Chemical Properties,Usage,Production

Preparation

Methyl-3-bromo-4-methyl-5-nitropicolinate synthesis: 3-bromo-2-iodo-4-methyl-5-nitropyridine (129.0 g, 0.38 mol) and (Ph3P)2PdCl2 (7.92 g, 3 mol%) were suspended in CH3CN (1300 mL) and MeOH (430 mL) and Et3N (79.3 mL, 1.5 eq) was added. The mixture was transferred to a steel 5000 mL pressure vessel, 4 bar of CO pressure was applied and the reaction mixture was slowly heated to 80 oC. Subsequently, it was stirred for 5 h at this temperature, then allowed to cool overnight. The volatiles were removed in vacuo, the residue was stirred in EtOAc (1000 mL) and filtered. The residue was extracted with EtOAc (2*250 mL) and the combined filtrates were washed with brine (1000 mL) and dried on Na2SO4. The volatiles were removed in vacuo, affording 120 g of a brown oil. This was coated on 120 g of silicagel and purified by column chromatography (3500 g of silica gel, EtOAc/heptane 1:3, KMnO4 staining). The appropriate fractions were combined and concentrated to give Methyl-3-bromo-4-methyl-5-nitropicolinate as a beige solid (63.5 g, 61%).

methyl 3-bromo-4-methyl-5-nitropicolinate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from methyl 3-bromo-4-methyl-5-nitropicolinate manufacturers

Dideu Industries Group Limited

Product: methyl 3-bromo-4-methyl-5-nitropicolinate 1150618-07-7
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons min
Release date: 2021-09-23

Career Henan Chemical Co

Product: methyl 3-bromo-4-methyl-5-nitropicolinate 1150618-07-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95-99%
Supply Ability: 1ton
Release date: 2020-01-08

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2-Pyridinecarboxylic acid, 3-bromo-4-methyl-5-nitro-, methyl ester

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methyl3-bromo-4-methyl-5-nitropyridine-2-carboxylate

methyl 3-bromo-4-methyl-5-nitropicolinate ISO 9001：2015 REACH

1150618-07-7