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exo-5-Norbornenecarboxylic acid

Product Name
exo-5-Norbornenecarboxylic acid
CAS No.
934-30-5
Chemical Name
exo-5-Norbornenecarboxylic acid
Synonyms
exo-5-Norbornenecarboxylic acid;exo-5-Norbornene-2-carboxylic acid;exo-5-Norbornenecarboxylic acid 97%;exo-5-Norbornenecarboxylic acid;exo-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid;(1R,2S,4R)-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid;Bicyclo(2.2.1)hept-5-ene-2-carboxylic acid, exo- (9CI);rel-(1S,2R,4S)-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid;Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, (1R,2S,4R)-rel-
CBNumber
CB52480368
Molecular Formula
C8H10O2
Formula Weight
138.16
MOL File
934-30-5.mol
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exo-5-Norbornenecarboxylic acid Property

Melting point:
40-44 °C
Boiling point:
266.7±19.0 °C(Predicted)
Density 
1.247±0.06 g/cm3(Predicted)
Flash point:
>110°C
storage temp. 
2-8°C
form 
solid
pka
4.63±0.20(Predicted)
color 
White to Light Yellow and Faint Beige to Beige
InChI
InChI=1/C8H10O2/c9-8(10)7-4-5-1-2-6(7)3-5/h1-2,5-7H,3-4H2,(H,9,10)/t5-,6+,7+/s3
InChIKey
FYGUSUBEMUKACF-QXWMLGDLNA-N
SMILES
[C@@]12([H])C[C@@]([H])(C=C1)C[C@@H]2C(O)=O |&1:0,3,8,r|
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
RTECS 
RB8195000
HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
718149
Product name
exo-5-Norbornenecarboxylic acid
Purity
97%
Packaging
1g
Price
$133
Updated
2025/07/31
Sigma-Aldrich
Product number
S662321
Product name
EXO-BICYCLO(2.2.1)HEPT-5-ENE-2-CARBOXYLIC ACID
Purity
Aldrich<sup>CPR</sup>
Packaging
1 unit
Price
$185
Updated
2025/07/31
Sigma-Aldrich
Product number
718149
Product name
exo-5-Norbornenecarboxylic acid
Purity
97%
Packaging
5g
Price
$397
Updated
2025/07/31
Sigma-Aldrich
Product number
S662321
Product name
exo-5-Norbornenecarboxylic acid
Purity
AldrichCPR
Packaging
250mg
Price
$179
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CCH0000745
Product name
(1R,2S,4R)-BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLIC ACID
Purity
95.00%
Packaging
500MG
Price
$796.95
Updated
2021/12/16
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exo-5-Norbornenecarboxylic acid Chemical Properties,Usage,Production

Description

Exo-5-norbornenecarboxylic acid is a bicyclic compound that has potential applications in the field of material science due to its unique chemical properties. It is a versatile building block for the synthesis of various functional materials, including polymers, dendrimers, and self-assembled monolayers. It can be used to modify surfaces or to functionalize nanoparticles, influencing their optical, magnetic, or electronic properties. It is also often used in ring-opening metathesis polymerization reactions to form polymers with controlled molecular weight and structure. Additionally, exo-5-norbornenecarboxylic acid can function as a ligand for coordination chemistry and catalysis.

Uses

Exo-5-norbornenecarboxylic acid can be used as:

  • A starting material in the synthesis of the metathesis polymer via a ring-opening metathesis polymerization (ROMP) reaction of the ester of exo-5-norbornenecarboxylic acid and 1,1μ-bi-2-naphthol.
  • A monomer in the preparation of thin films via surface-initiated polymerization process. The resulting thin film serves as a template for selective deposition and etching of metal oxides, which is of significant importance in the microelectronic industry.
exo-5-Norbornenecarboxylic acid can be used as a precursor in the synthesis of:
  • Different crosslinkers for ring-opening metathesis polymerization.
  • Norbornene-functionalized monomers, which are used to make poly(norbornene)s via ring-opening metathesis polymerization (ROMP).
  • Hydrolytically cleavable and hydrolytically stable functionalized macromonomers for hydrogel preparation.

References

[1] IVAN V NAZAROV. Gas-Transport and the Dielectric Properties of Metathesis Polymer from the Ester of exo-5-Norbornenecarboxylic Acid and 1,1’-Bi-2-naphthol.[J]. ACS Applied Energy Materials, 2022. DOI:10.3390/polym14132697.
[2] CHRISTOPHER L. MCGANN. Thiol-ene Photocrosslinking of Cytocompatible Resilin-Like Polypeptide-PEG Hydrogels[J]. Macromolecular bioscience, 2015, 16 1: 129-138. DOI:10.1002/mabi.201500305.

exo-5-Norbornenecarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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exo-5-Norbornenecarboxylic acid Suppliers

Beijing Kemaiqi Medical Technology Co., LTD
Tel
010-15910349257 15910349257
Email
biandeqian@163.com
Country
China
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698
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
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44801
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Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 13167063860
Fax
021-50323701
Email
anhua.mao@aladdin-e.com
Country
China
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25003
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Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
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51395
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Zhengzhou Gecko Scientific Inc.
Tel
0371-63336364 17344886665
Fax
0371-65511872
Email
209932355@qq.com
Country
China
ProdList
489
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Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
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QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
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60
Aikon International Limited
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025-66113011 13155353615
Fax
(7)02557626880
Email
qzhang@aikonchem.com
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China
ProdList
15394
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Alfa Chemistry
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+1-5166625404;
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1-516-927-0118
Email
Info@alfa-chemistry.com
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United States
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20405
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Zhengzhou Alfa Chemical Co.,Ltd
Tel
+8618530059196
Email
sale04@alfachem.cn
Country
China
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11797
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Hubei Jusheng Technology Co.,Ltd.
Tel
18871490254
Fax
027-59599243
Email
linda@hubeijusheng.com
Country
CHINA
ProdList
28172
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58

934-30-5, exo-5-Norbornenecarboxylic acidRelated Search:


  • (1R,2S,4R)-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid
  • exo-5-Norbornenecarboxylic acid 97%
  • exo-5-Norbornenecarboxylic acid
  • exo-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid
  • exo-5-Norbornene-2-carboxylic acid
  • Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, (1R,2S,4R)-rel-
  • rel-(1S,2R,4S)-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid
  • Bicyclo(2.2.1)hept-5-ene-2-carboxylic acid, exo- (9CI)
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