2-Bromo-3-fluoro-6-picoline

Product Name: 2-Bromo-3-fluoro-6-picoline
CAS No.: 374633-36-0
Chemical Name: 2-Bromo-3-fluoro-6-picoline
Synonyms: 2-bromo-3-fluoro-6-methylpyridine;2-Bromo-3-fL;uoro-6-methyL;6-Bromo-5-fluoro-2-picoline;2-BROMO-3-FLUORO-6-PICOLINE;Pyridine, 2-bromo-3-fluoro-6-methyl-;2-Bromo-3-fluoro-6-methylpyridine,98%;2-BROMO-3-FLUORO-6-PICOLINE ISO 9001：2015 REACH
CBNumber: CB5252466
Molecular Formula: C6H5BrFN
Formula Weight: 190.01
MOL File: 374633-36-0.mol

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2-Bromo-3-fluoro-6-picoline Property

Boiling point:: 185.6±35.0 °C(Predicted)
Density: 1.592±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
pka: -0.91±0.10(Predicted)
form: Solid
InChIKey: KKVUMKHUMBXLMH-UHFFFAOYSA-N
CAS DataBase Reference: 374633-36-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xn
Risk Statements: 22
HS Code: 2933499090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: AGN00010
Product name: 2-Bromo-3-fluoro-6-methylpyridine
Purity: Aldrich
Packaging: 1g
Price: $320
Updated: 2024/03/01

Alfa Aesar

Product number: H64900
Product name: 2-Bromo-3-fluoro-6-methylpyridine, 98%
Packaging: 1g
Price: $25.7
Updated: 2023/06/20

Alfa Aesar

Product number: H64900
Product name: 2-Bromo-3-fluoro-6-methylpyridine, 98%
Packaging: 5g
Price: $106
Updated: 2023/06/20

Alfa Aesar

Product number: H64900
Product name: 2-Bromo-3-fluoro-6-methylpyridine, 98%
Packaging: 25g
Price: $391
Updated: 2021/12/16

TRC

Product number: B685188
Product name: 2-Bromo-3-fluoro-6-picoline
Packaging: 250mg
Price: $55
Updated: 2021/12/16

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2-Bromo-3-fluoro-6-picoline Chemical Properties,Usage,Production

Synthesis

3-Amino-2-bromo-6-methylpyridine or 4-amino-2-bromo-6-methylpyridine (25.20 g, 134.73 mmol) was added to a mixture of water (78.1 mL) and conc. HCl (12.8 mL, 350.30 mmol), and then the mixture was cooled to 0 ℃. To it, sodium nitrite (18.6 g,269.46 mmol) was added portion-wise with stirring over 20 min while keeping the reaction temperature between –5 ℃and 0 ℃. After 10 min, 65 per cent hexafluorophosphoric acid solution (43.26 g, 296.41 mmol) was added dropwise with cooling, at which point many precipitates were formed. The precipitates were collected by filtration using a glass filter funnel, washed with cold water (2 × 50 mL) and diethyl ether (100 mL), and then dried in the air for 48 h. The solid was slowly heated to 100 ℃ (very exothermic), and a dark, oily material was formed after 10 min. The oil was basified with diluted NaOH solution to pH~10 and extracted with CH2Cl2 (2 × 150 mL). The combined organic layer was dried over anhydrous Na2SO4, filtered, and evaporated to dryness under reduced pressure. The residue was purified by MPLC on neutral alumina using hexane/EtOAc (10:1) as an eluent to afford 2-Bromo-3-fluoro-6-picoline.

2-Bromo-3-fluoro-6-picoline Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromo-3-fluoro-6-picoline Suppliers

China 187 Europe 2 Germany 1 India 2 United Kingdom 5 United States 23 Global 220

Tianjin Jinyuda Chemical Co., Ltd.

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Shanghai Longsheng chemical Co.,Ltd.

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View Lastest Price from 2-Bromo-3-fluoro-6-picoline manufacturers

Dideu Industries Group Limited

Product: 2-BROMO-3-FLUORO-6-PICOLINE 374633-36-0
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons min
Release date: 2021-08-25

Zhuozhou Wenxi import and Export Co., Ltd

Product: 2-BROMO-3-FLUORO-6-PICOLINE 374633-36-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-11

Career Henan Chemical Co

Product: 2-BROMO-3-FLUORO-6-PICOLINE 374633-36-0
Price: US $3.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-10

374633-36-0, 2-Bromo-3-fluoro-6-picolineRelated Search:

5-BROMO-2-FLUORO-6-PICOLINE 5-BROMO-2-FLUORO-3-PICOLINE (5-BROMO-2-FLUORO-3-METHYLPYRIDINE),5-BROMO-2-FLUORO-3-PICOLINE 2-Bromo-6-methylpyridine 2-BROMO-3-FLUORO-6-PICOLINE 5-Fluoro-2-methylpyridine 2-Bromo-3-fluoropyridine 2-BROMO-3-FLUORO-4-METHYLPYRIDINE 2-Bromo-6-Fluoro-4-Picoline 2-BROMO-5-FLUORO-6-PICOLINE (2-BROMO-5-FLUORO-6-METHYLPYRIDINE),2-BROMO-5-FLUORO-6-PICOLINE 2-Bromo-5-Fluoro-3-Methylpyridine 2-BROMO-3-FLUORO-4-PICOLINE 2-Bromo-5-fluoro-3-picoline 3-BROMO-2-FLUORO-5-PICOLINE,3-BROMO-2-FLUORO-5-PICOLINE (3-BROMO-2-FLUORO-5-METHYLPYRIDINE) 2-Bromo-3-Fluoro-5-Methylpyridine 3-BROMO-2-FLUORO-6-PICOLINE 2-BROMO-5-FLUORO-4-PICOLINE 3-Bromo-2-fluoro-5-methylpyridine 3-BROMO-2-FLUORO-4-PICOLINE

2-BROMO-3-FLUORO-6-PICOLINE

2-bromo-3-fluoro-6-methylpyridine

6-Bromo-5-fluoro-2-picoline

2-Bromo-3-fL

uoro-6-methyL

Pyridine, 2-bromo-3-fluoro-6-methyl-

2-Bromo-3-fluoro-6-methylpyridine,98%

2-BROMO-3-FLUORO-6-PICOLINE ISO 9001：2015 REACH

374633-36-0

C6H11NBrF

Pyridine

Pyridines

Boronic Acid

Pyridine Series