Bicyclo[2.2.2]octane-1,4-dimethanol

Product Name: Bicyclo[2.2.2]octane-1,4-dimethanol
CAS No.: 826-45-9
Chemical Name: Bicyclo[2.2.2]octane-1,4-dimethanol
Synonyms: Bicyclo[2.2.2]octane-1,4-diMethano;Bicyclo[2.2.2]octane-1,4-dimethanol;Bicyclo[2.2.2]octane-1,4-diyldiMethanol;1,4-Bis(hydroxymethyl)bicyclo[2.2.2]octane;(4-Hydroxymethyl-bicyclo[2.2.2]oct-1-yl)-methanol;[4-(hydroxymethyl)-1-bicyclo[2.2.2]octanyl]methanol
CBNumber: CB52538919
Molecular Formula: C10H18O2
Formula Weight: 170.25
MOL File: 826-45-9.mol

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Bicyclo[2.2.2]octane-1,4-dimethanol Property

Melting point:: 107-108 °C
Boiling point:: 298.8±8.0 °C(Predicted)
Density: 1.137±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 14.94±0.10(Predicted)
Appearance: Off-white to light yellow Solid
InChI: InChI=1S/C10H18O2/c11-7-9-1-2-10(8-12,5-3-9)6-4-9/h11-12H,1-8H2
InChIKey: DLBHMXBDKPROEG-UHFFFAOYSA-N
SMILES: C12(CO)CCC(CO)(CC1)CC2

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Safety

HS Code: 2906190090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Activate Scientific

Product number: AS45702
Product name: Bicyclo[2.2.2]octane-1,4-diyldimethanol
Purity: 98%
Packaging: 250mg
Price: $230
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2204-1-14
Product name: Bicyclo[2.2.2]octane-1,4-diyldimethanol
Packaging: 250mg
Price: $396
Updated: 2021/12/16

Activate Scientific

Product number: AS45702
Product name: Bicyclo[2.2.2]octane-1,4-diyldimethanol
Purity: 98%
Packaging: 1g
Price: $450
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0391950
Product name: BICYCLO-[2.2.2]-OCTANE-1,4-DIYLDIMETHANOL
Purity: 95.00%
Packaging: 5MG
Price: $500.87
Updated: 2021/12/16

AK Scientific

Product number: 2775AC
Product name: Bicyclo[2.2.2]octane-1,4-diyldimethanol
Packaging: 5g
Price: $860
Updated: 2021/12/16

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Bicyclo[2.2.2]octane-1,4-dimethanol Chemical Properties,Usage,Production

Synthesis

1659-75-2

826-45-9

An ether solution of diethyl dicyclo[2,2,2]octane-1,4-cyclohexanedicarboxylate (3.0313 g, 11.91 mmol) was slowly added to an ether suspension of lithium aluminum hydride (856.9 mg, 23.84 mmol) under argon protection. The reaction mixture was heated to reflux for 4 hours. Upon completion of the reaction, the reaction was quenched by slow addition of 2 M sodium hydroxide solution and water. The reaction mixture was filtered and the solid salt was washed with ether. All ether layers were combined and dried with anhydrous sodium sulfate and subsequently concentrated under reduced pressure to give bicyclo[2.2.2]octane-1,4-dimethanol (1.7899 g, 88% yield). The product was characterized by 1H-NMR (600 MHz, CDCl3): δ 1.43 (s, 14H), 3.27 (s, 4H).

References

[1] Journal of Organic Chemistry, 1984, vol. 49, # 4, p. 665 - 670
[2] Journal of the American Chemical Society, 2008, vol. 130, # 24, p. 7659 - 7669
[3] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 4, p. 1756 - 1760
[4] Journal of pharmaceutical sciences, 1971, vol. 60, # 10, p. 1534 - 1537
[5] Journal of the American Chemical Society, 2011, vol. 133, # 10, p. 3570 - 3581

Bicyclo[2.2.2]octane-1,4-dimethanol Preparation Products And Raw materials

Raw materials

Preparation Products

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Bicyclo[2.2.2]octane-1,4-dimethanol Suppliers

China 50 India 1 United Kingdom 1 United States 5 Global 57

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View Lastest Price from Bicyclo[2.2.2]octane-1,4-dimethanol manufacturers

Career Henan Chemical Co

Product: Bicyclo[2.2.2]octane-1,4-dimethanol 826-45-9
Price: US $6.68/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg-1000kg
Release date: 2020-01-09

826-45-9, Bicyclo[2.2.2]octane-1,4-dimethanolRelated Search:

Hexane 2,3,3a,5,6,6a-Hexahydropentalene-1,4-dione 2,3-NORBORNANEDICARBOXYLIC ACID BICYCLO[2.2.1]HEPTANE-2-CARBOXYLIC ACID bicyclo[1.1.1]pentan-1-ylmethanol Bicyclo[1.1.1]pentane-1,3-dicarboxylic acid, MonoMethyl ester ETHYL 5-NORBORNENE-2-CARBOXYLATE (MIXTURE OF ENDO AND EXO) 5-Norbornene-2-carboxamide bicyclo[3.2.1]octane-2,4-dione Bicyclo[3.1.0]hexan-3-ol Bicyclo[1.1.1]pentane-1-carboxylic acid, methyl ester (9CI) 4-Aminobenzocyclobutene 4-Hydroxymethylbenzocyclobutene 4-Carboxylbenzocyclobutene bicyclo[1.1.1]pentane-1,3-dicarbonitrile Bicyclo[1.1.1]pentane-1-sulfonamide Bicyclo[1.1.1]pentane-1,3-dicarboxamide Bicyclo[1.1.1]pentane-1-carboxamide

Bicyclo[2.2.2]octane-1,4-dimethanol

Bicyclo[2.2.2]octane-1,4-diMethano

Bicyclo[2.2.2]octane-1,4-diyldiMethanol

1,4-Bis(hydroxymethyl)bicyclo[2.2.2]octane

[4-(hydroxymethyl)-1-bicyclo[2.2.2]octanyl]methanol

(4-Hydroxymethyl-bicyclo[2.2.2]oct-1-yl)-methanol

826-45-9