DIPHENYL(VINYL)PHOSPHINE OXIDE

Product Name: DIPHENYL(VINYL)PHOSPHINE OXIDE
CAS No.: 2096-78-8
Chemical Name: DIPHENYL(VINYL)PHOSPHINE OXIDE
Synonyms: AURORA KA-1579;Ethenyldiphenylphosphine Oxide;DIPHENYL(VINYL)PHOSPHINE OXIDE;[phenyl(vinyl)phosphoryl]benzene;Phosphine oxide, ethenyldiphenyl-;[ethenyl(phenyl)phosphoryl]benzene;PHOSPHINE, ETHENYLDIPHENYL-, OXIDE
CBNumber: CB5257249
Molecular Formula: C14H13OP
Formula Weight: 228.23
MOL File: 2096-78-8.mol

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DIPHENYL(VINYL)PHOSPHINE OXIDE Property

Melting point:: 117.5℃
Boiling point:: 397.6±15.0 °C(Predicted)
Density: 1.11±0.1 g/cm3(Predicted)
solubility: soluble in THF, CH2Cl2, toluene; insoluble in H2O.
form: powder
color: Light yellow

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Safety

HS Code: 2931499090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

H360May damage fertility or the unborn child

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

TRC

Product number: P353715
Product name: EthenyldiphenylphosphineOxide
Packaging: 500mg
Price: $175
Updated: 2021/12/16

Matrix Scientific

Product number: 188293
Product name: Phosphine oxide
Purity: ethenyldiphenyl-
Packaging: 1g
Price: $226
Updated: 2021/12/16

SynQuest Laboratories

Product number: 6974-1-02
Product name: Diphenyl(vinyl)phosphine oxide
Packaging: 1g
Price: $120
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0000732
Product name: DIPHENYL(VINYL)PHOSPHINE OXIDE
Purity: 95.00%
Packaging: 250MG
Price: $153.3
Updated: 2021/12/16

Apolloscientific

Product number: OR22135
Product name: Diphenyl(vinyl)phosphineoxide
Packaging: 5g
Price: $428
Updated: 2021/12/16

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DIPHENYL(VINYL)PHOSPHINE OXIDE Chemical Properties,Usage,Production

Uses

Ethenyldiphenylphosphine Oxide was used a starting material in the synthesis of sorbents for the selective and effective sorption of Am(III) from HNO3 solutions containing high concentration of Fe(III) and Zr(IV).

Synthesis Reference(s)

Synthesis, p. 691, 1986 DOI: 10.1055/s-1986-31753

Reactivity Profile

Diphenyl(vinyl)phosphine Oxide is a Horner-Wittig reagent for the preparation of allylic amines; it undergoes a variety of cycloaddition and conjugate addition reactions.

Synthesis

Diphenyl(vinyl)phosphine Oxide can be prepared (eq 1) by four methods: (a) dehydrohalogenation of a haloethyldiphenylphosphine oxide, (b) reaction of diphenylphosphinic chloride and vinylmagnesium bromide, (c) palladium-catalyzed coupling of vinyl bromide and diphenylphosphine oxide, (d) oxidation of commercially available diphenyl(vinyl)phosphine.

Precautions

The reagent's toxicological properties are unknown; however, by analogy with other Michael acceptors, it should be assumed to be toxic. While radical polymerization is sluggish, diphenyl(vinyl)phosphine oxide readily undergoes anionic polymerization in the presence of Grignard reagents.

DIPHENYL(VINYL)PHOSPHINE OXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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DIPHENYL(VINYL)PHOSPHINE OXIDE Suppliers

Austria 1 China 16 United Kingdom 1 United States 3 Global 21

Beijing Donghualituo Techonlogy Development Co.,Ltd.

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Jikang Chemical Industry Co. , Ltd.

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2096-78-8, DIPHENYL(VINYL)PHOSPHINE OXIDERelated Search:

ISOEUGENOL DIPHENYLVINYLPHOSPHINE CIS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE DIOXIDE 2-(DIPHENYLPHOSPHORYL)CYCLOHEX-1-ENE-1-CARBALDEHYDE AURORA KA-1599 2-(DIPHENYLPHOSPHORYL)CYCLOPENT-1-ENE-1-CARBALDEHYDE 2-(DIPHENYL-PHOSPHINOYL)-CYCLOHEPT-1-ENECARBOXYLIC ACID 2-(DIPHENYL-PHOSPHINOYL)-CYCLOPENT-1-ENECARBOXYLIC ACID DIPHENYL(VINYL)PHOSPHINE OXIDE AURORA KA-1586 2-(DIPHENYL-PHOSPHINOYL)-CYCLOHEX-1-ENECARBOXYLIC ACID 2-(DIPHENYLPHOSPHORYL)CYCLOHEPT-1-ENE-1-CARBALDEHYDE AURORA KA-1580

AURORA KA-1579

DIPHENYL(VINYL)PHOSPHINE OXIDE

PHOSPHINE, ETHENYLDIPHENYL-, OXIDE

[ethenyl(phenyl)phosphoryl]benzene

[phenyl(vinyl)phosphoryl]benzene

Phosphine oxide, ethenyldiphenyl-

Ethenyldiphenylphosphine Oxide

2096-78-8

C14H13OP