N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II)

Product Name: N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II)
CAS No.: 14167-20-5
Chemical Name: N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II)
Synonyms: Nickel(II) salen;N,N'-Ethylenebis(salicylideniminato)nickel;Bis(salicylaldehyde)ethylenediiminatonickel;Nickel, [N,N'-ethylenebis(salicylaldiminato)]-;N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II);[[α,α′-(Ethylenedinitrilo)di-o-cresolato](2-)]nickel;N,N′-Bis(salicylidene)ethylenediaminonickel(II);Nickel, [[alpha,alpha'-(ethylenedinitrilo)di-o-cresolato](2-)]-;[[2,2′-[1,2-Ethanediylbis[(nitrilo-κN)methylidyne]]bis[phenolato-κO]](2-)]nickel;Nickel, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-
CBNumber: CB5261422
Molecular Formula: C16H14N2NiO2
Formula Weight: 324.99
MOL File: 14167-20-5.mol

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N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II) Property

Melting point:: >150 °C (decomp)
InChI: InChI=1S/C16H16N2O2.Ni/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2/b17-11+,18-12+;
InChIKey: DKBSGGSJQXGHBV-OYJDLGDISA-L
SMILES: C12C=CC=CC=1C=NCCN=CC1C=CC=CC=1O[Ni]O2 |t:7,11|

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Safety

Hazard Codes: T
Risk Statements: 45-20/21/22-36/37/38-42/43
Safety Statements: 53-26-36/37/39-45
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation

Product number: OGM0001371
Product name: N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II)
Purity: 98.00%
Packaging: 5G
Price: $914.41
Updated: 2021/12/16

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N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II) Chemical Properties,Usage,Production

Uses

Catalyst for:

Covalent functionalization of multiwall carbon nanotubes
Reduction reactions
Epoxidation reactions
Reduction and intramolecular cyclization

Synthesis Reference(s)

[1]Goedken, V. L.; Weiss, M. C. Inorg. Synth. 1980, 20, 115.

reaction suitability

core: nickel
reagent type: catalyst

Synthesis

N,N′-Bis(salicylidene)ethylenediaminenickel(II) is easily and cheaply prepared from ethylenediamine, salicylaldehyde, and Ni(OAc)2.^[1]

storage

N,N′-Bis(salicylidene)ethylenediaminenickel(II) is low sensitivity to air and water; cancer suspect agent; handle with care.

N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II) Suppliers

China 16 Switzerland 1 United Kingdom 1 United States 3 Global 21

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14167-20-5, N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II)Related Search:

DIBENZYLIDENE ETHYLENEDIAMINE NICKEL(II) HYDROXIDE Nickel sulfate hexahydrate N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II)

Bis(salicylaldehyde)ethylenediiminatonickel

N,N'-Ethylenebis(salicylideniminato)nickel

Nickel, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-

Nickel, [[alpha,alpha'-(ethylenedinitrilo)di-o-cresolato](2-)]-

Nickel, [N,N'-ethylenebis(salicylaldiminato)]-

N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II)

[[2,2′-[1,2-Ethanediylbis[(nitrilo-κN)methylidyne]]bis[phenolato-κO]](2-)]nickel

[[α,α′-(Ethylenedinitrilo)di-o-cresolato](2-)]nickel

Nickel(II) salen

<i>N</i>,<i>N</i>′-Bis(salicylidene)ethylenediaminonickel(II)

14167-20-5

-CH2NCHC6H42O2Ni

C16H14N2NiO2

Catalysis and Inorganic Chemistry

Chemical Synthesis