ChemicalBook > CAS DataBase List > Methyl 3-fluoro-4-forMylbenzoate

Methyl 3-fluoro-4-forMylbenzoate

Product Name: Methyl 3-fluoro-4-forMylbenzoate
CAS No.: 74733-25-8
Chemical Name: Methyl 3-fluoro-4-forMylbenzoate
Synonyms: Methyl 3-fluoro-4-forMylbenzoate;4-Methyl 3-fluoro-4-formylbenzoate;3-Fluoro-4-formylbenzoic acid methyl ester;Benzoic acid, 3-fluoro-4-formyl-, methyl ester
CBNumber: CB52616680
Molecular Formula: C9H7FO3
Formula Weight: 182.15
MOL File: 74733-25-8.mol

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Methyl 3-fluoro-4-forMylbenzoate Property

Boiling point:: 290.9±30.0 °C(Predicted)
Density: 1.271±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
color: Cream

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M305488
Product name: Methyl3-fluoro-4-formylbenzoate
Packaging: 500mg
Price: $75
Updated: 2021/12/16

AK Scientific

Product number: Z5096
Product name: Methyl3-fluoro-4-formylbenzoate
Packaging: 5g
Price: $271
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0369335
Product name: METHYL-3-FLUORO-4-FORMYLBENZOATE
Purity: 95.00%
Packaging: 5MG
Price: $503.89
Updated: 2021/12/16

Chemenu

Product number: CM158684
Product name: Methyl3-fluoro-4-formylbenzoate
Purity: 95+%
Packaging: 5g
Price: $169
Updated: 2021/12/16

Crysdot

Product number: CD12036995
Product name: Methyl3-fluoro-4-formylbenzoate
Purity: 98%
Packaging: 5g
Price: $177
Updated: 2021/12/16

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Methyl 3-fluoro-4-forMylbenzoate Chemical Properties,Usage,Production

Synthesis

193290-80-1

74-88-4

74733-25-8

General procedure for the synthesis of methyl 3-fluoro-4-formylbenzoate (compound 14D) from 3-fluoro-4-formylbenzoic acid (compound 14C, 0.25 g, 1.49 mmol) and iodomethane: Compound 14C was dissolved in DMF (4.5 mL), and sodium hydride (60% oil dispersion, 0.069 g, 1.73 mmol) was added. The reaction mixture was stirred under nitrogen protection for 30 min, followed by the addition of iodomethane (0.11 mL, 1.74 mmol). The reaction was stirred continuously at room temperature for about 15 hours. Upon completion of the reaction, the mixture was poured into 1N HCl solution and extracted several times with EtOAc. The organic phases were combined, washed with saturated brine, dried over anhydrous MgSO4, filtered and concentrated under reduced pressure to give compound 14D as a wet residue, which solidified to a white solid after standing (0.23 g, 85% yield).

References

[1] Patent: WO2008/130584, 2008, A1. Location in patent: Page/Page column 144-145
[2] Patent: WO2013/74641, 2013, A1. Location in patent: Paragraph 00382
[3] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 17, p. 4804 - 4807
[4] Patent: WO2004/89916, 2004, A1. Location in patent: Page 22-23
[5] Journal of Medicinal Chemistry, 2009, vol. 52, # 19, p. 5950 - 5966

Methyl 3-fluoro-4-forMylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 3-fluoro-4-forMylbenzoate manufacturers

Shanghai UCHEM Inc.

Product: Methyl 3-fluoro-4-forMylbenzoate 74733-25-8
Price: US $138.00-1333.00/g
Min. Order: 5g
Purity: 0.98
Supply Ability: 1kg
Release date: 2023-12-18

74733-25-8, Methyl 3-fluoro-4-forMylbenzoateRelated Search:

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74733-25-8