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N-(4-Methoxybenzyl)hydroxylaMine

Product Name
N-(4-Methoxybenzyl)hydroxylaMine
CAS No.
51307-59-6
Chemical Name
N-(4-Methoxybenzyl)hydroxylaMine
Synonyms
N-Hydroxy-4-methoxybenzylamine;N-(p-Methoxybenzyl)hydroxylamine;N-(4-Methoxybenzyl)hydroxylaMine;N-hydroxy(4-methoxyphenyl)methanamine;Benzenemethanamine, N-hydroxy-4-methoxy-;N-[(4-methoxyphenyl)methyl]hydroxylamine;N-Hydroxy-1-(4-Methoxyphenyl)MethanaMine;3-Pyridinecarbonitrile,6-bromo-6-methyl-;N-(4-Methoxybenzyl)hydroxylamine - [M71588];N-(4-Methoxybenzyl)hydroxylamine hydrochloride
CBNumber
CB52624351
Molecular Formula
C8H11NO2
Formula Weight
153.18
MOL File
51307-59-6.mol
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N-(4-Methoxybenzyl)hydroxylaMine Property

Boiling point:
301.5±44.0 °C(Predicted)
Density 
1.125±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
pka
13.26±0.30(Predicted)
Appearance
White to off-white Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Ark Pharm
Product number
AK123262
Product name
N-(4-Methoxybenzyl)hydroxylamine
Purity
97%
Packaging
100mg
Price
$55
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0393541
Product name
N-(4-METHOXYBENZYL)HYDROXYLAMINE
Purity
95.00%
Packaging
5MG
Price
$499.16
Updated
2021/12/16
AK Scientific
Product number
7133AB
Product name
N-(4-Methoxybenzyl)hydroxylamine
Packaging
5g
Price
$1061
Updated
2021/12/16
A1 Biochem Labs
Product number
6565103
Product name
N-hydroxy(4-methoxyphenyl)methanaminehydrochloride
Purity
95%
Packaging
10g
Price
$1100
Updated
2021/12/16
Crysdot
Product number
CD12066459
Product name
N-(4-Methoxybenzyl)hydroxylamine
Purity
97%
Packaging
10g
Price
$1508
Updated
2021/12/16
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N-(4-Methoxybenzyl)hydroxylaMine Chemical Properties,Usage,Production

Synthesis

3717-21-3

51307-59-6

To a methanolic solution of (E)-4-methoxybenzaldehyde oxime (compound D) (1.0 mL containing 77.8 mg, 0.52 mmol) was added sodium cyanoborohydride (NaBH3CN, 22.7 mg, 0.36 mmol) at room temperature. Subsequently, the pH of the reaction mixture was adjusted to 3 by slow addition of 2 M HCl-MeOH solution and stirred continuously for 3 h at room temperature. Upon completion of the reaction, the reaction mixture was alkalized to basic by dropwise addition of 15% NaOH aqueous solution. After saturation with the addition of sodium chloride, the mixture was extracted with ethyl acetate. The organic layers were combined, dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure. The residue was purified by fast column chromatography (eluent: chloroform/methanol = 1:0 → 10:1) to afford N-(4-methoxybenzyl)hydroxylamine (73.5 mg, 92% yield) as white crystals.1H NMR (CDCl3) δ: 7.25 (d, J = 8.6 Hz, 2H), 6.87 (d, J = 8.6 Hz, 2H), 4.73 (brs. 2H), 3.97 (s, 2H), 3.80 (s, 3H).

References

[1] Journal of the Chemical Society, Perkin Transactions 2, 2001, # 11, p. 2059 - 2062
[2] Patent: US2005/182032, 2005, A1. Location in patent: Page/Page column 6
[3] Journal of the American Chemical Society, 2017, vol. 139, # 25, p. 8428 - 8431

N-(4-Methoxybenzyl)hydroxylaMine Preparation Products And Raw materials

Raw materials

Preparation Products

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N-(4-Methoxybenzyl)hydroxylaMine Suppliers

China 51 United States 2 Global 53
Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
52923
Advantage
58
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
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View Lastest Price from N-(4-Methoxybenzyl)hydroxylaMine manufacturers

Career Henan Chemical Co
Product
N-(4-Methoxybenzyl)hydroxylaMine 51307-59-6
Price
US $2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100g , 1kg, 5kg , 50kg
Release date
2020-01-07

51307-59-6, N-(4-Methoxybenzyl)hydroxylaMineRelated Search:


  • N-hydroxy(4-methoxyphenyl)methanamine
  • N-hydroxy(4-methoxyphenyl)methanamine hydrochloride
  • N-Hydroxy-1-(4-Methoxyphenyl)MethanaMine
  • N-(p-Methoxybenzyl)hydroxylamine
  • N-Hydroxy-4-methoxybenzylamine
  • N-(4-Methoxybenzyl)hydroxylaMine
  • N-[(4-methoxyphenyl)methyl]hydroxylamine
  • Benzenemethanamine, N-hydroxy-4-methoxy-
  • N-(4-Methoxybenzyl)hydroxylamine hydrochloride
  • 3-Pyridinecarbonitrile,6-bromo-6-methyl-
  • N-(4-Methoxybenzyl)hydroxylamine - [M71588]
  • 51307-59-6