ChemicalBook > CAS DataBase List > BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE

BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE

Product Name
BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE
CAS No.
136802-85-2
Chemical Name
BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE
Synonyms
BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE;chloro-bis(4-methoxy-3,5-dimethylphenyl)phosphane;Bis(3,5-dimethyl-4-methoxyphenyl)phosphinouschloride;Chlorobis(3,5-dimethyl-4-methoxyphenyl)phosphine, 98+%;Bis(3,5-diMethyl-4-Methoxyphenyl)chlorophosphine,Min.98%;Phosphinous chloride, P,P-bis(4-methoxy-3,5-dimethylphenyl)-
CBNumber
CB5264610
Molecular Formula
C18H22ClO2P
Formula Weight
336.79
MOL File
136802-85-2.mol
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BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE Property

Boiling point:
451.7±45.0 °C(Predicted)
Density 
1.141 g/cm3 at 25 °C
refractive index 
n20/D1.597
Flash point:
>110℃
form 
liquid
color 
colorless, viscous
Sensitive 
Moisture Sensitive
InChI
InChI=1S/C18H22ClO2P/c1-11-7-15(8-12(2)17(11)20-5)22(19)16-9-13(3)18(21-6)14(4)10-16/h7-10H,1-6H3
InChIKey
JWCZKGYRAINWJA-UHFFFAOYSA-N
SMILES
P(C1=CC(C)=C(OC)C(C)=C1)(C1=CC(C)=C(OC)C(C)=C1)Cl
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-43-45
RIDADR 
UN3265
WGK Germany 
3
HazardClass 
8
PackingGroup 
II
Storage Class
8A - Combustible corrosive hazardous materials
Hazard Classifications
Skin Corr. 1B
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
695130
Product name
Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine
Packaging
100mg
Price
$75.8
Updated
2023/01/07
Sigma-Aldrich
Product number
695130
Product name
Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine
Packaging
500mg
Price
$176
Updated
2023/01/07
Strem Chemicals
Product number
15-0111
Product name
Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine, min. 98%
Packaging
500mg
Price
$77
Updated
2024/03/01
Strem Chemicals
Product number
15-0111
Product name
Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine, min. 98%
Packaging
2g
Price
$232
Updated
2024/03/01
Sigma-Aldrich
Product number
710385
Product name
Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine
Purity
95%
Packaging
1g
Price
$157
Updated
2025/07/31
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BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE Chemical Properties,Usage,Production

Uses

Reactant for:

  • Asymmetric organocatalytic electrophilic phosphination
  • Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands
  • Synthesis of ferrocene-based chiral diphosphines
  • Alcoholysis of phosphane-boranes
  • Asymmetric hydrogenations of bifep-type biferrocenes

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE Suppliers

Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
285
Advantage
55
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44802
Advantage
61
Beijing VSciChem Technology Co., Ltd.
Tel
13811761079
Email
vscichem@163.com
Country
China
ProdList
263
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51395
Advantage
80
Shanghai Haozhixiang Biotechnology Co., Ltd
Tel
526763801 13301653310
Fax
+86-21-51619052
Email
526763801@qq.com
Country
China
ProdList
9294
Advantage
55
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2280
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Aikon International Limited
Tel
025-58851090 15955137747
Fax
(6)02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
15949
Advantage
58
Shaoxing Zejun Pharmaceuticals Co.,Ltd
Tel
0575-82126188 15395856318
Email
nbzjyyservice@zejunpharma.com
Country
China
ProdList
476
Advantage
58
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View Lastest Price from BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE 136802-85-2
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-18
XINXIANG RUNYU MATERIAL CO., LTD.
Product
Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine 136802-85-2
Price
US $0.00-0.00/G
Min. Order
50G
Purity
96%+
Supply Ability
100KG
Release date
2024-11-18

136802-85-2, BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINERelated Search:


  • BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE
  • Chlorobis(3,5-dimethyl-4-methoxyphenyl)phosphine, 98+%
  • Bis(3,5-diMethyl-4-Methoxyphenyl)chlorophosphine,Min.98%
  • chloro-bis(4-methoxy-3,5-dimethylphenyl)phosphane
  • Phosphinous chloride, P,P-bis(4-methoxy-3,5-dimethylphenyl)-
  • Bis(3,5-dimethyl-4-methoxyphenyl)phosphinouschloride
  • 136802-85-2
  • C18H22ClO2P
  • organophosphine ligand