ChemicalBook > CAS DataBase List > 1,3,5-TribroMo-2,4,6-TriMethyl-Benzene

1,3,5-TribroMo-2,4,6-TriMethyl-Benzene

Product Name
1,3,5-TribroMo-2,4,6-TriMethyl-Benzene
CAS No.
608-72-0
Chemical Name
1,3,5-TribroMo-2,4,6-TriMethyl-Benzene
Synonyms
-Benzene;NSC 97124;ar-Tribromomesitylene;1,3,5-Trisbromomesitylene;1,3,5-Tribromotrimethylbenzene;1,3,5-TribroMo-2,4,6-TriMethyL;,3,5-Tribromo-2,4,6-trimethylbenzene;2,4,6-Tribromo-1,3,5-trimethylbenzene;2,4,6-Tribromo-2,4,6-trimethyl-benzene;1,3,5-TribroMo-2,4,6-TriMethyl-Benzene
CBNumber
CB52665264
Molecular Formula
C9H9Br3
Formula Weight
356.88
MOL File
608-72-0.mol
More
Less

1,3,5-TribroMo-2,4,6-TriMethyl-Benzene Property

Melting point:
225.5-226.5℃
Boiling point:
329.3±37.0 °C(Predicted)
Density 
1.910±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Heated), Hexanes (Slightly, Heated)
form 
Solid
color 
Pale Grey to Light Grey
InChI
InChI=1S/C9H9Br3/c1-4-7(10)5(2)9(12)6(3)8(4)11/h1-3H3
InChIKey
LTSSSVHTLGQZAQ-UHFFFAOYSA-N
SMILES
C1(Br)=C(C)C(Br)=C(C)C(Br)=C1C
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S97587
Product name
1,3,5-TRIBROMO-2,4,6-TRIMETHYL-BENZENE
Purity
Aldrich<sup>CPR</sup>
Packaging
1 unit
Price
$113
Updated
2025/07/31
Sigma-Aldrich
Product number
S109630
Product name
1,3,5-TRIBROMO-2,4,6-TRIMETHYL-BENZENE
Purity
Aldrich<sup>CPR</sup>
Packaging
1 unit
Price
$185
Updated
2025/07/31
Sigma-Aldrich
Product number
S97587
Product name
1,3,5-TRIBROMO-2,4,6-TRIMETHYL-BENZENE
Purity
AldrichCPR
Packaging
100MG
Price
$110
Updated
2024/03/01
Sigma-Aldrich
Product number
S109630
Product name
1,3,5-TRIBROMO-2,4,6-TRIMETHYL-BENZENE
Purity
AldrichCPR
Packaging
100MG
Price
$179
Updated
2024/03/01
TCI Chemical
Product number
T3516
Product name
1,3,5-Tribromo-2,4,6-trimethylbenzene
Purity
min. 98.0 %
Packaging
1G
Price
$58
Updated
2025/07/31
More
Less

1,3,5-TribroMo-2,4,6-TriMethyl-Benzene Chemical Properties,Usage,Production

Uses

1,3,5-Tribromo-2,4,6-Trimethylbenzene is a useful reagent for preparing highly durable superhydrophobic nanothorn arrays.

Synthesis

108-67-8

608-72-0

General procedure for the synthesis of 2,4,6-tribromo-1,3,5-trimethylbenzene from 1,3,5-trimethylbenzene: 1-methoxy-3,5-dimethylbenzene (100 mg, 0.73 mmol), N-bromosuccinimide (NBS, 260 mg, 1.46 mmol), and a stainless steel ball (5 mm in diameter) were placed in a 10 mL stainless steel grinding jar. The ball milling reaction was carried out and the reaction process was monitored by thin layer chromatography (TLC) and proton nuclear magnetic resonance (1H NMR). Upon completion of the reaction, the reaction mixture was transferred to 30 mL of ethyl acetate and cooled at 0 °C. The product in the filtrate and the precipitated spent succinimide were separated by filtration through filter paper. The filtrate was concentrated under vacuum to give 250 mg (85% yield) of 2,4,6-tribromo-1,3,5-trimethylbenzene as a colorless powder. To test the efficiency of the large-scale reaction, a monobromination reaction was also carried out with 1.3 g of 1-methoxy-3,5-dimethylbenzene for 1 h. The product was isolated in 87% yield. During the reaction, the grinding equipment was suspended and a small amount of sample was removed from the reaction tank for TLC and 1H NMR analysis, after which the reaction was continued, and the time of this operation was not included in the total reaction time.

References

[1] Bulletin of the Chemical Society of Japan, 1989, vol. 62, # 2, p. 439 - 443
[2] Organic Letters, 2003, vol. 5, # 4, p. 549 - 552
[3] Tetrahedron Letters, 1997, vol. 38, # 20, p. 3499 - 3502
[4] Journal of Materials Chemistry A, 2017, vol. 5, # 18, p. 8292 - 8296
[5] Organic Preparations and Procedures International, 1995, vol. 27, # 6, p. 652 - 656

1,3,5-TribroMo-2,4,6-TriMethyl-Benzene Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

1,3,5-TribroMo-2,4,6-TriMethyl-Benzene Suppliers

China 94 India 2 Japan 1 United States 4 Global 101
Henan Copyrene New Material Technology Co., Ltd.
Tel
13144621062
Email
15938783487@163.com
Country
China
ProdList
57
Advantage
58
Anhui Yongsheng Pharmaceutical Technology Co., Ltd
Tel
181-3307-5798 18017383231
Email
983544897@qq.com
Country
China
ProdList
921
Advantage
58
Shanghai Boyle Chemical Co., Ltd.
Tel
Fax
86-21-57758967
Email
sales@boylechem.com
Country
China
ProdList
2922
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Carbott PharmTech Inc.
Tel
0535-6385396
Fax
+86 (535) 638-9971
Email
info@carbottpharm.com
Country
China
ProdList
957
Advantage
56
Hunan Hui Bai Shi Biotechnology Co., Ltd.
Tel
0731-85526065 13308475853
Email
ivy@hnhbsj.com
Country
China
ProdList
7247
Advantage
62
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Changzhou Tianrui Pharmaceutical Technology Co., Ltd.
Tel
0519-85386832 13382812559
Fax
0519-85386832
Email
sales@cztrchem.com
Country
China
ProdList
1185
Advantage
56
Nanjing Chalf-Pharm Technology Co., Ltd.
Tel
025-57018978 18251899859
Fax
025-57018008
Email
sales@chalf-pharm.com
Country
China
ProdList
5674
Advantage
50
Zhengzhou Alfachem Co., Ltd.
Tel
0371-53765687 18937137882
Fax
QQ:2885373884
Email
2853979813@qq.com
Country
China
ProdList
7991
Advantage
55
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd
Tel
0431-0431-80514535 19917294565
Email
et@chemextension.com
Country
China
ProdList
3935
Advantage
55
Codow Chemical Co.,Ltd.
Tel
18620099427
Fax
+86-20-62619665
Email
amy@howeipharm.com
Country
China
ProdList
6687
Advantage
55
Shanghai Xilong Biochemical Technology Co., Ltd.
Tel
021-52907766-8042
Fax
021-52906523
Country
China
ProdList
9941
Advantage
58
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
Advantage
60
Shanghai Changyan Chem & Tech Co., Ltd.
Tel
021-20242659 18930833303
Fax
+86 (21) 2024-2659
Email
Sales@changyanchem.cn
Country
China
ProdList
5001
Advantage
55
Zhengzhou AnMusi Chemical Products Co., Ltd.
Tel
0371-55289822 18737195735
Fax
QQ：2370407954
Email
2370407954@qq.com
Country
China
ProdList
1981
Advantage
55
Zhengzhou Acme Chemical Co., Ltd.
Tel
0371-0371-55629727 13323845623
Fax
037155629727
Email
2885676761@qq.com
Country
China
ProdList
10110
Advantage
58
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Hubei Hongxin Ruiyu Fine Chemical Co., Ltd.
Tel
027-027-65526929 15102793023
Fax
027-65526669
Email
hbhxry@foxmail.com
Country
China
ProdList
1786
Advantage
55
Shanghai CR Corporation Limited
Tel
13062833949; 4006653949 4006653949
Fax
QQ: 2136646215
Email
fred.wen@crcorporation.cn
Country
China
ProdList
9757
Advantage
58
JinJin Le Chemical Co., Ltd
Tel
18001959627(微信同号) 18001959627
Email
jjlchem2@163.com
Country
China
ProdList
9981
Advantage
58
Zhengzhou JACS Chemical Co., Ltd.
Tel
0371-0371-86259281 15981966935
Fax
0371-86259281
Email
jacschem@163.com
Country
China
ProdList
2005
Advantage
58
Shenzhen Regent Biochemical Technology Co., Ltd.
Tel
0755-85201366 18938635012
Fax
0755-85201366
Email
sales@regentsciences.com
Country
China
ProdList
9751
Advantage
58
Aikon International Limited
Tel
025-66061636 18013972705
Fax
(3)02557626880
Email
qqyang@aikonchem.com
Country
China
ProdList
15814
Advantage
58
Wuhan FengyaoTonghui Chemical Products Co., Ltd.
Tel
027-87466105 15377573527
Email
2678564200@qq.com
Country
China
ProdList
17987
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 400821072
Fax
021-58955996
Email
malulu@leyan.com
Country
China
ProdList
25000
Advantage
58
Zhengzhou Ruke Biological Co., Ltd.
Tel
15981811963
Fax
QQ：1410472904
Email
1410472904@qq.com
Country
China
ProdList
5825
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52687
Advantage
58
Cool Pharm, Ltd
Tel
021-58581007 18019463053
Fax
021-50966098
Email
sales@coolpharm.com
Country
China
ProdList
12878
Advantage
58
Suzhou Adelaide Chemical Technology Co., Ltd.
Tel
15995785122
Email
3003020078@qq.com
Country
China
ProdList
1198
Advantage
58
Henan Wittig Chemical Technology Co. Ltd.
Tel
0371-55153829
Email
891701645@qq.com
Country
China
ProdList
107
Advantage
58
Hubei Hongxin Ruiyu Fine Chemical Co., Ltd.
Tel
027-027-65385071 17771822910
Fax
027-65526669
Email
shelleyl.meng@foxmail.com
Country
China
ProdList
2354
Advantage
58
Zhengzhou Alfa Chemical Co.,Ltd
Tel
+8618530059196
Email
sale04@alfachem.cn
Country
China
ProdList
11784
Advantage
58
Allfluoro pharmaceutical co. ltd.
Tel
+86-400-0216110 +86-15958047586
Fax
0086-21-33275002
Email
sales@allfluoro.com
Country
China
ProdList
11385
Advantage
58
Shanghai Daeyeon Chemicals Co., Ltd
Tel
021-64478606 +8615900664856
Email
daeyeon001@vip.163.com
Country
China
ProdList
2062
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418671 +8618949823763
Fax
0551-65418697
Email
sales@tnjchem.com
Country
China
ProdList
34563
Advantage
58
CD Chemical Group Limited
Tel
+8615986615575
Fax
0086-13651442114
Email
info@codchem.com
Country
China
ProdList
20342
Advantage
58
Shaanxi Dideu Medichem Co. Ltd
Tel
+86-029-89586680 +86-18192503167
Fax
+86-29-88380327
Email
1026@dideu.com
Country
China
ProdList
8025
Advantage
58
Win-Win chemical CO., Limited
Tel
+86-0086-577-64498589 +86-15355981851
Fax
0086-577-56994596
Email
sales@win-winchemical.com
Country
China
ProdList
14359
Advantage
58
Career Henan Chemica Co
Tel
+86-0371-86658258 +8613203830695
Fax
0371-86658258
Email
laboratory@coreychem.com
Country
China
ProdList
30229
Advantage
58
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd.
Tel
0431-80514535 13634302652
Fax
0431-88607838
Email
Extension@chemextension.com
Country
CHINA
ProdList
967
Advantage
58
Shanghai TenSus Biotechnology Co., Ltd.
Tel
021-50895067 18616507272
Fax
021-50895067
Email
tensus@163.com
Country
China
ProdList
8073
Advantage
58
Zhengzhou Edward Biology Co.,Ltd
Tel
0371-63682289 15538176268
Fax
QQ：1875164801
Email
jacschem@163.com
Country
China
ProdList
9926
Advantage
58
Shanghai Kaiwei Chemical Technology Co., Ltd.
Tel
021-58461859 15821823057
Email
service@aiviche.com
Country
China
ProdList
49312
Advantage
58
Hangzhou Oder Technology Co., Ltd.
Tel
0571-88772972-0 15057128248
Email
2746615063@qq.com
Country
China
ProdList
1106
Advantage
58
Beijing Haite lesk Technology Co., Ltd
Tel
15210893940; 15116916250
Fax
QQ: 237008221
Email
chemistryliu@163.com
Country
China
ProdList
7327
Advantage
58
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd
Tel
0431-80534350 15044023330
Email
caoy@chemextension.com
Country
China
ProdList
2016
Advantage
58
Fuxin Pharmaceutical
Tel
+86-021-021-50872116 +8613122107989
Email
contact@fuxinpharm.com
Country
China
ProdList
10000
Advantage
58
Wuhan ShuEr Biology Technology Co.,Ltd
Tel
027-15827133616-6 15827133616
Fax
QQ 1799696397
Email
1799696397@qq.com
Country
China
ProdList
2582
Advantage
58

608-72-0, 1,3,5-TribroMo-2,4,6-TriMethyl-BenzeneRelated Search:

2,4,6-trimethyl-1,3,5-triazine 2,4,6-trimethylbenzene-1,3,5-tricarboxylic acid 1,3,5-BENZENETRICARBONITRILE,2,4,6-TRIMETHYL- Benzaldehyde,4,4',4”-(1,3,5-triazine-2,4,6-triyl)tris- 2,4,6-Trimethylpyridine-3,5-dicarbonitrile

  • 1,3,5-Tribromotrimethylbenzene
  • 1,3,5-Trisbromomesitylene
  • ar-Tribromomesitylene
  • NSC 97124
  • Benzene,1,3,5-tribromo-2,4,6-trimethyl-
  • 2,4,6-Tribromo-1,3,5-trimethylbenzene
  • 1,3,5-TribroMo-2,4,6-TriMethyl-Benzene
  • 2,4,6-Tribromo-2,4,6-trimethyl-benzene
  • 1,3,5-TribroMo-2,4,6-TriMethyL
  • ,3,5-Tribromo-2,4,6-trimethylbenzene
  • -Benzene
  • 1,3,5-TribroMo-2,4,6-TriMethyl-Benzene ISO 9001：2015 REACH
  • 608-72-0