(4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyl-Oxazole

Product Name: (4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyl-Oxazole
CAS No.: 157904-67-1
Chemical Name: (4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyl-Oxazole
Synonyms: （4R，4'R，5S，5'S）-;(R,S)-BisPh-propabBox;(4R,4μR,5S,5μS)-2,2μ-(1-Methylethylidene;(4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene 95%;2,2-Bis[2-(4R,5S-diphenyl-1,3-oxazolinyl)]propane, 95%;(4R,4’R,5S,5’S)-2,2’-(Propane-2,2-diyl)bis(4,5-diphenyl-4,5-dihydrooxazole);(4R,4’R,5S,5’S)-2,2’-(Propane-2,2-diyl)bis(4,5-diphenyl-4,5-dihydrooxazole);(4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole;(4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyl-Oxazole;(4R,4''R,5S,5''S)-2,2''-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole]
CBNumber: CB52707784
Molecular Formula: C33H30N2O2
Formula Weight: 486.6
MOL File: 157904-67-1.mol

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(4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyl-Oxazole Property

Melting point:: 164-169°C
Boiling point:: 606.7±55.0 °C(Predicted)
Density: 1.16±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
pka: 4.33±0.70(Predicted)

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Safety

Safety Statements: 24/25
WGK Germany: 3
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 795682
Product name: (4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene
Purity: 95%
Packaging: 250mg
Price: $290
Updated: 2024/03/01

Strem Chemicals

Product number: 07-1378
Product name: (4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole], 98%, (99% ee)
Packaging: 50mg
Price: $101
Updated: 2024/03/01

Frontier Specialty Chemicals

Product number: JK1836137
Product name: 2,2-Bis[2-(4R,5S-diphenyl-1,3-oxazolinyl)]propane
Packaging: 50mg
Price: $54
Updated: 2021/12/16

Ambeed

Product number: A204877
Product name: (4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole
Purity: 98%99%ee
Packaging: 50mg
Price: $61
Updated: 2021/12/16

Ambeed

Product number: A204877
Product name: (4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole
Purity: 98%99%ee
Packaging: 100mg
Price: $108
Updated: 2021/12/16

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(4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyl-Oxazole Chemical Properties,Usage,Production

Uses

(4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene) or (4S,5R)-Bis-Phbox) can be used as a ligand:

To prepare selective exo-catalysts for enantioselective 1,3-dipolar cycloaddition reactions.
In the asymmetric aminooxygenation of alkenes in the presence of tetramethylaminopyridyl radical (TEMPO) as an oxidant and copper(II) triflate as a catalyst.
In asymmetric aminofluorination of olefins using an iron catalyst.

This chiral Box ligand was most recently shown to mediate an asymmetric aminofluorination of olefins utlizing Xtalfuor-E (719439) and TREAT-HF (344648). The resulting cyclic carbamates can be readily converted into their concomitant beta-fluoro amino acids.

(4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyl-Oxazole Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyl-Oxazole manufacturers

R&D Scientific Inc.

Product: (4R,4'R,5S,5'S)-2,2'-(Propane-2,2-diyl)bis(4,5-diphenyl-4,5-dihydrooxazole) 157904-67-1
Price: US $1780.00/g
Min. Order: 1g
Purity: 98
Supply Ability: 500 Kg
Release date: 2024-04-24

157904-67-1, (4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyl-OxazoleRelated Search:

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157904-67-1