ChemicalBook > CAS DataBase List > N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine

N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine

Product Name
N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine
CAS No.
1010396-31-2
Chemical Name
N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine
Synonyms
VNPB;4,4′-Bis[(1-naphthyl)(4-styryl)amino][1,1′]biphenyl;N,N'-Bis(naphthalen-1-yl)-N,N'-bis(4-vinyl-phenyl)benzidine;N4,N4'-Di(naphthalen-1-yl)-N4,N4'-bis(4-vinylphenyl)biphenyl-4,4'-diamine;N4,N4′-di(Naphthalen-1-yl)-N4,N4′-bis(4- vinylphenyl)biphenyl-4,4′-diamine;N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine;N4,N4'-Di(naphthalen-1-yl)-N4,N4'-bis(4-vinylphenyl)-[1,1'-biphenyl]-4,4'-diamine;[1,1'-Biphenyl]-4,4'-diamine, N4,N4'-bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-;N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine ISO 9001:2015 REACH
CBNumber
CB52717671
Molecular Formula
C48H36N2
Formula Weight
640.81
MOL File
1010396-31-2.mol
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N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine Property

Boiling point:
825.3±65.0 °C(Predicted)
Density 
1.192±0.06 g/cm3(Predicted)
solubility 
THF: soluble
chloroform: soluble
toluene: soluble
pka
0.06±0.50(Predicted)
λmax
350 nm±5 nm in THF (UV)
InChIKey
WTEWXIOJLNVYBZ-UHFFFAOYSA-N
SMILES
C1(C2=CC=C(N(C3=CC=C(C=C)C=C3)C3=C4C(C=CC=C4)=CC=C3)C=C2)=CC=C(N(C2=CC=C(C=C)C=C2)C2=C3C(C=CC=C3)=CC=C2)C=C1
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Hazard and Precautionary Statements (GHS)

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N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine Chemical Properties,Usage,Production

Uses

N4,N4μ-Di(naphthalen-1-yl)-N4,N4μ-bis(4-vinylphenyl)biphenyl-4,4μ-diamine, also known as VNPB, is a solution-processable Hole Transport / Electron Blocking Layer (HTL / EBL) material popularly used in organic electronics, such as OLEDs and perovskite solar cells .
In OLED devices, the use of VNPB enabled the maximum current efficiency of 22.2 Cd/A, compared to 9.7 Cd/A in the reference device without VNPB, and the device lifetime was extended by up to 74.8% . VNPB allowed a simple and additive-free strategy to prevent the formation of defects in solution processed thin-film stacks made of small-molecular materials.
In solar cells, VNPB increased open-circuit voltage (VOC) and power conversion efficiency (PCE) of wide-bandgap perovskite solar cells by changing the hole transport layer (HTL) from commonly used poly(bis(4-phenyl)(2,4,6-trimethylphenyl)amine) (PTAA) to in-situ cross-linked small mol. VNPB . PCEs of 24.9% and 25.4% have been achieved in perovskite/perovskite and perovskite/silicon tandem solar cells, resp.

N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine Preparation Products And Raw materials

Raw materials

Preparation Products

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N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine Suppliers

Shanghai Uchem Inc.
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15618758386 15618758386
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Shine Materials Technology Co., Ltd
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1010396-31-2, N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamineRelated Search:


  • N4,N4′-di(Naphthalen-1-yl)-N4,N4′-bis(4- vinylphenyl)biphenyl-4,4′-diamine
  • VNPB
  • N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine
  • N,N'-Bis(naphthalen-1-yl)-N,N'-bis(4-vinyl-phenyl)benzidine
  • [1,1'-Biphenyl]-4,4'-diamine, N4,N4'-bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-
  • N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine ISO 9001:2015 REACH
  • 4,4′-Bis[(1-naphthyl)(4-styryl)amino][1,1′]biphenyl
  • N4,N4'-Di(naphthalen-1-yl)-N4,N4'-bis(4-vinylphenyl)-[1,1'-biphenyl]-4,4'-diamine
  • N4,N4'-Di(naphthalen-1-yl)-N4,N4'-bis(4-vinylphenyl)biphenyl-4,4'-diamine
  • 1010396-31-2