ChemicalBook > CAS DataBase List > 1-Methylcyclopentyl methacrylate

1-Methylcyclopentyl methacrylate

Product Name
1-Methylcyclopentyl methacrylate
CAS No.
178889-45-7
Chemical Name
1-Methylcyclopentyl methacrylate
Synonyms
MCPMA;1-Methylcyclopentyl methacrylate;MCPMA 1-Methylcyclopentyl methacrylate;1-Methylcyclopentyl methacrylate (MCPMA);Methacrylic Acid 1-Methylcyclopentyl Ester;(1-Methylcyclopentyl) 2-methylprop-2-enoate;1-Methylcyclopentyl methacrylate 178889-45-7;1-Methylcyclopentyl methacrylate MCPMA ArF monomers;2-Propenoic acid, 2-methyl-, 1-methylcyclopentyl ester;1-Methylcyclopentyl Methacrylate (stabilized with MEHQ)
CBNumber
CB52717727
Molecular Formula
C10H16O2
Formula Weight
168.23
MOL File
178889-45-7.mol
More
Less

1-Methylcyclopentyl methacrylate Property

Boiling point:
205.2±9.0 °C(Predicted)
Density 
0.96±0.1 g/cm3(Predicted)
Flash point:
74 °C
storage temp. 
Room temperature ( recommended cool, dark place below 15°C)
form 
clear liquid
Specific Gravity
0.95
color 
Colorless to Light yellow
InChI
InChI=1S/C10H16O2/c1-8(2)9(11)12-10(3)6-4-5-7-10/h1,4-7H2,2-3H3
InChIKey
VSYDNHCEDWYFBX-UHFFFAOYSA-N
SMILES
C(OC1(C)CCCC1)(=O)C(C)=C
More
Less

Safety

HS Code 
2916.14.2050
More
Less

Hazard and Precautionary Statements (GHS)

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
M3228
Product name
1-Methylcyclopentyl Methacrylate (stabilized with MEHQ)
Packaging
1G
Price
$59
Updated
2024/03/01
TCI Chemical
Product number
M3228
Product name
1-Methylcyclopentyl Methacrylate (stabilized with MEHQ)
Packaging
5G
Price
$192
Updated
2023/01/07
AK Scientific
Product number
9608CV
Product name
1-Methylcyclopentylmethacrylate
Packaging
5g
Price
$307
Updated
2021/12/16
AK Scientific
Product number
9608CV
Product name
1-Methylcyclopentylmethacrylate
Packaging
1g
Price
$124
Updated
2021/12/16
More
Less

1-Methylcyclopentyl methacrylate Chemical Properties,Usage,Production

Description

1-Methylcyclopentyl methacrylate, also known as Methacrylic Acid 1-Methylcyclopentyl Ester, is a organic compound. It is commonly used as the Photoresist monomer. Photoresist (photo reactive materials) is a light-sensitive material used in several processes, such as photolithography and photoengraving, to form a patterned coating on a surface. Lithographic techniques such as deep X-ray lithography (DXRL), X-ray lithography (XRL), deep ultraviolet lithography (DUVL) and ultraviolet lithography (UVL) rely on this material[1].

Chemical Properties

Colorless to Light yellow clear liquid

Uses

1-Methylcyclopentyl methacrylate is used as Photoresist monomer.

Preparation

The preparation of 1-Methylcyclopentyl methacrylate is as follows:Add 1-methylcyclopentanol (730g, 7.29mol), dichloromethane (5100g), triethylamine (1819g, 17.98mol), 4-dimethylaminopyridine (8.9g, 0.0728mol) to the 10L four-necked flask Stirring and cooling with phenothiazine (7.3g) were started, and methacryloyl chloride (1143g, 10.93mol) was added dropwise at a temperature of 0 to 5℃., and the temperature was kept for 2h after the dropwise addition. (raw material≦2.0%).Water (2000g) was added to quench, and the temperature was controlled not to exceed 20℃. The organic phase was washed twice with 5% hydrochloric acid (2000g*2), twice with 5% aqueous sodium hydroxide solution (2000g*2), and twice with water (2000g*2), the organic phase was dried by adding anhydrous sodium sulfate, and spun. The solvent was evaporated and concentrated to obtain 1268g of crude product. The crude product was distilled under reduced pressure (negative pressure: 1mmHg column, external temperature: 60-70℃., main fraction: 35-40℃.) to obtain 921g of product.

Application

1-Methylcyclopentyl methacrylate can be applied in analog semiconductor, light-emitting diode LED, solar photovoltaic and other fields.

Solubility in organics

Very soluble in N,N-Dimethylformamide. Soluble in methanol. Sparingly soluble inglacial acetic acid. Very slightly soluble inchloroform. Practically insoluble in water.

References

[1] Vlnieska V, et al. Epoxy Resins for Negative Tone Photoresists. Polymers, 2019; 11: 1457.

1-Methylcyclopentyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

1-Methylcyclopentyl methacrylate Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
More
Less

View Lastest Price from 1-Methylcyclopentyl methacrylate manufacturers

Shanghai Qyubiotech Co., Ltd.
Product
1-Methylcyclopentyl methacrylate 178889-45-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%+
Supply Ability
100000kg per Month
Release date
2023-04-14
Apeloa production Co.,Limited
Product
1-Methylcyclopentyl methacrylate 178889-45-7
Price
US $1.00/g
Min. Order
1g
Purity
0.98
Supply Ability
1000
Release date
2024-07-19
Changzhou waston chemical technology Co.,Ltd
Product
1-Methylcyclopentyl methacrylate 178889-45-7
Price
US $0.00/L
Min. Order
1L
Purity
GC/LC≥99%
Supply Ability
According to customer requirements
Release date
2022-10-11

178889-45-7, 1-Methylcyclopentyl methacrylateRelated Search:


  • 1-Methylcyclopentyl methacrylate
  • MCPMA 1-Methylcyclopentyl methacrylate
  • 1-Methylcyclopentyl methacrylate MCPMA ArF monomers
  • 1-Methylcyclopentyl methacrylate 178889-45-7
  • 2-Propenoic acid, 2-methyl-, 1-methylcyclopentyl ester 178889-45-7
  • 2-Propenoic acid, 2-methyl-, 1-methylcyclopentyl ester
  • 1-Methylcyclopentyl Methacrylate (stabilized with MEHQ)
  • Methacrylic Acid 1-Methylcyclopentyl Ester
  • 1-Methylcyclopentyl methacrylate (MCPMA)
  • MCPMA
  • (1-Methylcyclopentyl) 2-methylprop-2-enoate
  • 178889-45-7
  • 178880-45-7