N,N-DIMETHYL-3-FLUOROANILINE
- Product Name
- N,N-DIMETHYL-3-FLUOROANILINE
- CAS No.
- 2107-43-9
- Chemical Name
- N,N-DIMETHYL-3-FLUOROANILINE
- Synonyms
- 3-Fluoro-N,N-diMethylaniline;N,N-DIMETHYL-3-FLUOROANILINE;1-(DIMETHYLAMINO)-3-FLUOROBENZENE;1-Fluoro-3-(dimethylamino)benzene;3-Fluoro-N,N-dimethyl-benzenamine;Benzenamine, 3-fluoro-N,N-dimethyl-;Benzenamine, 3-fluoro-2,4-dimethyl-
- CBNumber
- CB5282218
- Molecular Formula
- C8H10FN
- Formula Weight
- 139.17
- MOL File
- 2107-43-9.mol
N,N-DIMETHYL-3-FLUOROANILINE Property
- storage temp.
- Sealed in dry,Room Temperature
Safety
- Hazard Codes
- Xi
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36/37/39
- RIDADR
- 1993
- Hazard Note
- Irritant
- HazardClass
- 3
- PackingGroup
- Ⅲ
- HS Code
- 2921490090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- F600155
- Product name
- 3-Fluoro-N,N-dimethylaniline
- Packaging
- 100mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- HCH0000659
- Product name
- 1-(DIMETHYLAMINO)-3-FLUOROBENZENE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $499.65
- Updated
- 2021/12/16
- Product number
- CM251302
- Product name
- 3-Fluoro-N,N-dimethylaniline
- Purity
- 95+%
- Packaging
- 10g
- Price
- $677
- Updated
- 2021/12/16
- Product number
- CD12096731
- Product name
- 3-Fluoro-N,N-dimethylaniline
- Purity
- 97%
- Packaging
- 10g
- Price
- $717
- Updated
- 2021/12/16
- Product number
- A199409
- Product name
- 3-Fluoro-N,N-dimethylaniline
- Purity
- 97%
- Packaging
- 250mg
- Price
- $43
- Updated
- 2021/12/16
N,N-DIMETHYL-3-FLUOROANILINE Chemical Properties,Usage,Production
Synthesis
124-38-9
1978-37-6
2107-43-9
The general procedure for the synthesis of 3-fluoro-N,N-dimethylaniline from carbon dioxide and 3-fluoro-N-methylaniline was as follows: the methylation of various secondary amines was carried out using the general method Example II. The specific operating conditions were as follows: the substituted aromatic amines (1.0 mmol), [Ru(Triphos)(TMM)] (2.5 mol%), and HNTf2 (5 mol%) were dissolved in THF (2 mL), and reacted at 150 °C under a CO2/H2 (20/60 bar) atmosphere. The reaction time and yield data are detailed in Table II below.The reaction times and corresponding yields for different amine substrates are listed in Table II.
References
[1] Patent: WO2015/753, 2015, A1. Location in patent: Page/Page column 8-9
[2] Chemical Science, 2013, vol. 4, # 5, p. 2127 - 2131
[3] Angewandte Chemie - International Edition, 2013, vol. 52, # 36, p. 9554 - 9557
[4] Angew. Chem., 2013, vol. 125, # 36, p. 9733 - 9736
[5] Patent: EP2821397, 2015, A1. Location in patent: Paragraph 0039; 0041
N,N-DIMETHYL-3-FLUOROANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
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