ChemicalBook > CAS DataBase List > [1,1
[1,1
- Product Name
- [1,1
- CAS No.
- 134-52-1
- Chemical Name
- [1,1
- Synonyms
- 2,4-BIPHENYLDIOL;4-Phenyl resorcinol;1,1'-Biphenyl]-2,4-diol;4-PHENYLBENZENE-1,3-DIOL;4-phenyl-1,3-dihydroxybenzene
- CBNumber
- CB53043331
- Molecular Formula
- C12H10O2
- Formula Weight
- 186.21
- MOL File
- 134-52-1.mol
More
Less
[1,1 Property
- Melting point:
- 145 °C
- Boiling point:
- 378.9±12.0 °C(Predicted)
- Density
- 1.228±0.06 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- 9.66±0.18(Predicted)
- InChI
- InChI=1S/C12H10O2/c13-10-6-7-11(12(14)8-10)9-4-2-1-3-5-9/h1-8,13-14H
- InChIKey
- LYXCJGJSIWFKHZ-UHFFFAOYSA-N
- SMILES
- C1(C2=CC=CC=C2)=CC=C(O)C=C1O
More
Less
Safety
- Toxicity
- LD50 ipr-mus: 100 mg/kg VCVGK*-,241,1994
More
Less
More
Less
N-Bromosuccinimide Price
TRC
- Product number
- P321655
- Product name
- 4-phenylbenzene-1,3-diol
- Packaging
- 10mg
- Price
- $65
- Updated
- 2021/12/16
AK Scientific
- Product number
- 3182CS
- Product name
- [1,1'-Biphenyl]-2,4-diol
- Packaging
- 100mg
- Price
- $72
- Updated
- 2021/12/16
AK Scientific
- Product number
- 3182CS
- Product name
- [1,1'-Biphenyl]-2,4-diol
- Packaging
- 250mg
- Price
- $82
- Updated
- 2021/12/16
AK Scientific
- Product number
- 3182CS
- Product name
- [1,1'-Biphenyl]-2,4-diol
- Packaging
- 5g
- Price
- $193
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 121383
- Product name
- 4-Phenylresorcinol
- Purity
- 95%
- Packaging
- 1g
- Price
- $480
- Updated
- 2021/12/16
More
Less
[1,1 Chemical Properties,Usage,Production
Hazard
A poison by skin contact.
Safety Profile
A poison by intraperitoneal ndskin contact routes. When heated to decomposition itemits acrid smoke and irritating vapors.
Synthesis
6626-15-9
98-80-6
134-52-1
(a) Step 1 was synthesized with reference to known literature (). 4-Bromoresorcinol (0.42 g, 2.2 mmol) was dissolved in 1,2-dimethoxyethane (10 mL), phenylboronic acid (0.37 g, 3.0 mmol) and 2M aqueous sodium carbonate solution (3.5 mL) were added sequentially and the mixture was stirred at room temperature. Under argon protection, tetrakis(triphenylphosphine)palladium(0) (0.14 g, 0.12 mmol) was added to the reaction system, followed by placing the reaction mixture in a sealed tube and stirring the reaction for 6 hours at 95 °C. After completion of the reaction, ice water was added to the mixture and extracted with ethyl acetate. The organic layer was washed sequentially with water and saturated saline and dried over anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure and the residue was purified by silica gel column chromatography with hexane/ethyl acetate (75:25) as eluent to afford [1,1'-biphenyl]-2,4-diol (0.25 g, 61% yield).1H NMR (300 MHz, DMSO-d6) δ 6.30 (dd, J = 2.2 Hz, 8.8 Hz, 1H), 6.40 (d, J = 2.2 Hz, 1H), 7.04 (d, J = 8.8 Hz, 1H), 7.20 (m, 1H), 7.33 (m, 2H), 7.47 (d, J = 7.3 Hz, 2H), 9.31 (s, 1H), 9.34 (s, 1H).
References
[1] Patent: EP2565192, 2013, A1. Location in patent: Paragraph 0180
[1,1 Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
[1,1 Suppliers
- Tel
- 0512-62910395 17751098781
- Fax
- 0512-62910396
- sales@crstpharma.com
- Country
- China
- ProdList
- 499
- Advantage
- 58
- Tel
- sales@ahpharmatech.com
- Country
- China
- ProdList
- 5734
- Advantage
- 55
- Tel
- 0371-53778726 18003825608
- Fax
- QQ：2885354392
- liuxiaoyan@alfachem.cn
- Country
- China
- ProdList
- 1987
- Advantage
- 58
- Tel
- 021-61312847; 18021002903
- Fax
- QQ:3008007432
- 3008007409@qq.com
- Country
- China
- ProdList
- 71826
- Advantage
- 60
- Tel
- 025-66061636 18013972705
- Fax
- (3)02557626880
- qqyang@aikonchem.com
- Country
- China
- ProdList
- 15814
- Advantage
- 58
- Tel
- +86-021-34783353 15000719740
- Fax
- QQ765016903
- baynoe@baynoe.com
- Country
- China
- ProdList
- 487
- Advantage
- 58
- Tel
- 021-52836897 13917661608
- info@spring-chem.com
- Country
- China
- ProdList
- 2023
- Advantage
- 58
- Tel
- 021-021-54382182 18601603956
- 18601603956@163.com
- Country
- China
- ProdList
- 1255
- Advantage
- 58
- Tel
- 0512-65816829 18662214788
- Fax
- 0512-65816829
- info@rovathin.com.cn
- Country
- China
- ProdList
- 9987
- Advantage
- 58
- Tel
- 021-021-54321516 17717324060
- 2719672468@qq.com
- Country
- China
- ProdList
- 2032
- Advantage
- 58
- Tel
- 0751-2886766 13927870850
- Fax
- 0751-2886756
- 3001267247@qq.com
- Country
- China
- ProdList
- 9941
- Advantage
- 58
- Tel
- +86-0371-86658258 +8613203830695
- Fax
- 0086-371-86658258
- factory@coreychem.com
- Country
- China
- ProdList
- 29798
- Advantage
- 58
- Tel
- 18503026267
- info@antaichem.com
- Country
- CHINA
- ProdList
- 9636
- Advantage
- 58
- Tel
- 021-58432009 400-005-6266
- Fax
- 021-58436166
- marketing1@energy-chemical.com
- Country
- China
- ProdList
- 44894
- Advantage
- 58
- Tel
- 021-51816796-820 13611835272
- Fax
- 021-5161 3951
- sales2@sunwaypharm.com
- Country
- China
- ProdList
- 44119
- Advantage
- 58
- Tel
- 400-8210725 4008210725
- malulu@leyan.com
- Country
- China
- ProdList
- 40000
- Advantage
- 58
- Tel
- 13456210265
- Fax
- 13355928635
- 3578746376@qq.com
- Country
- China
- ProdList
- 843
- Advantage
- 58
- Tel
- 021-52230662 13795399395
- seaman79@126.com
- Country
- China
- ProdList
- 268
- Advantage
- 58
- Tel
- 400-1647117 13681763483
- product02@bidepharm.com
- Country
- China
- ProdList
- 59936
- Advantage
- 58
- Tel
- 400-6005915
- sales@picasso-e.com
- Country
- China
- ProdList
- 39653
- Advantage
- 58
- Tel
- +86(21)5895 0110 19945755304
- sales@chemany.com
- Country
- China
- ProdList
- 9984
- Advantage
- 58
- Tel
- 021-021-50706066 15221275939
- shenlinxing@macklin.cn
- Country
- China
- ProdList
- 29784
- Advantage
- 58
- Tel
- 15618536883
- 1228181347@qq.com
- Country
- China
- ProdList
- 7951
- Advantage
- 58
- Tel
- 010-50973130 17801761073
- Gsiyu@solarbio.com
- Country
- China
- ProdList
- 50751
- Advantage
- 58
- Tel
- 4000255188
- sales@pharmablock.com
- Country
- China
- ProdList
- 7268
- Advantage
- 58
- Tel
- 15555063509
- 153666767@qq.com
- Country
- China
- ProdList
- 2751
- Advantage
- 58
- Tel
- 021-50795510 4000665055
- syeu@accelachem.com
- Country
- China
- ProdList
- 11015
- Advantage
- 58
- Tel
- 0745-2866551 19976851779
- 3002713163@qq.com
- Country
- China
- ProdList
- 7333
- Advantage
- 58
- Tel
- 021-34783353 15572194250
- 1197363448@qq.com
- Country
- China
- ProdList
- 1295
- Advantage
- 58
- Tel
- 51288865780
- sales@biosynth.com
- Country
- China
- ProdList
- 6051
- Advantage
- 58
- Tel
- +8613817748580
- Fax
- 021-50175322
- cooperation@kean-chem.com
- Country
- China
- ProdList
- 40066
- Advantage
- 58
- Tel
- +86-512-68323658 +86-18168183658
- sales1@artkmedchem.com
- Country
- China
- ProdList
- 39002
- Advantage
- 58
- Tel
- +86-371-86557731 +86-13613820652
- Fax
- 86-0371-86557731
- info@fdachem.com
- Country
- China
- ProdList
- 20136
- Advantage
- 58
- Tel
- +86-571-87711850
- market18@leapchem.com
- Country
- China
- ProdList
- 43339
- Advantage
- 58
- Tel
- +86-16632316109
- xinshengkeji@xsmaterial.com
- Country
- China
- ProdList
- 1085
- Advantage
- 58
- Tel
- +8613524650931
- jason@kosinbio.com
- Country
- China
- ProdList
- 953
- Advantage
- 58
- Tel
- +86-13004516015 +86-18149392822
- christina@laingbiotec.com
- Country
- China
- ProdList
- 777
- Advantage
- 58
- Tel
- 13032137268
- 171198252@qq.com
- Country
- China
- ProdList
- 130
- Advantage
- 58
- Tel
- --
- Fax
- --
- 3245176082@qq.com
- Country
- CHINA
- ProdList
- 6800
- Advantage
- 58
More
Less
View Lastest Price from [1,1 manufacturers
Henan Fengda Chemical Co., Ltd
- Product
- [1,1'-Biphenyl]-2,4-diol 134-52-1
- Price
- US $101.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-29
Hebei Xinsheng New Material Technology Co., LTD.
- Product
- [1,1'-Biphenyl]-2,4-diol 134-52-1
- Price
- US $35.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 Ton
- Release date
- 2023-11-08
Career Henan Chemical Co
- Product
- [1,1'-Biphenyl]-2,4-diol 134-52-1
- Price
- US $6.68/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 1kg-1000kg
- Release date
- 2020-01-10