3'-CHLOROMETHYLACETOPHENONE
- Product Name
- 3'-CHLOROMETHYLACETOPHENONE
- CAS No.
- 41908-12-7
- Chemical Name
- 3'-CHLOROMETHYLACETOPHENONE
- Synonyms
- SKL141;3'-CHLOROMETHYLACETOPHENONE;1-(3-(chloroMethyl)phenyl)ethanone;1-[3-(chloroMethyl)phenyl]ethan-1-one;Ethanone, 1-[3-(chloromethyl)phenyl]-;3′-Chloromethylacetophenone, CAS 41908-12-7
- CBNumber
- CB5307627
- Molecular Formula
- C9H9ClO
- Formula Weight
- 168.62
- MOL File
- 41908-12-7.mol
3'-CHLOROMETHYLACETOPHENONE Property
- Boiling point:
- 130-131 °C(Press: 7 Torr)
- Density
- 1.134±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
Safety
- HS Code
- 2914790090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P321Specific treatment (see … on this label).
P322Specific measures (see …on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P363Wash contaminated clothing before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- C597860
- Product name
- 1-(3-(Chloromethyl)phenyl)ethanone
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- FC154867
- Product name
- 1-(3-(Chloromethyl)phenyl)ethanone
- Packaging
- 100mg
- Price
- $100
- Updated
- 2021/12/16
- Product number
- W6202
- Product name
- 1-(3-(Chloromethyl)phenyl)ethanone
- Packaging
- 1g
- Price
- $178
- Updated
- 2021/12/16
- Product number
- FC154867
- Product name
- 1-(3-(Chloromethyl)phenyl)ethanone
- Packaging
- 250mg
- Price
- $180
- Updated
- 2021/12/16
- Product number
- OR964995
- Product name
- 3'-Chloromethylacetophenone
- Purity
- 95%
- Packaging
- 250mg
- Price
- $182
- Updated
- 2021/12/16
3'-CHLOROMETHYLACETOPHENONE Chemical Properties,Usage,Production
Synthesis
917-54-4
31719-77-4
41908-12-7
At 0°C, 4 g (23.4 mmol) of 3-(chloromethyl)benzoic acid was dissolved in 250 g of anhydrous ether. Subsequently, 30 ml of lithium methyl solution was slowly added dropwise to this solution. After the dropwise addition was completed, the reaction mixture was continued to be stirred at 0°C for 30 minutes. Upon completion of the reaction, the reaction was quenched by the slow addition of water and the mixture was acidified with hydrochloric acid. The organic phase was separated, washed several times with water and dried with anhydrous magnesium sulfate. The organic phase was concentrated under reduced pressure to give the crude product. The crude product was purified by silica gel column chromatography with the eluent ethyl acetate:heptane (5:95, v/v). Finally, 2.7 g of 3'-chloromethylacetophenone was obtained in 69% yield. The structure of the product was confirmed by 1H NMR (CDCl3): δ 2.62 (3H, s), 4.63 (2H, s), 7.44-7.50 (1H, t), 7.59-7.62 (1H, d, J = 7.6 Hz), 7.89-7.93 (1H, d, J = 6.5 Hz), 7.97 (1H, s).
References
[1] Patent: US6689922, 2004, B1. Location in patent: Page column 20-21
3'-CHLOROMETHYLACETOPHENONE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3'-CHLOROMETHYLACETOPHENONE manufacturers
- Product
- 3'-CHLOROMETHYLACETOPHENONE 41908-12-7
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-09