ChemicalBook > CAS DataBase List > 1-Acetyl-2-phenylhydrazine

1-Acetyl-2-phenylhydrazine

Product Name
1-Acetyl-2-phenylhydrazine
CAS No.
114-83-0
Chemical Name
1-Acetyl-2-phenylhydrazine
Synonyms
2-PHENYLACETOHYDRAZIDE;APH;Pyrodin;Pyrodine;1-Acetyl-2-phenylhyd;2APH;AKOS 90136;HYDRACETIN;AKOS B029762;AURORA KA-349
CBNumber
CB5323155
Molecular Formula
C8H10N2O
Formula Weight
150.18
MOL File
114-83-0.mol
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1-Acetyl-2-phenylhydrazine Property

Melting point:
128-131 °C(lit.)
Boiling point:
271.72°C (rough estimate)
Density 
1.1392 (rough estimate)
refractive index 
1.6180 (estimate)
storage temp. 
Store at +15°C to +25°C.
solubility 
soluble in Alcohol
form 
powder to crystal
pka
12.75±0.23(Predicted)
color 
White to Light yellow to Light orange
BRN 
742880
InChIKey
UICBCXONCUFSOI-UHFFFAOYSA-N
CAS DataBase Reference
114-83-0(CAS DataBase Reference)
NIST Chemistry Reference
2-Acetyl-1-phenylhydrazine(114-83-0)
EPA Substance Registry System
.beta.-Acetylphenylhydrazine (114-83-0)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38-43-20/21/22
Safety Statements 
22-26-36-24/25-36/37
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
RTECS 
AJ2900000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29280090
Hazardous Substances Data
114-83-0(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
A4626
Product name
1-Acetyl-2-phenylhydrazine
Purity
≥98%
Packaging
100g
Price
$135
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20561
Product name
2-Phenylacetohydrazide
Purity
for synthesis
Packaging
50g
Price
$118
Updated
2024/03/01
Sigma-Aldrich
Product number
A4626
Product name
1-Acetyl-2-phenylhydrazine
Purity
≥98%
Packaging
25g
Price
$81.6
Updated
2023/06/20
Sigma-Aldrich
Product number
8.20561
Product name
2-Phenylacetohydrazide
Purity
for synthesis
Packaging
10g
Price
$56.7
Updated
2023/01/07
TCI Chemical
Product number
A0107
Product name
1-Acetyl-2-phenylhydrazine
Purity
>98.0%(GC)
Packaging
25g
Price
$32
Updated
2024/03/01
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1-Acetyl-2-phenylhydrazine Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

1-Acetyl-2-phenylhydrazine is an Anaerobically curable compound.

Synthesis Reference(s)

The Journal of Organic Chemistry, 30, p. 2486, 1965 DOI: 10.1021/jo01018a525

General Description

Colorless prisms or white solid.

Air & Water Reactions

Water insoluble.

Reactivity Profile

1-Acetyl-2-phenylhydrazine is an amide and an amine. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition 1-Acetyl-2-phenylhydrazine emits toxic fumes.

Fire Hazard

Flash point data for 1-Acetyl-2-phenylhydrazine are not available. 1-Acetyl-2-phenylhydrazine is probably combustible.

Purification Methods

Crystallise the hydrazine from aqueous EtOH. [Beilstein 15 H 241.]

1-Acetyl-2-phenylhydrazine Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Acetyl-2-phenylhydrazine Suppliers

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View Lastest Price from 1-Acetyl-2-phenylhydrazine manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
1-Acetyl-2-phenylhydrazine 114-83-0
Price
US $100.00-30.00/kg
Min. Order
1kg
Purity
99.93%
Supply Ability
1000kg per week
Release date
2024-04-22
Shandong Juchuang Chemical Co., LTD
Product
1-Acetyl-2-phenylhydrazine 114-83-0
Price
US $20.00-10.00/kg
Min. Order
500kg
Purity
99.9
Supply Ability
200tons
Release date
2024-03-11
Hebei Yanxi Chemical Co., Ltd.
Product
1-Acetyl-2-phenylhydrazine 114-83-0
Price
US $30.00-25.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
30 tons
Release date
2024-03-04

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