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ChemicalBook > CAS DataBase List > Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)

Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)

Uses
Product Name
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)
CAS No.
2049086-35-1
Chemical Name
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)
Synonyms
)[(R)-1-[(S)-2-(dicycL;CHLORO(4-CYANOPHENYL){(R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYL(DICYCLOHEXYLPHOSPHINE)}NICKEL(II)
CBNumber
CB53357076
Molecular Formula
C43H55ClFeNNiP2
Formula Weight
797.86
MOL File
2049086-35-1.mol
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Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II) Property

form 
solid
color 
orange
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Safety

RIDADR 
UN 3175 4.1 / PGII
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
900943
Product name
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II)
Packaging
250MG
Price
$260
Updated
2024/03/01
Strem Chemicals
Product number
28-0172
Product name
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
28-0172
Product name
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)
Packaging
500mg
Price
$355
Updated
2024/03/01
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Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II) Chemical Properties,Usage,Production

Uses

  1. Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions.
  2. Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines.
  3. Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions.
  4. Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts.

Uses

Amination of aryl chlorides, bromides and sulfonates with ammonia. Amination of aryl carbamates with ammonia or ammonium salts.

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst
reaction type: Asymmetric synthesis

Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II) Suppliers

Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
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sales.bj@hwrkchemical.com
Country
China
ProdList
9371
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Sigma-Aldrich
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021-61415566 800-8193336
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orderCN@merckgroup.com
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China
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Tianjin Kailiqi Biotechnology Co., Ltd.
Tel
15076683720
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022-23754520
Email
klq@cw-bio.com
Country
China
ProdList
5960
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Domole Scientific
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13275595566 13275595566
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Energy Chemical
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China
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Changzhou Furuisi Biotechnology Co., Ltd
Tel
0519-85524369
Email
3477467573@qq.com
Country
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Beijing Jin Ming Biotechnology Co., Ltd.
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psaitong@jm-bio.com
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Shanghai Haohong Scientific Co., Ltd.
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Shanghai Aladdin Biochemical Technology Co.,Ltd.
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Taizhou Chuanxu Pharmaceutical Technology Co., Ltd.
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Shanghai Hao Zhun Biological Technology Co., Ltd.
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Country
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2049086-35-1, Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)Related Search:


  • CHLORO(4-CYANOPHENYL){(R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYL(DICYCLOHEXYLPHOSPHINE)}NICKEL(II)
  • )[(R)-1-[(S)-2-(dicycL
  • 2049086-35-1
  • C43H60ClFeNNiP2