Reactions
ChemicalBook > CAS DataBase List > METHYLTRIOXORHENIUM(VII)

METHYLTRIOXORHENIUM(VII)

Reactions
Product Name
METHYLTRIOXORHENIUM(VII)
CAS No.
70197-13-6
Chemical Name
METHYLTRIOXORHENIUM(VII)
Synonyms
MTO;METHYLTRIOXORHENIUM;METHYLRHENIUM TRIOXIDE;trioxorhenium(VII);Methyltrioxorhenium(Ⅶ);METHYLTRIOXORHENIUM(7);METHYLTRIOXORHENIUM(VII);Methyltrioxo rhenium (V11);Methylrhenium(VII) trioxide;METHYLRHENIUM TRIOXIDE(VII)
CBNumber
CB5353770
Molecular Formula
CH3O3Re
Formula Weight
249.24
MOL File
70197-13-6.mol
More
Less

METHYLTRIOXORHENIUM(VII) Property

Melting point:
111 °C(lit.)
Boiling point:
65°C 0mm
Density 
d23 4.21
form 
crystal
color 
colorless to pale-gray
Water Solubility 
Soluble in water.
Sensitive 
Moisture & Light Sensitive
Merck 
14,6130
BRN 
3927932
More
Less

Safety

Risk Statements 
41
Safety Statements 
22-24/25
RIDADR 
UN1479
WGK Germany 
3
8-10-21
TSCA 
No
HazardClass 
5.1
PackingGroup 
II
HS Code 
29319090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H272May intensify fire; oxidizer

Precautionary statements

P220Keep/Store away from clothing/…/combustible materials.

P221Take any precaution to avoid mixing with combustibles/…

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
412910
Product name
Methyltrioxorhenium(VII)
Purity
Re 71.0-76.0 %
Packaging
100mg
Price
$58.9
Updated
2024/03/01
Sigma-Aldrich
Product number
412910
Product name
Methyltrioxorhenium(VII)
Purity
Re 71.0-76.0 %
Packaging
2g
Price
$428
Updated
2024/03/01
TCI Chemical
Product number
M1296
Product name
Methyltrioxorhenium(VII)
Purity
>97.0%(T)
Packaging
100mg
Price
$38
Updated
2024/03/01
Alfa Aesar
Product number
L18478
Product name
Methyltrioxorhenium(VII), 98%
Packaging
500mg
Price
$106
Updated
2021/12/16
Alfa Aesar
Product number
L18478
Product name
Methyltrioxorhenium(VII), 98%
Packaging
100mg
Price
$30.7
Updated
2021/12/16
More
Less

METHYLTRIOXORHENIUM(VII) Chemical Properties,Usage,Production

Reactions

Catalyst used with H2O2 for oxidation of a variety of substrates.
(a) Alkenes
(b) Secondary amines
(c) Arenes
(d) Silyl enol ethers/Silyl ketene acetals
(e) Sulfides
(f) Bayer-Villager-Type oxidation
(g) Amine oxidation
(h) Phenol oxidation

Chemical Properties

white to blue-grey crystals

Uses

Methyltrioxorhenium(VII) is used as a catalyst for various transformations such as olefin metathesis. It is associated with hydrogen peroxide and used as an oxidizing agent. It is used to prepare acid or ester from the corresponding terminalalkynes. It is a catalytic oxidant used with urea hydrogen peroxide to prepare nitrones. It reacts with 2-methylnaphthalene to get 2-methyl-1,4-naphthoquinone (Vitamin K3). Further, it catalyzes the reaction with aldehydes and diazoketones to get an alkene. In addition to this, it is used as an effective antioxidant under various conditions.

Uses

Potent catalytic oxidant for converting alkenes to epoxides in a variety of solvents and 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone (Vitamin K3).
Catalytic oxidant used with urea hydrogen peroxide in an efficient conversion of imines to nitrones.
An effective antioxidant under various conditions.

METHYLTRIOXORHENIUM(VII) Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

METHYLTRIOXORHENIUM(VII) Suppliers

Tai 'an Jiangzhou Biotechnology Co., LTD
Tel
13854830759 13854830759
Email
3563349062@qq.com
Country
China
ProdList
1963
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8415
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Aemon Chemical
Tel
0086-755-86198205
Email
acinfo@aemonchem.com
Country
China
ProdList
1931
Advantage
57
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Beijing innoChem Science & Technology Co.,Ltd.
Tel
400-810-7969 010-59572699
Fax
010-59572688
Email
ningzi.li@inno-chem.com.cn
Country
China
ProdList
6134
Advantage
55
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66099280 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19915
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22514
Advantage
55
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Aloespharm Co., Ltd.
Tel
021-20960837
Fax
021-20960837
Email
market@aloespharm.com
Country
China
ProdList
1302
Advantage
55
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9978
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
Advantage
60
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Codow Chemical Co.,Ltd.
Tel
18620099427
Fax
+86-20-62619665
Email
amy@howeipharm.com
Country
China
ProdList
17687
Advantage
55
skychemical Co.Ltd
Tel
021-20960837,QQ1332204249
Fax
021-20960837
Email
sales@skychemical.com
Country
China
ProdList
3331
Advantage
55
ShangHai Biochempartner Co.,Ltd
Tel
177-54423994 17754423994
Fax
QQ:2853530913
Email
2853530910@QQ.com
Country
China
ProdList
8014
Advantage
62
Shanghai Civic Chemical Technology Co., Ltd.
Tel
021-34053660
Fax
QQ:2881074831
Email
sale2@labgogo.com
Country
China
ProdList
2018
Advantage
58
Shanghai Yihe Biological Technology Co., Ltd.
Tel
17721395025
Fax
021-68882955
Email
2423903095@qq.com
Country
China
ProdList
3683
Advantage
58
Jinan Jason Pharmaceutical Co., Ltd.
Tel
0531-82956131 15069164249
Fax
0531-82956625
Email
jnjspharm@126.com
Country
China
ProdList
1518
Advantage
55
JinJin Le Chemical Co., Ltd
Tel
10106090
Email
jjlchem2@163.com
Country
China
ProdList
9981
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
021-021-52271985 17721149837
Fax
+86 (21) 52271987
Email
sales@9dingchem.com
Country
China
ProdList
19800
Advantage
60
Rhawn Reagent
Tel
400-400-1332688 18019345275
Fax
400-133-2688
Email
amy@rhawn.cn
Country
China
ProdList
15497
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 18016230971
Fax
021-58955996
Email
malulu@leyan.com
Country
China
ProdList
24969
Advantage
58
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400-6387771-6038 18902104717
Email
sales@heowns.com
Country
China
ProdList
21037
Advantage
60
Jinan Feiteng Pharmaceutical Technology Co., Ltd.
Tel
15589964716
Fax
qq:3360232875
Email
15253102672@163.com
Country
China
ProdList
211
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Shanghai neon biological technology co., LTD
Tel
021-54252912-8903
Email
leona.xin@forneeds.cn
Country
China
ProdList
4759
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52693
Advantage
58
Beijing Minruida Technology Co., Ltd.
Tel
010-82387566 18001021521;
Fax
82387566-801
Email
sales@mreda.com.cn
Country
China
ProdList
10789
Advantage
58
Shanghai bike new material technology co., LTD
Tel
021-34790086 17317635738
Fax
021-34790236
Email
17317635738@163.com
Country
China
ProdList
490
Advantage
58
Zhengzhou Alfa Chemical Co.,Ltd
Tel
+8618530059196
Email
sale04@alfachem.cn
Country
China
ProdList
13502
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418684 +8618949823763
Fax
0086-551-65418684
Email
sales@tnjchem.com
Country
China
ProdList
25356
Advantage
58
sgtlifesciences pvt ltd
Tel
+8617013299288
Email
dj@sgtlifesciences.com
Country
China
ProdList
12373
Advantage
58
Dayang Chem (Hangzhou) Co.,Ltd.
Tel
571-88938639 +8617705817739
Fax
+86-571-88938652,+86-571- 88492614
Email
info@dycnchem.com
Country
China
ProdList
52849
Advantage
58
Shaanxi Dideu Medichem Co. Ltd
Tel
+86-029-89586680 +86-18192503167
Fax
+86-29-88380327
Email
1026@dideu.com
Country
China
ProdList
7724
Advantage
58
Chemwill Asia Co.,Ltd.
Tel
86-21-51086038
Fax
86-21-51861608
Email
chemwill_asia@126.com
Country
CHINA
ProdList
23912
Advantage
58
Hubei Jusheng Technology Co.,Ltd.
Tel
18871490254
Fax
027-59599243
Email
linda@hubeijusheng.com
Country
CHINA
ProdList
28172
Advantage
58

70197-13-6, METHYLTRIOXORHENIUM(VII)Related Search:


  • METHYLTRIOXORHENIUM(VII)
  • METHYLRHENIUM TRIOXIDE
  • Methyltrioxorhenium(VII) Powder
  • Rhenium, methyltrioxo-,(T-4)- (9CI)
  • METHYLRHENIUM TRIOXIDE(VII)
  • Methylrhenium(VII) trioxide
  • METHYLTRIOXORHENIUM(VII), 71.0%-76.0% RE
  • Methyltrioxorhenium(VII),98%
  • Methylrhenium(VII) trioxide, MTO
  • Methyltrioxorhenium(VII),MTO, Methylrhenium(VII) trioxide
  • MethyltrioxorheniuM (VII), 98% 100MG
  • MethyltrioxorheniuM (VII),98% CH3ReO3
  • Methyltrioxorhenium(Ⅶ)
  • MethyltrioxorheniuM(VII) (MTO)
  • MethyltrioxorheniuM(VII) Re 71.0-76.0 %
  • Rhenium,methyltrioxo-,(T-4)-
  • MTO
  • METHYLTRIOXORHENIUM
  • METHYLTRIOXORHENIUM(7)
  • Methyltrioxo rhenium (V11)
  • Methyltrioxorhenium(VII)&gt
  • trioxorhenium(VII)
  • METHYLTRIOXORHENIUM(VII) ISO 9001:2015 REACH
  • 70197-13-6
  • CH3ReO3
  • CH3O3Re
  • Rhenium
  • Catalysis and Inorganic Chemistry
  • organometallic oxide