ChemicalBook > CAS DataBase List > 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE

Product Name
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
CAS No.
88284-48-4
Chemical Name
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
Synonyms
2-(Trimethylsilyl)phenyl Triflate;DK943;DKFELEX0252;(TriMethylsilyl)phenyl Triflate;TriMethylsilyl)phenyl trifluoroMethanesulfona;2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFOTE;2-(trimethylsilyl)phenyl trifluoromethane-sulfona;2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE;2-(TriMethylsilyl)phenyl trifluoroMethanesulfonate 97%;Trifluoromethanesulfonic Acid 2-(Trimethylsilyl)phenyl Ester
CBNumber
CB5399688
Molecular Formula
C10H13F3O3SSi
Formula Weight
298.35
MOL File
88284-48-4.mol
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2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Property

Boiling point:
70 °C/2 mmHg (lit.)
Density 
1.229 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.456(lit.)
Flash point:
205 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
color 
Colorless to Light yellow
Specific Gravity
1.229
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
InChIKey
XBHPFCIWRHJDCP-UHFFFAOYSA-N
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-27-36/37/39-45
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
Ⅱ
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
470430
Product name
2-(Trimethylsilyl)phenyl trifluoromethanesulfonate
Purity
97%
Packaging
1g
Price
$71.5
Updated
2024/03/01
Sigma-Aldrich
Product number
470430
Product name
2-(Trimethylsilyl)phenyl trifluoromethanesulfonate
Purity
97%
Packaging
5g
Price
$223
Updated
2024/03/01
TCI Chemical
Product number
T2089
Product name
2-(Trimethylsilyl)phenyl Trifluoromethanesulfonate
Purity
>95.0%(GC)
Packaging
1g
Price
$62
Updated
2024/03/01
TCI Chemical
Product number
T2089
Product name
2-(Trimethylsilyl)phenyl Trifluoromethanesulfonate
Purity
>95.0%(GC)
Packaging
5g
Price
$188
Updated
2024/03/01
TCI Chemical
Product number
T2089
Product name
2-(Trimethylsilyl)phenyl Trifluoromethanesulfonate
Purity
>95.0%(GC)
Packaging
25g
Price
$626
Updated
2024/03/01
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2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production

Physical properties

bp 70 °C/2 mmHg; d 1.229 g mL?1

Uses

2-(Trimethylsilyl)phenyl trifluoromethanesulfonate may be used to generate benzyne under mild conditions of simple fluoride treatment at room temperature.

Uses

2-(Trimethylsilyl)phenyl Triflate is a useful reagent applied in reactions of Polycyclic Arenes, Heteroatom Arylation,Heteroarenes and Benzannulated Heterocycles, Carbon Arylations, etc.

General Description

2-(Trimethylsilyl)phenyl trifluoromethanesulfonate is an important ortho-benzyne precursor in aryne chemistry.

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials

2-Chlorophenol Toluene Chlorotrimethylsilane Sodium Trifluoromethanesulfonic anhydride Diethyl ether n-Butyllithium

Preparation Products

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2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Suppliers

Belgium 1 China 152 Germany 2 India 2 Japan 2 Switzerland 1 United Kingdom 3 United States 27 Global 190
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Japan
Tel
--
Fax
--
Email
@TCIchemicals.com
Country
Japan
ProdList
2741
Advantage
58
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View Lastest Price from 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
(TriMethylsilyl)phenyl Triflate 88284-48-4
Price
US $1.00-1.00/KG
Min. Order
1g
Purity
99%
Supply Ability
50ton
Release date
2020-05-20
PNP Biotech Co. Ltd
Product
2-trimethylsilylphenyl triflate 88284-48-4
Price
US $0.00/KG
Min. Order
25KG
Purity
97%HPLC
Supply Ability
Inquiry
Release date
2023-03-30
Henan Aochuang Chemical Co.,Ltd.
Product
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE 88284-48-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-09

88284-48-4, 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATERelated Search:

Phenyl trifluoromethanesulfonate Trifluoromethane 4-METHOXY-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,4-METHOXY-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,95.0+%(GC) 3-METHOXY-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,95.0+%(GC),3-Methoxy-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate 1-(TRIMETHYLSILYL)-2-NAPHTHYL TRIFLATE 4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,98.0+%(GC) 2-METHYL-6-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,96.0+%(GC),2-METHYL-6-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE 1,3,5-TRIS[4-(TRIFLUOROMETHANESULFONYLOXY)-3-(TRIMETHYLSILYL)PHENYL]BENZENE 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE 3-(TRIMETHYLSILYL)-2-NAPHTHYL TRIFLUOROMETHANESULFONATE 3,3''-BIS-(TRIMETHYLSILYL)BIPHENYL-4,4''-DIYL BIS(TRIFLUOROMETHANESULFONATE)

  • 2-(Trimethylsilyl)phenyl Triflate
  • Trifluoromethanesulfonic Acid 2-(Trimethylsilyl)phenyl Ester
  • 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
  • 2-(trimethylsilyl)phenyl trifluoromethane-sulfona
  • 2-(Trimethylsilyl)phenyl Triflate Trifluoromethanesulfonic Acid 2-(Trimethylsilyl)phenyl Ester
  • (TriMethylsilyl)phenyl Triflate
  • TriMethylsilyl)phenyl trifluoroMethanesulfona
  • 2-(TriMethylsilyl)phenyl trifluoroMethanesulfonate 97%
  • 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFOTE
  • Methanesulfonic acid, 1,1,1-trifluoro-, 2-(trimethylsilyl)phenyl ester
  • 88284-48-4 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
  • DK943
  • DKFELEX0252
  • 88284-48-4
  • CF3SO3C6H4SiCH33
  • C10H13F3O3SSi
  • Building Blocks
  • Organic Building Blocks
  • Sulfur Compounds
  • Organic Triflates
  • Si (Classes of Silicon Compounds)
  • Si-(C)4 Compounds
  • Silicon Compounds (for Synthesis)
  • Synthetic Organic Chemistry
  • Organic Triflates
  • Organic Building Blocks
  • Sulfur Compounds