ChemicalBook > CAS DataBase List > 3-Methyl-1-phenyl-2-phospholene 1-oxide

3-Methyl-1-phenyl-2-phospholene 1-oxide

Product Name
3-Methyl-1-phenyl-2-phospholene 1-oxide
CAS No.
707-61-9
Chemical Name
3-Methyl-1-phenyl-2-phospholene 1-oxide
Synonyms
NSC 107634;-2-phosphoL;ene 1-Oxide;3-Methyl-1-Phenyl-2;4-methyl-1-phenyl-2,3-dihydro-1;3-methyl-1-phenyl-2-phospholen1-oxide;3-METHYL-1-PHENYL-2-PHOSPHOLENE OXIDE;1-Phenyl-3-methyl-1-oxo-3-phospholine;1-Oxo-3-methyl-1-phenyl-2-phospholene;Methyl-1-Phenyl-2-Phospholene 1-Oxide
CBNumber
CB5411243
Molecular Formula
C11H13OP
Formula Weight
192.19
MOL File
707-61-9.mol
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3-Methyl-1-phenyl-2-phospholene 1-oxide Property

Melting point:
58-62 °C
Boiling point:
150 °C/0.15 mmHg (lit.)
Density 
1.11±0.1 g/cm3(Predicted)
refractive index 
n20/D 1.5707(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Soluble in polar solvents.
form 
Lumps
color 
White to cream
Sensitive 
Hygroscopic
BRN 
609223
InChI
InChI=1S/C11H13OP/c1-10-7-8-13(12,9-10)11-5-3-2-4-6-11/h2-6,9H,7-8H2,1H3
InChIKey
YMKWWHFRGALXLE-UHFFFAOYSA-N
SMILES
P1(=O)(C2=CC=CC=C2)C=C(C)CC1
CAS DataBase Reference
707-61-9(CAS DataBase Reference)
EPA Substance Registry System
1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-, 1-oxide (707-61-9)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-40
Safety Statements 
26-28-36/37/39-45
WGK Germany 
3
RTECS 
SZ6105100
TSCA 
Yes
HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H351Suspected of causing cancer

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
191744
Product name
3-Methyl-1-phenyl-2-phospholene 1-oxide
Purity
85%, technical grade
Packaging
10g
Price
$205
Updated
2023/01/07
TCI Chemical
Product number
M0705
Product name
3-Methyl-1-phenyl-2-phospholene 1-Oxide
Purity
>95.0%(HPLC)
Packaging
5g
Price
$66
Updated
2025/07/31
TCI Chemical
Product number
M0705
Product name
3-Methyl-1-phenyl-2-phospholene 1-Oxide
Purity
>95.0%(HPLC)
Packaging
25g
Price
$234
Updated
2025/07/31
TRC
Product number
M220508
Product name
3-Methyl-1-phenyl-2-phospholine1-Oxide
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
M220508
Product name
3-Methyl-1-phenyl-2-phospholine1-Oxide
Packaging
500mg
Price
$75
Updated
2021/12/16
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3-Methyl-1-phenyl-2-phospholene 1-oxide Chemical Properties,Usage,Production

Chemical Properties

white to yellow adhering crystals

Uses

3-Methyl-1-phenyl-2-phospholene 1-oxide is used as a catalyst for intramolecular aza-wittig cyclization reactions and polymerization reactions. It is a reactant used for the preparation of phospha sugars and their radical bromination derivatives as anticancer agents.

Application

Catalyst for:
Intramolecular aza-Wittig cyclization reactions
Polymerization reactions
Reactant for preparation of:
Phospha sugars and their radical bromination derivatives as anticancer agents

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

3-Methyl-1-phenyl-2-phospholene 1-oxide Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Methyl-1-phenyl-2-phospholene 1-oxide Suppliers

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View Lastest Price from 3-Methyl-1-phenyl-2-phospholene 1-oxide manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE 707-61-9
Price
US $8.80-1.10/kg
Min. Order
1kg
Purity
99%
Supply Ability
500kg
Release date
2025-09-16
Shaanxi Dideu New Materials Co. Ltd
Product
3-Methyl-1-phenyl-2-phospholene 1-oxide 707-61-9
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-02-22
Hebei Chuanghai Biotechnology Co,.LTD
Product
Methyl-1-Phenyl-2-Phospholene 1-Oxide 707-61-9
Price
US $10.70/kg
Min. Order
10kg
Purity
99%
Supply Ability
10000kg
Release date
2024-08-15

707-61-9, 3-Methyl-1-phenyl-2-phospholene 1-oxideRelated Search:

3-METHYL-1-PHENYL-3-PHOSPHOLENE 1-OXIDE,3-METHYL-1-PHENYL-3-PHOSPHOLENE 1-OXIDE (=3-METHYL-1-PHENYL-1-PHOSPHA-3-CYCLOPENTENE 1-OXIDE) 95+% 3-Methyl-1-phenyl-2-phospholene 1-oxide (METHYL-VINYL-PHOSPHINOYL)-BENZENE (ETHYL-VINYL-PHOSPHINOYL)-BENZENE TRIMETHYLPHOSPHINE OXIDE

  • 3-methyl-1-phenyl-2-phospholen1-oxide
  • 3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE
  • 3-METHYL-1-PHENYL-2-PHOSPHOLENE OXIDE
  • 4-METHYL-1-PHENYL-2,3-DIHYDRO-1H-1LAMBDA5-PHOSPHOL-1-ONE
  • 4-METHYL-1-PHENYL-2,3-DIHYDROPHOSPHOL-1-ONE
  • 2,3-DIHYDRO-4-METHYL-1-PHENYL-1H-PHOSPHOLE 1-OXIDE
  • 3-Methyl-1-Phenyl-2-Phosphelene 1-Oxide
  • 3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE TECH., 85%
  • 4,5-Dihydro-3-Methyl-1-Phenylphosphole1-Oxide
  • 3-Methyl-1-phenyl-2-phospholene-1-oxide, ca. 98%
  • 4,5-Dihydro-3-Methyl-1-Phenyl-Oxo-Pentylidene Phosphine
  • 1-Methyl-3-phenyl-2-phospholene 1-oxide
  • 2,3-Dihydro-4-methyl-1-phenylphosphole 1-oxide
  • NSC 107634
  • 3-Methyl-1-phenyl-2-phospholene 1-oxide 85%, technical grade
  • 1-Phenyl-3-methyl-4,5-dihydro-1H-phosphole 1-oxide
  • 1-Phenyl-4-methyl-2,3-dihydro-1H-phosphole 1-oxide
  • 3-Methyl-1-phenyl-4,5-dihydro-1H-phosphole 1-oxide
  • 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide
  • 3-Methyl-1-Phenyl-2
  • 1-Phenyl-3-methyl-1-oxo-3-phospholine
  • 3-Methyl-1-phe3-Methyl-1-phenyl-2-phospholene 1-oxide, 94％
  • 2,3-Dihydro-4-methyl-1-phenyl-1H-phosphole 1-Oxide 4-Methyl-1-phenyl-2,3-dihydrophosphol-1-one
  • 3-Methyl-1-phenyl-2-phospholene oxide, 1-Oxo-3-methyl-1-phenyl-2-phospholene
  • 1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-, 1-oxide
  • 1H-Phosphole,2,3-dihydro-4-methyl-1-phenyl-,1-oxide
  • 2,3-dihydro-4-methyl-1-phenyl-1h-phosphol1-oxide
  • 4,5-Dihydro-3-methyl-1-phenyl-1H-phosphole 1-oxide
  • 3-Methyl-1-phenyl-2-phospholene oxide,98%
  • 2-Phospholene, 3-methyl-1-phenyl-, 1-oxide
  • 1-Oxo-3-methyl-1-phenyl-2-phospholene
  • 3-Methyl-1-phenyl-2-phospholene1-Oxide&gt
  • -2-phosphoL
  • ene 1-Oxide
  • 3-Methyl-1-phenyl-2-phospholine 1-Oxide
  • Methyl-1-Phenyl-2-Phospholene 1-Oxide
  • 4-methyl-1-phenyl-2,3-dihydro-1$l^{5}-phosphole 1-oxide
  • 3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE (MPPO)
  • 4-methyl-1-phenyl-2,3-dihydro-1
  • 3-Methyl-1-phenyl-2-phosphocyclopenten-1-oxide
  • 4-methyl-1-phenyl-2,3-dihydro-1H-1λ?-phosphol-1-one
  • 707-61-9
  • C11H13OP
  • Catalysis and Inorganic Chemistry
  • Phosphorus Precursors
  • Phosphorus Compounds
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Phosphorus Precursors
  • 707-61-9