N,N',N''-METHYLIDYNETRISFORMAMIDE

Product Name: N,N',N''-METHYLIDYNETRISFORMAMIDE
CAS No.: 4774-33-8
Chemical Name: N,N',N''-METHYLIDYNETRISFORMAMIDE
Synonyms: TRIS-FORMAMINOMETHANE;N-(diformamidomethyl)formamide;N-(diformamidomethyl)methanamide;N,N',N''-METHYLIDYNETRISFORMAMIDE;N,N',N''-Methanetriyltriformamide;Formamide, N,N',N''-methylidynetris-;N,N',N''-Methylidynetrisformamide 97%;Tris-formaminomethane/N,N',N''-Methylidynetrisformamide
CBNumber: CB5417058
Molecular Formula: C4H7N3O3
Formula Weight: 145.12
MOL File: 4774-33-8.mol

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N,N',N''-METHYLIDYNETRISFORMAMIDE Property

Melting point:: 170-172 °C (dec.)(lit.)
Boiling point:: 720.5±55.0 °C(Predicted)
Density: 1.280±0.06 g/cm3(Predicted)
solubility: water: soluble25mg/mL, clear, colorless
pka: 12.69±0.23(Predicted)
form: solid
Water Solubility: water: soluble 25mg/mL, clear, colorless

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 159735
Product name: N,N′,N′′-Methylidynetrisformamide
Purity: 97%
Packaging: 5g
Price: $100
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: CHM0156734
Product name: N,N',N''-METHYLIDYNETRISFORMAMIDE
Purity: 95.00%
Packaging: 5G
Price: $857.66
Updated: 2021/12/16

AHH

Product number: MT-20196
Product name: N,N',N''-Methylidynetrisformamide
Purity: 98%
Packaging: 1000g
Price: $538
Updated: 2021/12/16

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N,N',N''-METHYLIDYNETRISFORMAMIDE Chemical Properties,Usage,Production

Uses

N,N′N′′-methylidynetrisformamide (TRIFO) is a source for formamide; used for N-formylformamidine (H2N-CH=N-CHO); for the N-formylformimidoyl group (H-C=NHCHO) as a building block in heterocyclic synthesis).

Preparation

Triethyl Orthoformate reacts with formamide under catalysis of mineral acids to give TRIFO (eq 1). The reaction of excess formamide with inorganic and organic acyl chlorides such as PCl3, POCl3, SOCl2, acetyl chloride, benzoyl chloride, and ethyl chloroformate proceeds via iminium salts to afford TRIFO. Analogously, alkylating reagents such as dialkyl sulfates, alkyl sulfonates or triethyloxonium tetrafluoroborate transform formamide to TRIFO. Alkoxymethyleneiminium salts and formamidinium salts are intermediates in these reactions. Pure salts of this type are also converted to the reagent by formamide. Reaction of Dimethyl Sulfate with formamide is the easiest way to prepare TRIFO.

General Description

N,N′,N′′-Methylidynetrisformamide is also referred as tris(formamido)methane.

Solubility in organics

N,N′N′′-methylidynetrisformamide is soluble in formamide; soluble in aprotic dipolar solvents such as DMF or DMA on heating.

storage

N,N′N′′-methylidynetrisformamide is stored at rt in closed bottles. Use in a fume hood.

N,N',N''-METHYLIDYNETRISFORMAMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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N,N',N''-METHYLIDYNETRISFORMAMIDE Suppliers

China 16 Switzerland 1 United Kingdom 1 United States 2 Global 20

Energy Chemical

Tel: 021-021-58432009 400-005-6266
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Capot Chemical Co., Ltd

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Beijing Ouhe Technology Co., Ltd

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Shanghai Hanhong Scientific Co.,Ltd.

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Country: China
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Sigma-Aldrich

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Amadis Chemical Company Limited

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Capot Chemical Co.,Ltd.

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Shaanxi Dideu Medichem Co. Ltd

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Henan Kehong Biological Technology Co. LTD

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Bide Pharmatech Ltd.

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View Lastest Price from N,N',N''-METHYLIDYNETRISFORMAMIDE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: N,N',N''-METHYLIDYNETRISFORMAMIDE 4774-33-8
Price: US $1.00-22.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100000KG
Release date: 2024-07-16

4774-33-8, N,N',N''-METHYLIDYNETRISFORMAMIDERelated Search:

TRIS(DIFORMYLAMINO)METHANE METHYLENEDIFORMAMIDE N,N',N''-METHYLIDYNETRISFORMAMIDE

TRIS-FORMAMINOMETHANE

Tris-formaminomethane/N,N',N''-Methylidynetrisformamide

N-(diformamidomethyl)formamide

N-(diformamidomethyl)methanamide

N,N',N''-Methylidynetrisformamide 97%

N,N',N''-METHYLIDYNETRISFORMAMIDE

Formamide, N,N',N''-methylidynetris-

N,N',N''-Methanetriyltriformamide

4774-33-8

C4H7N3O3

HCONH3CH

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Amides

Carbonyl Compounds