TRIPHENYLTIN HYDRIDE

Product Name: TRIPHENYLTIN HYDRIDE
CAS No.: 892-20-6
Chemical Name: TRIPHENYLTIN HYDRIDE
Synonyms: TRIPHENYLTIN;TRIPHENYLSTANNANE;triphenyl-stannan;Stannane, triphenyl-;TRIPHENYLTIN HYDRIDE;Triphenylhydridetin(IV);triphenylstannylhydride;Triphenylstannyl hydride;Triphenyltin hydride,95%;Triphenyltin hydride, 97%,
CBNumber: CB5462311
Molecular Formula: C18H16Sn
Formula Weight: 351.03
MOL File: 892-20-6.mol

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TRIPHENYLTIN HYDRIDE Property

Melting point:: 28 °C (lit.)
Boiling point:: 163-165 °C/0.3 mmHg (lit.)
Density: 1.374 g/mL at 25 °C (lit.)
refractive index: n20/D 1.632(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
form: solid
Specific Gravity: 1.374
Appearance: White to off-white Liquid
Water Solubility: Insoluble in water.
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 3544353
Exposure limits: ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference: 892-20-6(CAS DataBase Reference)
EPA Substance Registry System: Triphenyltin (892-20-6)

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Safety

Hazard Codes: T,N
Risk Statements: 23/24/25-50/53
Safety Statements: 26-27-28-45-60-61
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
RTECS: WH8882000
TSCA: No
HazardClass: 6.1
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 244775
Product name: Triphenyltin hydride
Packaging: 5g
Price: $104
Updated: 2023/06/20

Sigma-Aldrich

Product number: 244775
Product name: Triphenyltin hydride
Packaging: 25g
Price: $328
Updated: 2023/06/20

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TRIPHENYLTIN HYDRIDE Chemical Properties,Usage,Production

Chemical Properties

opalescent colorless or milky white to pale yellow. Soluble in many common organic solvents; usually used in benzene or toluene.

Uses

Although the triphenyltins exhibit some curative effect, they are used mainly as protectants for control of a range of diseases, examples being early and late blights of potato and leaf spots on sugar beet and peanut.

Reactivity Profile

Triphenylstannane could be used in the reactions:
Generation of carbon radicals from selenides, halides, sulfides, and alkynes; radical deoxygenation; reduction of α,β- unsaturated aldehydes and ketones; hydrostannylation of alkynes and alkenes; reversible addition of stannyl radicals to double bonds; formation of metal triphenylstannates; reduction of aldehydes and ketones; desulfonation of β-keto phenyl sulfones; hole-transfer-promoted hydrogenation.

reaction suitability

reagent type: reductant

Synthesis

The Preparative Method of Triphenylstannane: reduction of Chlorotriphenylstannane with Lithium Aluminum Hydride in ether or with Sodium Borohydride in glyme; reduction of bis(triphenyltin) oxide with polymethylhydrosiloxane; reduction of triphenyltin methoxide with diborane; protonation of Ph3SnLi. The reagent was also generated in situ from Ph3SnCl and Sodium Cyanoborohydride in t-butyl alcohol.

Precautions

Triphenylstannane (Ph3SnH) can be stored for several months and is easily repurified by Kugelrohr distillation (oil-pump vacuum) before use. Organotin hydrides decompose slowly at rt and are best stored at 0 °C or below.

TRIPHENYLTIN HYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIPHENYLTIN HYDRIDE Suppliers

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View Lastest Price from TRIPHENYLTIN HYDRIDE manufacturers

Henan Fengda Chemical Co., Ltd

Product: TRIPHENYLTIN HYDRIDE 892-20-6
Price: US $8.00-2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-25

892-20-6, TRIPHENYLTIN HYDRIDERelated Search:

Fentin hydroxide BIS(TRIPHENYLTIN) OXIDE Triphenyltin acetate Hexaphenylditin(IV) Tetraphenyltin ALLYLTRIPHENYLTIN Chlorotriphenyltin TRIPHENYLTIN FLUORIDE TRIPHENYLTIN HYDRIDE TETRABUTYLAMMONIUM DIFLUOROTRIPHENYLSTANNATE TETRAPHENYL-D20-TIN TRI-P-TOLYLHYDROXYTIN triphenyltin 3,5-diisopropylsalicylate Decafentin TRIPHENYLIODOTIN TRI-P-TOLYLCHLOROTIN BIS(TRIPHENYLTIN)SULFIDE Tetrakis(pentafluorophenyl)stannane

TRIPHENYLSTANNANE

TRIPHENYLTIN

TRIPHENYLTIN HYDRIDE

Triphenylhydridetin(IV)

Triphenyltin hydride,95%

Stannane, triphenyl-

triphenyl-stannan

Triphenylstannyl hydride

triphenylstannylhydride

TRIPHENYLTIN HYDRIDE ISO 9001：2015 REACH

Triphenyltin hydride, 97%,

892-20-6

Ph3SnH

C18H16Sn

C18H15Sn

C6H53SnH

C6H5SnH

Organometallic Reagents

Organotin

Organotins

Organometallic Reagents

Organotin

OrganotinsSynthetic Reagents

Reduction

Tin Hydrides