ChemicalBook > CAS DataBase List > (11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE

Product Name
(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
CAS No.
138517-66-5
Chemical Name
(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
Synonyms
(S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene;(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE;(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine>9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)-;(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >=95.0% (HPLC);(11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt
CBNumber
CB5500732
Molecular Formula
C16H16N2
Formula Weight
236.31
MOL File
138517-66-5.mol
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(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Property

Melting point:
158 °C
Boiling point:
396.7±42.0 °C(Predicted)
Density 
1.195±0.06 g/cm3(Predicted)
refractive index 
20 ° (C=1, MeOH)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
powder to crystal
pka
9.38±0.40(Predicted)
color 
White to Orange to Green
BRN 
8693351
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
2921.51.5000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D3445
Product name
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
Purity
>98.0%(HPLC)(T)
Packaging
1g
Price
$538
Updated
2024/03/01
TCI Chemical
Product number
D3445
Product name
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
Purity
>98.0%(HPLC)(T)
Packaging
100mg
Price
$103
Updated
2024/03/01
TRC
Product number
D450518
Product name
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
Packaging
2mg
Price
$60
Updated
2021/12/16
TRC
Product number
D450518
Product name
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
Packaging
10mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD59982
Product name
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
Packaging
50mg
Price
$65
Updated
2021/12/16
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(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Chemical Properties,Usage,Production

Uses

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:

  • To synthesize pyridine based C2-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
  • To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
  • To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Suppliers

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138517-66-5, (11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINERelated Search:


  • (11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt
  • (11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
  • (S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene
  • (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >=95.0% (HPLC)
  • (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine&gt
  • 9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)-
  • 138517-66-5
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry