1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE

Product Name: 1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE
CAS No.: 120418-31-7
Chemical Name: 1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE
Synonyms: 1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE;1,1'-Carbonylbis(3-methyl-1H-imidazol-3-ium) triflate;1,1'-Carbonylbis(3-methyl-1H-imidazol-3-ium) ditriflate;bis(3-methylimidazol-3-ium-1-yl)methanone,trifluoromethanesulfonate;1,1'-Carbonyldi(3-methyl-1H-imidazol-3-ium) trifluoromethanesulphonate;1,1'-Carbonylbis(3-methyl-1H-imidazol-3-ium) trifluoromethanesulfonate;1,1'-Carbonylbis[3-Methyl-1H-iMidazoliuM 1,1,1-TrifluoroMethanesulfonate;1,1'-Carbonylbis(3-Methyl-1H-Imidazol-3-Ium) Bis(Trifluoromethanesulfonate);1,1'-Carbonylbis(3-methyl-1H-imidazol-3-ium) bis(trifluoromethanesulphonate)
CBNumber: CB5501133
Molecular Formula: C9H12N4O.CF3O3S
Formula Weight: 490.3568
MOL File: 120418-31-7.mol

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1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE Property

Melting point:: 78-80
storage temp.: Hygroscopic, -20°C Freezer, Under Inert Atmosphere
solubility: Acetonitrile (Slightly), DMSO (Sparingly), Methanol (Slightly)
form: solid
color: White to off-white
Stability:: Hygroscopic
InChI: InChI=1S/C9H12N4O.2CHF3O3S/c1-10-3-5-12(7-10)9(14)13-6-4-11(2)8-13;2*2-1(3,4)8(5,6)7/h3-8H,1-2H3;2*(H,5,6,7)/q+2;;/p-2
InChIKey: BWBZTXSPTHTBBM-UHFFFAOYSA-L
SMILES: C(F)(F)(F)S(=O)([O-])=O.C(F)(F)(F)S([O-])(=O)=O.C(=O)(N1C=C[N+](C)=C1)N1C=C[N+](C)=C1

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Safety

Hazard Codes: Xi
HS Code: 2933299090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC

Product number: C177000
Product name: 1,1''-Carbonylbis(3-methylimidazolium)Triflate
Packaging: 5g
Price: $790
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0017050
Product name: 1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE
Purity: 95.00%
Packaging: 1G
Price: $795.8
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC99808
Product name: 1,1'-Carbonylbis(3-Methyl-1H-Imidazol-3-Ium) Bis(Trifluoromethanesulfonate)
Packaging: 50mg
Price: $50
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC99808
Product name: 1,1'-Carbonylbis(3-Methyl-1H-Imidazol-3-Ium) Bis(Trifluoromethanesulfonate)
Packaging: 100mg
Price: $80
Updated: 2021/12/16

AK Scientific

Product number: 0394BB
Product name: 1,1'-Carbonylbis(3-methylimidazolium)triflate
Packaging: 50mg
Price: $117
Updated: 2021/12/16

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1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE Chemical Properties,Usage,Production

Chemical Properties

1,1′-Carbonylbis(3-methylimidazolium) Bis(trifluoromethanesulfonate) is a White to Off-White Solid, H δ (CDCl3) 8.86 (s, 2H), 7.44 (m, 2H), 7.16 (m, 2H), 4.00 ;(s, 6H); sol nitromethane, chloroform; insol ether; reacts with water.

Uses

An efficient reagent for aminoacylations. Used in the synthesis of chiral Pilocarpine analogs via a C-8 ketone intermediate.

Uses

As an efficient reagent for aminoacylations, 1,1'-Carbonylbis(3-MethyliMidazoliuM) Triflate can be used in the synthesis of chiral Pilocarpine analogs via a C-8 ketone intermediate.

Preparation

Preparative Methods of 1,1′-Carbonylbis(3-methylimidazolium) Bis(trifluoromethanesulfonate): fresh methyl triflate is added to 1,1-carbonylbisimidazole in nitromethane at 10 °C. Solvent is then removed in vacuo, or the reagent used in situ^[1].

storage

1,1′-Carbonylbis(3-methylimidazolium) Bis(trifluoromethanesulfonate) is usually prepared under anhydrous conditions and used immediately. It can be stored in dry nitromethane solution or in solid state in absence of moisture. Preparation using aged methyl triflate should be avoided, owing to possible contamination of the coupling reagent with triflic acid^[1].

References

1. Saha, A. K.; Schultz, P.; Rapoport, H. JACS, 1989, 111, 4856.

1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE Suppliers

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120418-31-7, 1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATERelated Search:

1,3-DIMETHYLIMIDAZOLIUM TRIFLUOROMETHANESULFONATE AMMONIUM TRIFLUOROMETHANESULFONATE IMIDAZOLE TRIFLUOROMETHANESULFONATE SA& 1,3-Dimethylimidazolium methanesulfonate 1,1'-Carbonyldiimidazole 1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE

1,1'-Carbonylbis(3-methyl-1H-imidazol-3-ium) triflate

1,1'-Carbonylbis[3-Methyl-1H-iMidazoliuM 1,1,1-TrifluoroMethanesulfonate

1,1'-Carbonylbis(3-methyl-1H-imidazol-3-ium) bis(trifluoromethanesulphonate)

1,1'-Carbonylbis(3-methyl-1H-imidazol-3-ium) ditriflate

1,1'-Carbonylbis(3-methyl-1H-imidazol-3-ium) trifluoromethanesulfonate

1,1'-Carbonyldi(3-methyl-1H-imidazol-3-ium) trifluoromethanesulphonate

1,1'-Carbonylbis(3-Methyl-1H-Imidazol-3-Ium) Bis(Trifluoromethanesulfonate)

bis(3-methylimidazol-3-ium-1-yl)methanone,trifluoromethanesulfonate

1,1'-CARBONYLBIS(3-METHYLIMIDAZOLIUM) TRIFLATE

120418-31-7

C9H12N4OCF3O3S

C11H12F6N4O7S2

C9H12N4O2CF3O3S

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