METHOXYALLENE; 95%DISCONTINUED 05/24/01

Product Name: METHOXYALLENE; 95%DISCONTINUED 05/24/01
CAS No.: 13169-00-1
Chemical Name: METHOXYALLENE; 95%DISCONTINUED 05/24/01
Synonyms: NSC 363923;CH2=C=CHOCH3;Methoxyallene;1-Methoxyallene;3-Methoxyallene;Methoxypropadiene;1-Methoxypropadiene;Allenyl methyl ether;Propadienylmethyl ether;95%DISCONTINUED 05/24/01
CBNumber: CB5501951
Molecular Formula: C4H6O
Formula Weight: 70.09
MOL File: 13169-00-1.mol

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METHOXYALLENE; 95%DISCONTINUED 05/24/01 Property

Boiling point:: 48.2℃ (760 torr)
Density: 0.832 g/mL at 25 °C
refractive index: n20/D 1.429
Flash point:: -29 °C
storage temp.: 2-8°C
solubility: sol THF, ether, pentane, hexane, CH2Cl2, CHCl3, DMSO
form: liquid

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Safety

Hazard Codes: F
Risk Statements: 11
RIDADR: UN 1993 3/PG 2
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Danger
Hazard statements: H225Highly Flammable liquid and vapour
Precautionary statements: P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 694126
Product name: Methoxyallene
Purity: technical grade
Packaging: 1g
Price: $73.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 694126
Product name: Methoxyallene
Purity: technical grade
Packaging: 5g
Price: $246
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: CHM0116965
Product name: METHOXYALLENE
Purity: 95.00%
Packaging: 1G
Price: $645.42
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0116965
Product name: METHOXYALLENE
Purity: 95.00%
Packaging: 5G
Price: $918.06
Updated: 2021/12/16

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METHOXYALLENE; 95%DISCONTINUED 05/24/01 Chemical Properties,Usage,Production

Uses

Reactant involved in:• ;Multicomponent reactions with nitriles and carboxylic acids followed by cyclocondensation for synthesis of enantiopure pyridines1• ;Intermolecular hydroamination2• ;One-pot synthesis of alkoxy and (alkylsulfanyl)-substituted pyrroles and dihydropyridines3• ;Intermolecular [4+2] cycloaddition with dienes4• ;Allenyl cyclization and subsequent transformation into dicarbonyl, cyclopentenones, and butenolide compounds5• ;Insertion reactions of C-C pi-bonds into alkylidenesilacyclopropanes6

Uses

Reactant involved in:

Multicomponent reactions with nitriles and carboxylic acids followed by cyclocondensation for synthesis of enantiopure pyridines
Intermolecular hydroamination
One-pot synthesis of alkoxy and (alkylsulfanyl)-substituted pyrroles and dihydropyridines
Intermolecular [4+2] cycloaddition with dienes
Allenyl cyclization and subsequent transformation into dicarbonyl, cyclopentenones, and butenolide compounds
Insertion reactions of C-C pi-bonds into alkylidenesilacyclopropanes

Preparation

Methoxyallene can be prepared on a tens-of-grams scale by the base-catalyzed isomerization of 1-methoxy-2-propyne (methyl propargyl ether). Related 1-alkoxy-1,2-propadiene ethers can be prepared similarly. A convenient version of this preparation has been reported.

METHOXYALLENE; 95%DISCONTINUED 05/24/01 Preparation Products And Raw materials

Raw materials

Preparation Products

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METHOXYALLENE; 95%DISCONTINUED 05/24/01 Suppliers

China 13 India 1 Switzerland 2 United States 5 Global 21

Syntechem Co.,Ltd

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Aikon International Limited

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View Lastest Price from METHOXYALLENE; 95%DISCONTINUED 05/24/01 manufacturers

Career Henan Chemical Co

Product: METHOXYALLENE; 95%DISCONTINUED 05/24/01 13169-00-1
Price: US $0.01/KG
Min. Order: 1KG
Purity: 95%-99%
Supply Ability: 1kg; 100kg； 500kg
Release date: 2019-12-24

13169-00-1, METHOXYALLENE; 95%DISCONTINUED 05/24/01Related Search:

METHOXYALLENE; 95%DISCONTINUED 05/24/01 SPECS AE-562/12222523 Allene

Propadienylmethyl ether

Allenyl methyl ether

1-Methoxypropa-1,2-diene

NSC 363923

Methoxyallene technical grade

95%DISCONTINUED 05/24/01

METHOXYALLENE; 95%DISCONTINUED 05/24/01

1,2-Propadiene, 1-methoxy-

1-methoxy-1,2-propadiene

1-Methoxyallene

1-Methoxypropadiene

3-Methoxyallene

CH2=C=CHOCH3

Ether, methyl propadienyl

Methoxyallene

Methoxypropadiene

Methyl propadienyl ether

Methyl(1,2-propadienyl) ether

1,2-Propadiene, 1-methoxy- (9CI)

13169-00-1

Allenes

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